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Electrospun nanofibers containing CdTe@ZnNi-MOF for electrochemiluminescent determination of chlorpyrifos

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Abstract

Electrospun nanofibers containing CdTe@ZnNi-metal–organic frameworks (CdTe@ZnNi-MOF NFs) were used for the first time in luminol-O2 electrochemiluminescence (ECL) system to construct ECL sensor for chlorpyrifos (CPF) detection. Firstly, CdTe@ZnNi-MOF NFs obtained by blending method was used to modify the surface of a glassy carbon electrode, and then, the proposed solid-state ECL sensor was constructed by dropping luminol onto the surface of nanofiber benefiting from chitosan (CTS) viscosity. CdTe@ZnNi-MOF NFs with its large surface area and porosity can be used not only as luminol carrier but also as co-reaction promoter of the ECL system. The ECL sensor obtained satisfactory results in weakly alkaline solution under the synergistic action of CdTe@ZnNi-MOF NFs and luminol. The constructed ECL sensor can effectively detect CPF in the range 1.0 × 10−14–1.0 × 10−9 M, and the detection limit was 6.23 × 10−17 M (3σ/m). The constructed sensor was simple and sensitive, and can be used for the determination of CPF in vegetable samples. It not only broadened the application of MOFs in the field of ECL but also provided a new idea for expanding the application of the luminol-O2 system.

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Funding

We received financial support from the Graduate Innovation Project of ChangChun Normal University (No.2022–014).

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Authors and Affiliations

  1. College of Chemistry, Changchun Normal University, Changchun, 130032, People’s Republic of China

    Zhuo Sun, Juan Lu, Xin Zhang, Xiangyu Shan, Qian Wu, Chao Li, Huiling Li, Shuning Yang & Li Tian

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  1. Zhuo Sun
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  2. Juan Lu
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  3. Xin Zhang
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  4. Xiangyu Shan
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  5. Qian Wu
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  9. Li Tian
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Contributions

Zhuo Sun: supervision, visualization, conceptualization, formal analysis, investigation, writing — original draft. Juan Lu: methodology, data curation, visualization, conceptualization, formal analysis, investigation, writing — original draft, writing — review and editing. Xin Zhang: methodology, data curation, formal analysis, investigation, writing — review and editing. Xiangyu Shan: funding acquisition, project administration, supervision, conceptualization, investigation. Qian Wu: project administration, funding acquisition, resources, ssupervision, formal analysis. Chao Li: project administration, formal analysis, supervision, visualization, conceptualization. Huiling Li: formal analysis, project administration, visualization, supervision, conceptualization. Shuning Yang: formal analysis, project administration, visualization, conceptualization. Li Tian: resources, supervision, project administration, funding acquisition, conceptualization, formal analysis.

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Correspondence to Juan Lu or Li Tian.

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Sun, Z., Lu, J., Zhang, X. et al. Electrospun nanofibers containing CdTe@ZnNi-MOF for electrochemiluminescent determination of chlorpyrifos. Microchim Acta 189, 473 (2022). https://doi.org/10.1007/s00604-022-05574-1

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