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Copper p-toluenesulfonate/acetic acid: a recyclable synergistic catalytic system for the tetrahydropyranylation of alcohols and phenols

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Abstract

Copper p-toluenesulfonate/acetic acid was found to be an efficient, chemoselective synergistic catalytic system, with catalyst loading as low as 0.3 mol% leading to clean, high-yielding tetrahydropyranylation of a variety of alcohols and phenols. By simple phase-separation, copper p-toluenesulfonate can be easily recovered and reused for several times without deterioration in catalytic activity.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Bohai University, Jinzhou, China

    Min Wang

  2. Center for Science and Technology Experiment, Bohai University, Jinzhou, China

    Zhi-Guo Song

  3. Liaoning Shihua University, Fushun, China

    Heng Jiang & Hong Gong

Authors
  1. Min Wang
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  2. Zhi-Guo Song
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  3. Heng Jiang
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  4. Hong Gong
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Corresponding author

Correspondence to Min Wang.

Additional information

Correspondence: Min Wang, College of Chemistry and Chemical Engineering, Bohai University, Jinzhou, China.

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Wang, M., Song, ZG., Jiang, H. et al. Copper p-toluenesulfonate/acetic acid: a recyclable synergistic catalytic system for the tetrahydropyranylation of alcohols and phenols. Monatsh Chem 139, 601–604 (2008). https://doi.org/10.1007/s00706-007-0821-0

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  • DOI: https://doi.org/10.1007/s00706-007-0821-0

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