Skip to main content
SpringerLink
Log in

Europium-Containing Organic Gels and Organic and Carbon Aerogels. Preparation and Initial Applications in Catalysis

  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

We prepared organic gels and organic and carbon aerogels doped with europium through sol–gel processes. Eu-gels were prepared by sol–gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde followed by ion-exchange with Eu(OTf)3. Eu–organic aerogels were obtained after CO2 supercritical drying of the gels and Eu–carbon aerogels were obtained by pyrolysing the organic aerogels. The Eu-gels containing 12% europium proved to be efficient as recoverable catalyst in Michael additions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • For references on lanthanide grafting on silica xerogels see: a) Klonkowski AM, Lis S, Pietraszkiewicz M, Hnatejko Z, Czarnobaj K, Elbanowski M (2003) Chem Mater 15: 656; b) Zaitoun MA, Goken DM, Bailey LS, Kim T, Lin CT (2000) J Phys Chem 104: 189; c) Embert F, Mehdi A, Reyé C, Corriu RJP (2001) Chem Mater 13: 4542

    Google Scholar 

  • S Grandi C Tomasi P Mustarelli A Dossena G Cecchet (2004) Thermochim Acta 418 117 Occurrence Handle10.1016/j.tca.2003.11.048 Occurrence Handle1:CAS:528:DC%2BD2cXmtFyisLg%3D

    Article  CAS  Google Scholar 

  • Zhang B-X, Zhao W-M, Zhu W-Q, Wang K-S, Jinag X-Y (2000) Wuji Cailiao Xuebao 15: 727; (2000) Chem Abst 134: 10927

  • Ye C, Yao L, Guo C, Mou J, Shi G (2000) Huaxue Wuli Xuebao 13: 694; (2001) Chem Abst 134: 302441

  • Zhang B, Zhao W, Zhu W, Wang K, Jiang X, Zhang Z, Xu S (2000) Gongneng Cailiao 31: 637; (2001) Chem Abst 134: 127172

  • Wang K, Jiang X, Zhang Z, Xu S (1999) Faguang Xuebao 20: 176; (2000) Chem Abst 133: 111769

  • J Eid A-C Pierre G Baret (2005) J Non-Cryt Solids 351 218 Occurrence Handle10.1016/j.jnoncrysol.2004.11.020 Occurrence Handle1:CAS:528:DC%2BD2MXovVGq

    Article  CAS  Google Scholar 

  • J Bouaziz D Bourret A Sivade C Grill (1992) J Non-Cryst Solids 145 71 Occurrence Handle10.1016/S0022-3093(05)80432-6 Occurrence Handle1:CAS:528:DyaK38XlslKmtrc%3D

    Article  CAS  Google Scholar 

  • S Grandi L Costa (1998) J Non-Cryst Solids 225 141 Occurrence Handle10.1016/S0022-3093(98)00109-4 Occurrence Handle1:CAS:528:DyaK1cXjvVSrsL0%3D

    Article  CAS  Google Scholar 

  • For reviews on lanthanides as catalysts see: a) Comelles J, Moreno-Mañas M, Vallribera A (2005) ARKIVOC 9: 207; b) Kobayashi S, Sugiura M, Kitagawa H, Lam W-L (2002) Chem Rev 102: 2227; c) Mikami K, Terada M, Matsuzawa H (2002) Angew Chem Int Ed 41: 3554

    Google Scholar 

  • For review on metals supported in silica or carbon as catalysts see: Biffis A, Zecca M, Basato M (2001) J Mol Catal A Chem 173: 249

    Google Scholar 

  • S Martínez M Meseguer L Casas E Rodríguez E Molins M Moreno-Mañas A Roig R-M Sebastián A Vallribera (2003) Tetrahedron 59 1553 Occurrence Handle10.1016/S0040-4020(03)00051-6

    Article  Google Scholar 

  • T-F Baumann G-A Fox J-H Satcher NR-F Yoshizawa M-S Dresselhaus (2002) Langmuir 18 7073 Occurrence Handle10.1021/la0259003 Occurrence Handle1:CAS:528:DC%2BD38Xlslyms7s%3D

    Article  CAS  Google Scholar 

  • S Martínez A Vallribera CL Cotet M Popovici L Martín A Roig M Moreno-Mañas E Molins (2005) New J Chem 29 1345 Occurrence Handle10.1039/b506784g

    Article  Google Scholar 

  • R Fu T-F Baumman S Cronin G Dresselhaus M-S Dresselhaus J-H Satcher SuffixJr (2005) Langmuir 21 2647 Occurrence Handle10.1021/la047344d Occurrence Handle1:CAS:528:DC%2BD2MXhsVOqsrg%3D

    Article  CAS  Google Scholar 

  • F Bonadies A Lattanzi LR Orelli S Pesci A Scettri (1993) Tetrahedron Lett 34 7649 Occurrence Handle10.1016/S0040-4039(00)60424-0 Occurrence Handle1:CAS:528:DyaK2cXisVCjurg%3D

    Article  CAS  Google Scholar 

  • S Kobayashi S Nagayama (1998) J Am Chem Soc 120 2985 Occurrence Handle10.1021/ja9739289 Occurrence Handle1:CAS:528:DyaK1cXislWhu7s%3D

    Article  CAS  Google Scholar 

  • K Hiyoshizo A Koji (1997) Tetrahedron Lett 38 7583 Occurrence Handle10.1016/S0040-4039(97)01788-7

    Article  Google Scholar 

  • T Kawabata T Mizugaki K Ebitani K Kaneda (2003) J Am Chem Soc 125 10486 Occurrence Handle10.1021/ja0302578 Occurrence Handle1:CAS:528:DC%2BD3sXmtFOls7s%3D

    Article  CAS  Google Scholar 

  • J Comelles M Moreno-Mañas E Pérez A Roglans R-M Sebastián A Vallribera (2004) J Org Chem 69 6834 Occurrence Handle10.1021/jo049373z Occurrence Handle1:CAS:528:DC%2BD2cXntVOrtLg%3D

    Article  CAS  Google Scholar 

  • H Kotsuki K Arimura T Ohishi R Maruzasa (1999) J Org Chem 64 3770 Occurrence Handle10.1021/jo982521z Occurrence Handle1:CAS:528:DyaK1MXitlKrtrY%3D

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Universitat Autònoma de Barcelona, 08193, Cerdanyola, Barcelona, Spain

    Sandra Martínez, Marcial Moreno-Mañas & Adelina Vallribera

  2. Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus de la UAB, 08193, Cerdanyola, Barcelona, Spain

    Laura Martín, Elies Molins & Anna Roig

Authors
  1. Sandra Martínez
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Laura Martín
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Elies Molins
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Marcial Moreno-Mañas
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Anna Roig
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Adelina Vallribera
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Anna Roig or Adelina Vallribera.

Additional information

Deceased on February 20, 2006

Rights and permissions

Reprints and permissions

About this article

Cite this article

Martínez, S., Martín, L., Molins, E. et al. Europium-Containing Organic Gels and Organic and Carbon Aerogels. Preparation and Initial Applications in Catalysis. Monatsh. Chem. 137, 627–633 (2006). https://doi.org/10.1007/s00706-006-0451-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-006-0451-y

Search

Navigation