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Synthesis of S-Aryl/Alkyl Thiolcarbonates from Disulfides and Chloroformates in the Presence of the Zn/AlCl3 System

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Summary.

A simple, general, and high yielding method has been developed for the synthesis of S-aryl/alkyl-O-aryl/alkyl thiolcarbonates from various chloroformates and disulfides by reductive cleavage of the S–S bond with a Zn/AlCl3 system in dry acetonitrile at 80°C.

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Authors and Affiliations

  1. Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran

    Barahman Movassagh & Maryam Tavoosi

  2. Kermanshah Oil Refining Company, Kermanshah, Iran

    Barahman Movassagh

Authors
  1. Barahman Movassagh
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  2. Maryam Tavoosi
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Correspondence to Barahman Movassagh.

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Movassagh, B., Tavoosi, M. Synthesis of S-Aryl/Alkyl Thiolcarbonates from Disulfides and Chloroformates in the Presence of the Zn/AlCl3 System. Monatsh Chem 139, 251–253 (2008). https://doi.org/10.1007/s00706-007-0778-z

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  • DOI: https://doi.org/10.1007/s00706-007-0778-z

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