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Study on the Kinetics of Non-isothermal Dehydration of Alkaline Earth Metal Selenites

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Summary.

The dehydration kinetics of crystallohydrates of beryllium, magnesium and calcium selenites were studied under non-isothermal conditions. The values of the activation energy of dehydration, the pre-exponential factor in Arrhenius equation and the change of entropy for the formation of the activated complex were calculated using the calculation procedure of Coats and Redfern. Thermal stability and activation energy of dehydration of the crystallohydrates were found to increase by the same order. The relationships observed were interpreted using Klopman’s generalized perturbation theory of chemical reactivity. The same theory was applied to explain the differences in the IR spectra of the selenite crystallohydrates studied.

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Authors and Affiliations

  1. Assen Zlatarov University, 8010, Bourgas, Bulgaria

    Lyubomir T. Vlaev, Maria M. Nikolova & Georgy G. Gospodinov

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  1. Lyubomir T. Vlaev
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  2. Maria M. Nikolova
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  3. Georgy G. Gospodinov
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Correspondence to Lyubomir T. Vlaev.

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Vlaev, L., Nikolova, M. & Gospodinov, G. Study on the Kinetics of Non-isothermal Dehydration of Alkaline Earth Metal Selenites. Monatsh. Chem. 136, 1553–1566 (2005). https://doi.org/10.1007/s00706-005-0352-5

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  • DOI: https://doi.org/10.1007/s00706-005-0352-5

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