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Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts. Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)

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Summary.

We report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu 4 (tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P21/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed.

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Authors and Affiliations

  1. Departamento de Química, Universidad Nacional del Sur, Bahía Blanca, Argentina

    Mariana Dennehy & Oscar V. Quinzani

  2. INIQO, Departamento de Química, Universidad Nacional del Sur, Bahía Blanca, Argentina

    Sandra D. Mandolesi

  3. CEQUINOR, Facultad de Ciencias Exactas y Facultad de Ingeniería, Universidad Nacional de La Plata, La Plata, Argentina

    Jorge A. Güida

  4. Departamento de Física and Instituto IFLP (CONICET), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina

    Gustavo A. Echeverría & Oscar E. Piro

  5. Departamento de Ciencias Básicas, Universidad Nacional de Luján, Luján, Argentina

    Jorge A. Güida

Authors
  1. Mariana Dennehy
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  2. Oscar V. Quinzani
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  3. Sandra D. Mandolesi
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  4. Jorge A. Güida
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  5. Gustavo A. Echeverría
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  6. Oscar E. Piro
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Corresponding author

Correspondence to Oscar V. Quinzani.

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Dennehy, M., Quinzani, O., Mandolesi, S. et al. Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts. Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac). Monatsh. Chem. 138, 669–675 (2007). https://doi.org/10.1007/s00706-007-0648-8

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  • DOI: https://doi.org/10.1007/s00706-007-0648-8

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