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Diastereoselective Synthesis of meso-Bisphosphonates from Trialkyl(aryl) Phosphites and Activated Acetylenes in the Presence of 4-Nitrophenol

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Summary.

The reaction between trialkyl(aryl) phosphites and dibenzoylacetylene or dimethyl acetylenedicarboxylate in the presence of 4-nitrophenol leads to stable meso-bisphosphonate derivatives in good yields.

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Authors and Affiliations

  1. Department of Chemistry, Tarbiat Modarres University, Tehran, Iran

    Issa Yavari, Zinatossadat Hossaini & Abdolali Alizadeh

Authors
  1. Issa Yavari
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  2. Zinatossadat Hossaini
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  3. Abdolali Alizadeh
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Correspondence to Issa Yavari.

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Yavari, I., Hossaini, Z. & Alizadeh, A. Diastereoselective Synthesis of meso-Bisphosphonates from Trialkyl(aryl) Phosphites and Activated Acetylenes in the Presence of 4-Nitrophenol. Monatsh. Chem. 137, 1083–1088 (2006). https://doi.org/10.1007/s00706-006-0502-4

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  • DOI: https://doi.org/10.1007/s00706-006-0502-4

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