Abstract
Matrix complete dissolution combined with magnetic solid-phase extraction (MSPE) was applied to extract four benzotriazole ultraviolet stabilizers (BUVSs) from polyester curtains. Ultra-performance liquid chromatography tandem mass spectrometry was coupled to perform the content of trace BUVSs. The procedure was being developed in two steps. The polymer matrix was initially thoroughly dissolved by 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) followed by the addition of precipitant to separate the target from the dissolved polymer matrix. Next, triiron tetraoxide/biochar magnetic material was prepared and utilized as the sorbent for purification of the extract. Ultrasonic extraction coupled with the MSPE method and the proposed method was compared. Better extraction recovery of four BUVSs was acquired by the novel developed extraction method. The purification effect of the new extraction method was established by comparing the matrix effect of the polymer complete dissolution method and the polymer complete dissolution combined with the MSPE method. The extraction parameters were investigated. Under the optimized conditions, correlation coefficient (r) ranging from 0.9969 to 0.9997, limit of detection of 0.2 to 0.8 ng·g−1, and the recovery varied from 81.5 to 102.7% with RSD smaller than 10.7% were obtained for four BUVSs, respectively. This study provides a potential strategy for the efficient extraction and sensitive determination of BUVSs in polyester fibers samples.
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Chatha SAS, Asgher M, Asgher R et al (2019) Environmentally responsive and anti-bugs textile finishes—recent trends, challenges, and future perspectives [J]. Sci Total Environ 690:667–682. https://doi.org/10.1016/j.scitotenv.2019.06.520
Montesdeoca-Esponda S, Torres-Padrón ME, Sosa-Ferrera Z et al (2021) Fate and distribution of benzotriazole UV-filters and stabilizers in environmental compartments from Gran Canaria Island (Spain): a comparison study [J]. Sci Total Environ 756:144086. https://doi.org/10.1016/j.scitotenv.2020.144086
Sakuragi Y, Takada H, Sato H et al (2021) An analytical survey of benzotriazole UV-stabilizers in plastic products and their endocrine-disrupting potential via human estrogen and androgen receptors [J]. Sci Total Environ 800:149374. https://doi.org/10.1016/j.scitotenv.2021.149374
Li Q, Wang P, Wang C et al (2023) Benzotriazole UV stabilizer-induced genotoxicity in freshwater benthic clams: a survey on apoptosis, oxidative stress, histopathology and transcriptomics [J]. Sci Total Environ 857:159055. https://doi.org/10.1016/j.scitotenv.2022.159055
Li Z, Liang X, Liu W et al (2020) Elucidating mechanisms of immunotoxicity by benzotriazole ultraviolet stabilizers in zebrafish (Danio rerio): implication of the AHR-IL17/IL22 immune pathway [J]. Environ Pollut 262:114291. https://doi.org/10.1016/j.envpol.2020.114291
He T-T, Zhang T, Liu S-B et al (2019) Toxicological effects benzotriazole to the marine scallop Chlamys nobilis: a 2-month exposure study [J]. Environ Sci Pollut Res 26(10):10306–10318. https://doi.org/10.1007/s11356-019-04201-6
Liang XF, Wang M, Chen X et al (2014) Endocrine disrupting effects of benzotriazole in rare minnow (Gobiocypris rarus) in a sex-dependent manner [J]. Chemosphere 112(1):154–162. https://doi.org/10.1016/j.chemosphere.2014.03.106
Kim J-W, Isobe T, Malarvannan G et al (2012) Contamination of benzotriazole ultraviolet stabilizers in house dust from the Philippines: implications on human exposure [J]. Sci Total Environ 424:174–181. https://doi.org/10.1016/j.scitotenv.2012.02.040
International association for research and testing in the field of textile ecology, 2023. OEKO-TEX Standard 100. https://www.oeko-tex.com/. (Accessed 10 January 2023).
