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Preparation and Crystal Structure of MnBiS2Br

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Summary.

Black single crystals of MnBiS2Br were obtained by the reaction of stoichiometric amounts of α-MnS, Bi, S, and BiBr3 (3:2:3:1) at 600°C for 4 weeks. The compound crystallises in the monoclinic system, space group C2/m, with a = 12.767(2), b = 3.9468(4), c = 9.574(1) Å, β = 90.87(2)°, and Z = 4. The crystal structure refinement based on 720 reflections converged at R = 0.0244 and wR2 = 0.0579, respectively. MnBiS2Br forms a layer structure consisting of MnS6 octahedra, MnS2Br4 octahedra, and BiS3+2 pyramids.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Universität Regensburg, 93040, Regensburg, Germany

    Arno Pfitzner, Manfred Zabel & Franz Rau

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  1. Arno Pfitzner
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  2. Manfred Zabel
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  3. Franz Rau
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Correspondence to Arno Pfitzner.

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Pfitzner, A., Zabel, M. & Rau, F. Preparation and Crystal Structure of MnBiS2Br. Monatsh. Chem. 136, 1977–1983 (2005). https://doi.org/10.1007/s00706-005-0373-0

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