Skip to main content
SpringerLink
Log in

Cerium(III/IV) and Cerium(IV)–Titanium(IV) Citric Complexes Prepared in Ethylene Glycol Medium

  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Summary.

Cerium(III/IV) and Ce(IV)–Ti(IV) citric complexes were synthesized in ethylene glycol medium under conditions similar to those of the polymerized complex method (PCM). Solution phase 1H, 13C NMR, solid state 13C CP MAS NMR and IR spectroscopy, and X-ray powder diffractometry were used to characterize the composition and structure of the synthesized products. Thermal decomposition of the isolated complexes was studied and a scheme of the processes taking place is proposed. Complexes of Ce(III) can be prepared at low temperature (40°C), only. In the presence of Ti(IV) ions, the oxidation takes place even at this temperature. A mixed-metal nature of the Ce(IV)–Ti(IV) complexes is established. The comparison between their composition and the one of analogous lanthanide(III)–Ti(IV) citrates contributes to the elucidation of the complexation process mechanism in the case of the PCM application. The increased charge of the complexation agent in the Ce4+–Ti4+ complex (in comparison with Ln 3+–Ti4+ citrates) is “compensated” by the increase of the relative number of the ligands with deprotonated OH group.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • MM Milanova M Kakihana M Arima M Yashima M Yoshimura (1996) J Alloys Comp 224 6

    Google Scholar 

  • M Kakihana MM Milanova M Arima T Okubo M Yashima M Yoshmura (1996) J Am Ceram Soc 79 1673 Occurrence Handle10.1111/j.1151-2916.1996.tb08781.x Occurrence Handle1:CAS:528:DyaK28XjslaitrY%3D

    Article  CAS  Google Scholar 

  • MM Milanova MG Arnaudov MM Getsova DS Todorovsky (1997) J Alloys Comp 264 95 Occurrence Handle10.1016/S0925-8388(97)00225-9

    Article  Google Scholar 

  • MG Arnaudov MG Getsova DS Todorovsky MM Milanova (1998) Anal Lab 7 70 Occurrence Handle1:CAS:528:DyaK1cXns1Gitr8%3D

    CAS  Google Scholar 

  • MM Getsova DS Todorovsky MG Arnaudov (2000) Z Anorg Allg Chemie 626 1488 Occurrence Handle10.1002/(SICI)1521-3749(200006)626:6<1488::AID-ZAAC1488>3.0.CO;2-I Occurrence Handle1:CAS:528:DC%2BD3cXjslClsbg%3D

    Article  CAS  Google Scholar 

  • DS Todorovsky MM Getsova MA Vasileva (2002) J Mat Sci 37 4029 Occurrence Handle10.1023/A:1019600815906 Occurrence Handle1:CAS:528:DC%2BD38XlvVykurw%3D

    Article  CAS  Google Scholar 

  • M Getsova D Todorovsky (2000) Bulg Chem Commun 32 89 Occurrence Handle1:CAS:528:DC%2BD3cXos1Slt7Y%3D

    CAS  Google Scholar 

  • M Arima M Kakihana Y Nakamura M Yashima M Yoshimura (1996) J Am Ceram Soc 79 2847 Occurrence Handle10.1111/j.1151-2916.1996.tb08718.x Occurrence Handle1:CAS:528:DyaK28Xnt1akt7Y%3D

    Article  CAS  Google Scholar 

  • M Kakihana T Okubo M Arima O Uchiama M Yashima M Yoshimura Y Nakamura (1997) Chem Mat 9 451 Occurrence Handle10.1021/cm9602353 Occurrence Handle1:CAS:528:DyaK2sXnt1ansA%3D%3D

    Article  CAS  Google Scholar 

  • Zhou Z-H, Deng Y-F, Jiang JQ, Wan H-L, Ng S-W (2006) Dalton Trans 2636

  • ET Kefalas P Panagiotidis CP Raptopoulou A Terzis T Mavromoustakos A Salifoglou (2005) Inorg Chem 44 2596 Occurrence Handle15819544 Occurrence Handle10.1021/ic049276o Occurrence Handle1:CAS:528:DC%2BD2MXit1agsrY%3D

    Article  PubMed  CAS  Google Scholar 

  • JM Collins R Uppal CD Incarvito AM Valentine (2005) Inorg Chem 44 4331 Occurrence Handle10.1021/ic048158y Occurrence Handle1:CAS:528:DC%2BD2MXjtl2isL8%3D

