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Si-Containing Amides of Phosphoric Acid

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Summary.

The first representative of the N-silylmethylamides of phosphoric acid O=P[NMe(CH2SiMe n (OEt)3-n ]3 have been synthesized by interaction of MeNHCH2SiMe n (OEt)3-n (n = 2, 3) with POCl3. The interaction of the N,N′,N″-trimethyl-N,N′,N″-tris[(ethoxydimethyl- silyl)methyl]triamide phosphoric acid with BF3·Et2O or BCl3 results in the formation of the N,N′,N″-trimethyl-N,N′,N″-tris[(fluorodimethyl-silyl)methyl]triamide phosphoric acid or N,N′,N″-trimethyl-N,N′,N″-tris[(chlorodimethylsilyl)methyl]triamide phosphoric acid. NMR data show on the tetracoordinate state of silicon in these products.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia

    Vadim A. Pestunovich, Nataliya F. Lazareva & Alexander I. Albanov

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  1. Vadim A. Pestunovich
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  2. Nataliya F. Lazareva
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  3. Alexander I. Albanov
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Correspondence to Nataliya F. Lazareva.

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Professor Vadim Aleksandrovich Pestunovich, our chief, teacher and friend died on July 4th, 2004

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Pestunovich, V., Lazareva, N. & Albanov, A. Si-Containing Amides of Phosphoric Acid. Monatsh. Chem. 137, 1005–1013 (2006). https://doi.org/10.1007/s00706-006-0510-4

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