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Physicochemical Modelling of Solid/Liquid Interfacial Phenomena

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Summary.

The proposed modelling of solid/liquid interfacial phenomena consists in relating the main experimental parameter – contact angle θ for metals or alloys on different substrates to combinations of the interatomic interaction parameters of the phases in contact. Physically, these interatomic interaction parameters are analogous to the electronic density distribution in the first and second coordination spheres of the crystallographic lattice of the component, to the bond length, and to the electrochemical factors. The contact angle θ of some alloys on AlN substrates in the case of non-reactive or reactive wetting is calculated.

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Authors and Affiliations

  1. Moscow State Steel and Alloys Institute, Moscow, Russia

    Alexey V. Koltsov

  2. Nekrasov Institute of Ferrous Metallurgy, National Academy of Sciences of Ukraine, Dnepropetrovsk, Ukraine

    Eduard V. Prihod’ko

  3. Moscow Institute of Electronic Engineering, Zelenograd, Russia

    Andrey S. Pashinkin & Vladimir B. Koltsov

Authors
  1. Alexey V. Koltsov
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  2. Eduard V. Prihod’ko
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  3. Andrey S. Pashinkin
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  4. Vladimir B. Koltsov
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Correspondence to Vladimir B. Koltsov.

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Koltsov, A., Prihod’ko, E., Pashinkin, A. et al. Physicochemical Modelling of Solid/Liquid Interfacial Phenomena. Monatsh. Chem. 137, 693–701 (2006). https://doi.org/10.1007/s00706-006-0471-7

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  • DOI: https://doi.org/10.1007/s00706-006-0471-7

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