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Crystal Structure and Spectral Characterization of a Rare Example of a Salen-Type Zinc Complex with Neutral Monodentate Oxygen Donor Ligands Coordination

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Summary.

The new zinc complex of the N,N′-bis(salicylidene)-4-methyl-1,3-phenylenediamine ligand as a product of the [2 + 1] Schiff base condensation process was synthesized in the one-step metal-promoted reaction between salicylaldehyde and 4-methyl-1,3-phenylenediamine in ethanol in the presence of zinc chloride. The two potentially tetradentate N2O2 Schiff bases function as neutral monodentate ligands involving only one oxygen atom in coordination. This rare coordination pattern of a mononuclear salen-type zinc complex was revealed by X-ray crystallography and correlated with spectroscopic characterization.

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Authors and Affiliations

  1. Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland

    Małgorzata T. Kaczmarek, Maciej Kubicki & Wanda Radecka-Paryzek

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  1. Małgorzata T. Kaczmarek
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  2. Maciej Kubicki
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  3. Wanda Radecka-Paryzek
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Correspondence to Wanda Radecka-Paryzek.

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Kaczmarek, M., Kubicki, M. & Radecka-Paryzek, W. Crystal Structure and Spectral Characterization of a Rare Example of a Salen-Type Zinc Complex with Neutral Monodentate Oxygen Donor Ligands Coordination. Monatsh. Chem. 137, 997–1003 (2006). https://doi.org/10.1007/s00706-006-0505-1

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  • DOI: https://doi.org/10.1007/s00706-006-0505-1

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