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Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, 1H NMR, UV-Vis, and mass spectra.

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Authors and Affiliations

  1. Technical University of Istanbul, Department of Chemistry, Maslak, Istanbul, Turkey, , , , , , TR

    Ayfer Kalkan & Zehra A. Bayir

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  1. Ayfer Kalkan
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  2. Zehra A. Bayir
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Correspondence to Zehra A. Bayir.

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Kalkan, A., Bayir, Z. Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents . Monatshefte für Chemie 134, 1555–1560 (2003). https://doi.org/10.1007/s00706-003-0074-5

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  • DOI: https://doi.org/10.1007/s00706-003-0074-5

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