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Stereoselective Synthesis of Isomers of the Naturally Occurring 13-Hydroxy-2,4,9-tetradecatrienoic Acid. Part II [1]

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Summary.

The stereoselective syntheses of four unsaturated hydroxy fatty acids 13S,2E,4E,9E)- 13-hydroxy-2,4,9-tetradecatrienoic acid, (13S,9Z,11E)-13-hydroxy-9,11-tetradecadienoic acid, (13S,9E, 11E)-13-hydroxy-9,11-tetradecadienoic acid, and (13S,2E,4E,9E)-13-hydroxy-2,4,9,11-tetradecatrienoic acid, are described. Wittig reactions, regioselective oxidation of dialcohol 3, and diastereomerization were used.

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Authors and Affiliations

  1. Institute of Pharmaceutical Chemistry and Pharmaceutical Technology, University of Graz, A-8010, Graz, Austria

    Antje Huefner & Christa Hoeller

  2. Institute of Pharmacognosy, University of Vienna, PharmaCenter Vienna, A-1090, Wien, Austria

    Gottfried Reznicek

Authors
  1. Antje Huefner
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  2. Christa Hoeller
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  3. Gottfried Reznicek
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Correspondence to Antje Huefner.

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Huefner, A., Hoeller, C. & Reznicek, G. Stereoselective Synthesis of Isomers of the Naturally Occurring 13-Hydroxy-2,4,9-tetradecatrienoic Acid. Part II [1]. Monatshefte für Chemie 135, 447–459 (2004). https://doi.org/10.1007/s00706-003-0097-y

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  • DOI: https://doi.org/10.1007/s00706-003-0097-y

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