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Studies on the Distribution of Phenoxyacetic Acid in Two-Phase Systems: n-Aliphatic Hydrocarbon – Water

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Summary.

Phenoxyacetic acid distribution in two-phase systems n-aliphatic hydrocarbon (C5–C8) – water and its dimerization in organic phase were investigated. The values of distribution coefficient (D HR), distribution constant (K D), and dimerization constant (K dim) of acid were obtained. The empirical correlations of these quantities with Hildebrand solubility parameter of organic solvents were established. The influence of pH of the aqueous phase as well as the polarity of the applied organic solvents on phenoxyacetic acid physical chemistry in the two-phase systems was described.

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, Faculty of Chemistry, Rzeszów University of Technology, Rzeszów, Poland

    Jan Kalembkiewicz & Jolanta Szlachta

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  1. Jan Kalembkiewicz
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  2. Jolanta Szlachta
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Correspondence to Jan Kalembkiewicz.

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Kalembkiewicz, J., Szlachta, J. Studies on the Distribution of Phenoxyacetic Acid in Two-Phase Systems: n-Aliphatic Hydrocarbon – Water. Monatsh. Chem. 138, 849–852 (2007). https://doi.org/10.1007/s00706-007-0627-0

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  • DOI: https://doi.org/10.1007/s00706-007-0627-0

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