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Modeling the Kinetics of Hydrosilylation Based Polyaddition

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Summary.

Platinum(II) chloride was used in the hydrosilylation of 1,1,3,3-tetramethyldisiloxane and divinylbenzene. The reaction was monitored online by FTIR spectroscopy and reaction kinetics were determined by Self Modeling Curve Resolution (SMCR). The hydrosilylation polymerization follows a second order polyaddition kinetics with k = 2.03 × 10−4 dm3 mol−1 s−1.

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Authors and Affiliations

  1. Wacker Chemie AG, Burghausen, Germany

    Nicolas C. Imlinger & Manfred Krell

  2. Leibniz-Institute of Surface Modification e. V. (IOM), Leipzig, Germany

    Nicolas C. Imlinger & Michael R. Buchmeiser

  3. Institute of Technical Chemistry, University of Leipzig, Leipzig, Germany

    Nicolas C. Imlinger & Michael R. Buchmeiser

Authors
  1. Nicolas C. Imlinger
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  2. Manfred Krell
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  3. Michael R. Buchmeiser
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Correspondence to Manfred Krell or Michael R. Buchmeiser.

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Imlinger, N., Krell, M. & Buchmeiser, M. Modeling the Kinetics of Hydrosilylation Based Polyaddition. Monatsh. Chem. 138, 285–291 (2007). https://doi.org/10.1007/s00706-007-0619-0

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  • DOI: https://doi.org/10.1007/s00706-007-0619-0

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