Summary.
Unsymmetrically substituted metal-phthalocyanines composed of three hexylthio groups and one 1-chloro-3,4-dicyano-6-[2-(2-pyridylmethylamino)phenylthio]benzene moiety was prepared by cyclization of the reactants in the presence of the anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The new unsymmetric phthalocyanines are very soluble in common organic solvents. The compounds were characterised by their elemental analyses, IR, 1H NMR, MS and UV/Vis spectra.
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Received November 27, 2002; accepted (revised) December 2, 2002 Published online May 2, 2003
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Bayır, Z., Merey, Ş. & Hamuryudan, E. Metal-Containing Phthalocyanines Substituted with One Branched Bulky Moiety and Six Alkylthio Groups. Monatshefte für Chemie 134, 1027–1031 (2003). https://doi.org/10.1007/s00706-003-0004-6
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DOI: https://doi.org/10.1007/s00706-003-0004-6