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Synthesis, Structure, and Antimicrobial Activity of Complexes of Pt(II), Pd(II), and Ni(II) with the Condensation Product of 2-(Diphenylphosphino)benzaldehyde and Semioxamazide

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Summary.

Complexes of Pt(II), Pd(II), and Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and semioxamazide were synthesized, characterized, and their antimicrobial activity was evaluated. The ligand and the complexes were characterized by spectroscopic methods with the particular accent on NMR spectral analysis. For the palladium(II) complex, the crystal structure was determined by X-ray analysis. In all the complexes the ligand is coordinated as a tridentate via a P, N, O donor set. The Pd(II) and Pt(II) complexes have a square planar geometry, whereas the geometry of the Ni(II) complex is tetrahedral. The ligand showed antibacterial and antifungal activity, which was enhanced upon complexation.

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References

  • JX Gao XD Yi PP Xu CL Tang HL Wan T Ikariya (1999) J Organomet Chem 592 290 Occurrence Handle1:CAS:528:DC%2BD3cXnt1ygsw%3D%3D Occurrence Handle10.1016/S0022-328X(99)00565-3

    Article  CAS  Google Scholar 

  • J Gao P Xu X Yi C Yang H Zhang S Cheng H Wan K Tsai T Ikariya (1999) J Molec Catal A: Chemical 147 105 Occurrence Handle1:CAS:528:DyaK1MXnvVWgsb8%3D Occurrence Handle10.1016/S1381-1169(99)00135-1

    Article  CAS  Google Scholar 

  • P Pelagatti A Bacchi M Carcelli M Costa A Fochi P Ghidini E Leporati M Masi C Pellizi G Pellizi (1999) J Organomet Chem 583 94 Occurrence Handle1:CAS:528:DyaK1MXjslKisbo%3D Occurrence Handle10.1016/S0022-328X(99)00109-6

    Article  CAS  Google Scholar 

  • N Bharti SS Sharma F Naqvi A Azam (2003) Bioorg Med Chem 11 2923 Occurrence Handle1:CAS:528:DC%2BD3sXkt1OktLk%3D Occurrence Handle10.1016/S0968-0896(03)00213-X

    Article  CAS  Google Scholar 

  • DK Demertzi A Domopoulou MA Demertzis A Papageorgiou DX West (1997) Polyhedron 16 3625 Occurrence Handle10.1016/S0277-5387(97)00107-1

    Article  Google Scholar 

  • DK Demertzi A Domopoulou MA Demertzis G Valle (1997) J Inorg Biochem 68 147 Occurrence Handle10.1016/S0162-0134(97)00087-1

    Article  Google Scholar 

  • DK Demertzi MA Demertzis JR Miller C Papadopoulou C Dodorou G Filousis (2001) J Inorg Biochem 86 555 Occurrence Handle10.1016/S0162-0134(01)00224-0

    Article  Google Scholar 

  • A Bacchi M Carcelli M Costa A Fochi C Monici P Pelagatti C Pelizzi G Pelizzi LMS Roca (2000) J Organomet Chem 593–594 180 Occurrence Handle10.1016/S0022-328X(99)00519-7

    Article  Google Scholar 

  • A Bacchi M Carcelli M Costa A Leporati E Leporati P Pelagatti C Pelizzi G Pelizzi (1997) J Organomet Chem 535 107 Occurrence Handle1:CAS:528:DyaK2sXjvVehtro%3D Occurrence Handle10.1016/S0022-328X(96)06946-X

    Article  CAS  Google Scholar 

  • VM Leovac B Ribár G Argay A Kálmán I Brčeski (1996) J Coord Chem 39 11 Occurrence Handle1:CAS:528:DyaK28XltlKitbY%3D

    CAS  Google Scholar 

  • VM Leovac ID Brčeski PN Radivojša (2000) J Coord Chem 51 9

    Google Scholar 

  • I Brčeski VM Leovac GA Bogdanović SP Sovilj M Revenco (2004) Inorg Chem Comm 7 253 Occurrence Handle10.1016/j.inoche.2003.11.013

    Article  Google Scholar 

  • HO Kalinowski S Berger S Braun (1984) 13C NMR-Spektroskopie Georg Thieme Verlag Stuttgadt

    Google Scholar 

  • A Bacchi M Carcelli M Costa P Pelagatti C Pelizzi G Pelizzi (1994) Gazz Chim Ital 124 429 Occurrence Handle1:CAS:528:DyaK2MXjsVSisb8%3D

    CAS  Google Scholar 

  • A Bacchi M Carcelli M Costa A Fochi C Monici P Pelagatti C Pelizzi G Pelizzi LMS Roca (2000) J Organomet Chem 593–594 180 Occurrence Handle10.1016/S0022-328X(99)00519-7

    Article  Google Scholar 

  • D Cremer JA Pople (1975) J Am Chem Soc 97 1354 Occurrence Handle1:CAS:528:DyaE2MXhsFGis7c%3D Occurrence Handle10.1021/ja00839a011

    Article  CAS  Google Scholar 

  • a) SAINT: SAX, Area Detector Integration, Siemens Analytical instruments INC, Madison, Wisconsin, USA; b) Sheldrick G (1996) SADABS: Siemens Area Detector Absorption Correction Software, University of Goettingen, Germany

  • Altomare A, Burla MC, Camalli M, Cascarano G, Giacovazzo C, Guagliardi A, Moliterni AG, Polidori G, Spagna R (1997) Sir97: A new Program For Solving and Refining Crystal Structures, Istituto di Ricerca per lo Sviluppo di Metodologie Cristallografiche CNR, Bari

  • G Sheldrick (1997) Shelxl97 Program for structure refinement University of Goettingen Germany

    Google Scholar 

  • LJ Farrugia (1999) J Appl Cryst 32 837 Occurrence Handle10.1107/S0021889899006020

    Article  Google Scholar 

  • M Nardelli (1995) J Appl Cryst 28 659 Occurrence Handle1:CAS:528:DyaK2MXpt1ensbY%3D Occurrence Handle10.1107/S0021889895007138

    Article  CAS  Google Scholar 

  • a) Allen FH, Kennard O, Taylor R (1983) Acc Chem Res 16; 146 b) Bruno IJ, Cole JC, Edgington PR, Kessler M, Macrae CF, McCabe P, Pearson J, Taylor R (2002) Acta Cryst B58: 389

  • JN Eloff (1998) Planta Med 64 711 Occurrence Handle1:CAS:528:DyaK1MXktlOjtA%3D%3D

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Technology and Metallurgy, Belgrade, Serbia and Montenegro

    Vesna Radulović

  2. Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, University of Parma, Parma, Italy

    Alessia Bacchi & Giancarlo Pelizzi

  3. Faculty of Chemistry, University of Belgrade, Belgrade, Serbia and Montenegro

    Dušan Sladić, Ilija Brčeski & Katarina Andjelković

Authors
  1. Vesna Radulović
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  2. Alessia Bacchi
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  3. Giancarlo Pelizzi
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  4. Dušan Sladić
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  5. Ilija Brčeski
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  6. Katarina Andjelković
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Correspondence to Katarina Andjelković.

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Radulović, V., Bacchi, A., Pelizzi, G. et al. Synthesis, Structure, and Antimicrobial Activity of Complexes of Pt(II), Pd(II), and Ni(II) with the Condensation Product of 2-(Diphenylphosphino)benzaldehyde and Semioxamazide. Monatsh. Chem. 137, 681–691 (2006). https://doi.org/10.1007/s00706-005-0478-5

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  • DOI: https://doi.org/10.1007/s00706-005-0478-5

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