Rani M, Shim WJ, Han GM et al (2017) Benzotriazole-type ultraviolet stabilizers and antioxidants in plastic marine debris and their new products [J]. Sci Total Environ 579:745–754. https://doi.org/10.1016/j.scitotenv.2016.11.033
Avagyan R, Luongo G, Thorsen G et al (2015) Benzothiazole, benzotriazole, and their derivates in clothing textiles—a potential source of environmental pollutants and human exposure [J]. Environ Sci Pollut Res 22(8):5842–5849. https://doi.org/10.1007/s11356-014-3691-0
Liu WB, Xue JC, Kannan K (2017) Occurrence of and exposure to benzothiazoles and benzotriazoles from textiles and infant clothing [J]. Sci Total Environ 592:91–96. https://doi.org/10.1016/j.scitotenv.2017.03.090
Miyake Y, Tokumura M, Nakayama H et al (2017) Simultaneous determination of brominated and phosphate flame retardants in flame-retarded polyester curtains by a novel extraction method [J]. Sci Total Environ 601:1333–1339. https://doi.org/10.1016/j.scitotenv.2017.05.249
Miyake Y, Tokumura M, Wang Q et al (2018) Identification of novel phosphorus-based flame retardants in curtains purchased in Japan using orbitrap mass spectrometry [J]. Environ Sci Technol Lett 5(7):448–455. https://doi.org/10.1021/acs.estlett.8b00263
Zhou YY, Xu JB, Lu N et al (2021) Development and application of metal-organic framework@GA based on solid-phase extraction coupling with UPLC-MS/MS for the determination of five NSAIDs in water [J]. Talanta 225:121846. https://doi.org/10.1016/j.talanta.2020.121846
Qian Z, Mengdan Z, Yingying L et al (2022) Novel core–shell SiO2@dSiO2@NH2-MIL-53(Al) packed into solid phase extraction column for enrichment of non-steroidal anti-inflammatory drugs prior to UPLC-MS/MS [J]. Microchem J 183:107970. https://doi.org/10.1016/j.microc.2022.107970
Narimani-Sabegh S, Noroozian E (2019) Magnetic solid-phase extraction and determination of ultra-trace amounts of antimony in aqueous solutions using maghemite nanoparticles [J]. Food Chem 287:382–389. https://doi.org/10.1016/j.foodchem.2019.02.112
Yang D, Tammina SK, Li X et al (2019) Enhanced removal and detection of benzo[a]pyrene in environmental water samples using carbon dots-modified magnetic nanocomposites [J]. Ecotoxicol Environ Saf 170:383–390. https://doi.org/10.1016/j.ecoenv.2018.11.138
Sun RT, Lu FW, Yu CM et al (2022) Peanut shells-derived biochars as adsorbents for the pipette-tip solid-phase extraction of endocrine-disrupting phenols in water, milk and beverage [J]. J Chromatogr A 1673:463101. https://doi.org/10.1016/j.chroma.2022.463101
Zhou YW, Qin SY, Verma S et al (2021) Production and beneficial impact of biochar for environmental application: a comprehensive review [J]. Biores Technol 337:125451. https://doi.org/10.1016/j.biortech.2021.125451
Yao XX, Ji LL, Guo J et al (2020) Magnetic activated biochar nanocomposites derived from wakame and its application in methylene blue adsorption [J]. Biores Technol 302:122842. https://doi.org/10.1016/j.biortech.2020.122842
Huang YF, Peng JH, Huang XJ (2018) One-pot preparation of magnetic carbon adsorbent derived from pomelo peel for magnetic solid-phase extraction of pollutants in environmental waters [J]. J Chromatogr A 1546:28–35. https://doi.org/10.1016/j.chroma.2018.03.001
Zhang SL, Hua ZL, Yao WX et al (2021) Use of corn straw-derived biochar for magnetic solid-phase microextraction of organophosphorus pesticides from environmental samples [J]. J Chromatogr A 1660:462673. https://doi.org/10.1016/j.chroma.2021.462673
Ma JF, Chen YP, Wang H et al (2019) Traditional Chinese medicine residue act as a better fertilizer for improving soil aggregation and crop yields than manure [J]. Soil Tillage Res 195:104386. https://doi.org/10.1016/j.still.2019.104386
Liu HD, Xu GR, Li GB (2021) Preparation of porous biochar based on pharmaceutical sludge activated by NaOH and its application in the adsorption of tetracycline [J]. J Colloid Interface Sci 587:271–278. https://doi.org/10.1016/j.jcis.2020.12.014
Wang T, Zhao P, Lu N et al (2016) Facile fabrication of Fe3O4/MIL-101(Cr) for effective removal of acid red 1 and orange G from aqueous solution [J]. Chem Eng J 295:403–413. https://doi.org/10.1016/j.cej.2016.03.016
Hoteling AJ, Mourey TH, Owens KG (2005) Importance of solubility in the sample preparation of poly(ethylene terephthalate) for MALDI TOFMS [J]. Anal Chem 77(3):750–756. https://doi.org/10.1021/ac048525n
Tomczyk A, Sokołowska Z, Boguta P (2020) Biochar physicochemical properties: pyrolysis temperature and feedstock kind effects [J]. Rev Environ Sci Bio/Technol 19(1):191–215. https://doi.org/10.1007/s11157-020-09523-3
Chen WM, Wang X, Feizbakhshan M et al (2019) Preparation of lignin-based porous carbon with hierarchical oxygen-enriched structure for high-performance supercapacitors [J]. J Colloid Interface Sci 540:524–534. https://doi.org/10.1016/j.jcis.2019.01.058
Lomenech C, Hurel C, Messina L et al (2021) A humins-derived magnetic biochar for water purification by adsorption and magnetic separation [J]. Waste Biomass Valorization 12(12):6497–6512. https://doi.org/10.1007/s12649-021-01481-3
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Zhang, M., Li, Y., Zhang, S. et al. Matrix complete dissolution concatenated biochar magnetic solid-phase extraction of benzotriazole ultraviolet stabilizers in polyester fibers prior to UPLC-MS/MS analysis. Microchim Acta 190, 496 (2023). https://doi.org/10.1007/s00604-023-06074-6
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DOI: https://doi.org/10.1007/s00604-023-06074-6