    Article  CAS  Google Scholar 

  • D Todorovsky N Petrova M Getsova R Todorovska I Manolov S Groudeva-Zotova (2004) Key Eng Mat 264–268 359 Occurrence Handle10.4028/www.scientific.net/KEM.264-268.359

    Article  Google Scholar 

  • JP Glusker JA Minkin AL Patterson (1969) Acta Cryst B25 1066

    Google Scholar 

  • G Roelofsen JA Cauters (1972) Cryst Struct Commun 1 23 Occurrence Handle1:CAS:528:DyaE38Xhtlaksbw%3D

    CAS  Google Scholar 

  • T Fujita (1982) Chem Pharm Bull 30 3461 Occurrence Handle1:CAS:528:DyaL3sXhtVSitrs%3D

    CAS  Google Scholar 

  • K Nakamoto (1977) Infrared and Raman Spectra of Inorganic and Coordination Compounds Wiley New York 59

    Google Scholar 

  • ME Cudby (1988) Ekt Spectr News 78 18

    Google Scholar 

  • Breitmeier E, Voelter W (1987) Carbon-13 NMR Spectroscopy, VCH, Weinheim, p 226

  • J Strouse SW Layten CE Strouse (1977) J Am Chem Soc 99 562 Occurrence Handle830693 Occurrence Handle10.1021/ja00444a041 Occurrence Handle1:CAS:528:DyaE2sXmslCitQ%3D%3D

    Article  PubMed  CAS  Google Scholar 

  • D Todorovsky M Getsova I Wawer P Stefanov V Enchev (2004) Mater Lett 58 3559 Occurrence Handle10.1016/j.matlet.2004.06.051 Occurrence Handle1:CAS:528:DC%2BD2cXotFGmtLc%3D

    Article  CAS  Google Scholar 

  • E Zhecheva R Stoyanova M Gorova R Alcantara J Morales JL Tirado (1996) Chem Mater 8 1429 Occurrence Handle10.1021/cm960009t Occurrence Handle1:CAS:528:DyaK28Xjs1Gktb0%3D

    Article  CAS  Google Scholar 

  • N Daskalova S Velichkov P Slavova E Ivanova (1997) Spectrochim Acta B52 257

    Google Scholar 

  • N Daskalova S Velichkov N Krasnobaeva P Slavova (1992) Spectrochim Acta B47 E1595

    Google Scholar 

  • Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Montgomery Jr JA, Vreven T, Kudin KN, Burant JC, Millam JM, Iyengar SS, Tomasi J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson GA, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox J, Hratchian HP, Cross JB, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Ayala PY, Morokuma K, Voth GA, Salvador P, Dannenberg JJ, Zakrzewski VG, Dapprich S, Daniels AD, Strain MC, Farkas O, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Ortiz JV, Cui Q, Baboul AG, Clifford S, Cioslowski J, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin RL, Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Challacombe M, Gill PMW, Johnson B, Chen W, Wong MW, Gonzalez C, Pople JA (2003) Gaussian Inc., Pittsburgh PA

  • W Stevans H Basch J Krauss (1984) J Chem Phys 81 6028 Occurrence Handle1984JChPh..81.6026S

    ADS  Google Scholar 

  • W Stevans H Basch J Krauss (1992) Ca J Chem 81 612 Occurrence Handle10.1139/v92-085

    Article  Google Scholar 

  • TR Cundari WJ Stevans (1993) J Chem Phys 98 5555 Occurrence Handle10.1063/1.464902 Occurrence Handle1993JChPh..98.5555C Occurrence Handle1:CAS:528:DyaK3sXis1Whtr4%3D

    Article  ADS  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, University of Sofia, 1, Sofia, Bulgaria

    M. Getsova & D. Todorovsky

  2. Institute of Organic Chemistry, Bulgarian Academy of Science, Sofia, Bulgaria

    V. Enchev

  3. Faculty of Pharmacy, The Medical University of Warsaw, Warsaw, Poland

    I. Wawer

Authors
  1. M. Getsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. Todorovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. Enchev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. Wawer
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. Todorovsky.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Getsova, M., Todorovsky, D., Enchev, V. et al. Cerium(III/IV) and Cerium(IV)–Titanium(IV) Citric Complexes Prepared in Ethylene Glycol Medium. Monatsh. Chem. 138, 389–401 (2007). https://doi.org/10.1007/s00706-007-0624-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-007-0624-3

Search

Navigation