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An Easy One-Pot Procedure for the Synthesis of N-Sulfonyl Phosphorous Ylides and Sulfonyl Iminophosphoranes

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Summary.

Reaction of triphenylphosphine and an electron deficient acetylenic ester in the presence of strong N–H acid such as alkyl and aryl sulfamides or acetamide produces phosphorous ylides at room temperature in CH2Cl2. The aryl sulfamide phosphoranes undergo a smooth transformation reaction in boiling toluene and produce iminophosphoranes.

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Authors and Affiliations

  1. Department of Chemistry, Shahid Beheshti University, Tehran, Iran

    Ahmad Shaabani, Abbas Rahmati & Soheila Naderi

Authors
  1. Ahmad Shaabani
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  2. Abbas Rahmati
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  3. Soheila Naderi
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Correspondence to Ahmad Shaabani.

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Shaabani, A., Rahmati, A. & Naderi, S. An Easy One-Pot Procedure for the Synthesis of N-Sulfonyl Phosphorous Ylides and Sulfonyl Iminophosphoranes. Monatsh. Chem. 138, 553–557 (2007). https://doi.org/10.1007/s00706-007-0640-3

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  • DOI: https://doi.org/10.1007/s00706-007-0640-3

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