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A white-light-emitting sensor array based on cucurbit[8]uril for quantitative detection of multicomponent nitroaniline isomers

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Abstract

A white-light-emitting supramolecular complex through supramolecular interactions has been assembled; the white luminescent supramolecular complex exhibits two emission spectra. Based on this, a dual-channel white-light array sensor was constructed. The results show that it can quickly identify and detect nitroaniline isomer pollutants (p-nitroaniline, m-nitroaniline, o-nitroaniline). When these three nitroaniline isomers were added to the supramolecular white-light array sensor, the fluorescence intensity of the white-light complex decreased to varying degrees. Linear discriminant analysis (LDA) showed that the supramolecular white-light array sensor could recognize and distinguish three nitroaniline isomers and could classify mixtures containing different concentrations. Factor 1 of the array had a good linear relationship with the concentration of pollutants, and the detection limit (LOD) was as low as 0.7 μM. The method has good reproducibility and stability. In addition, it can also qualitatively detect the nitroaniline isomers in river water and contaminated rice seedling extract. It provides an ideal platform for constructing multiresponse sensors.

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Data Availability

The data that supports the findings of this study are available in the supplementary material of this article. Data available on request.

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Funding

We thank the National Natural Science Foundation of China (No. 22061009) and the Natural Science Foundation of the Science and Technology Department of Guizhou Province (Grant No. ZK-2021–024) for financial support.

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Authors and Affiliations

  1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang, 550025, China

    Shu-Zhen Huang, Kai-Ni Wei, Ru-Pei Yang & Zhu Tao

  2. School of Pharmaceutical Sciences, Guizhou University, Guiyang, 550025, China

    Hong-Ling Yi

  3. Department College of Tobacco Science, Guizhou University, Guiyang, 550025, China

    Qing Tang

  4. The Engineering and Research Center for Southwest Bio-Pharmaceutical Resources of National Education Ministry of China, Guizhou University, Guiyang, 550025, China

    Ying Huang

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  1. Shu-Zhen Huang
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  5. Qing Tang
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Contributions

Shu-Zhen Huang: conceptualization, formal analysis, investigation, methodology, visualization, validation, writing–original draft. Kai-Ni Wei: conceptualization, formal analysis, visualization. Ru-Pei Yang: performing cultivation and extraction of rice seedlings. Hong-Ling Yi: performing the anti-interference experiment. Qing Tang: formal analysis, resources, data curation, methodology. Zhu Tao: term, conceptualization, methodology, supervision, project administration. Ying Huang: term, conceptualization, methodology, supervision, funding acquisition, project administration, writing–review and editing.

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Correspondence to Ying Huang.

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Huang, SZ., Wei, KN., Yang, RP. et al. A white-light-emitting sensor array based on cucurbit[8]uril for quantitative detection of multicomponent nitroaniline isomers. Microchim Acta 190, 460 (2023). https://doi.org/10.1007/s00604-023-06040-2

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