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Porphyrin based porous organic polymer modified with Fe3O4 nanoparticles as an efficient adsorbent for the enrichment of benzoylurea insecticides

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Abstract

Porphyrin-based porous organic polymers (P-POPs) are amorphous polymers linked by strong covalent bonds between the porphyrin subunits that act as building blocks. The authors describe a magnetic P-POP that possesses high surface area, a highly porous structure, and strong magnetism. The MP-POP was employed as a magnetic sorbent for the extraction of benzoylurea insecticides from cucumber and tomato samples prior to their determination by HPLC. The sorbent has a typical sorption capacity of 1.90–2.00 mg∙g−1. The method exhibits a good linear range (0.8–160 ng·g−1), low limits of detection (0.08–0.2 ng·g−1), and high method recoveries (81.8–103.5%) for cucumber and tomato samples. The MP-POP has different adsorption capabilities for the benzoylurea insecticides, phenylurea herbicides and phenols compounds, and the adsorption mechanism is found to be based on π-stacking, hydrogen-bonding, and hydrophobic interactions.

A novel magnetic porphyrin-based porous organic polymer was fabricated and used as the adsorbent for the efficient extraction of benzoylurea insecticides.

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Acknowledgements

This study was funded by the National Natural Science Foundation of China (31471643, 31571925, and 31671930), and the Hebei “Double First Class Discipline” Construction Foundation for the Discipline of Food Science and Engineering of Hebei Agricultural University (2016SPGCA18), the Natural Science Foundation of Hebei Provinces (B2016204136, B2016204146, B2017204025), and the Scientific and Technological Research Foundation of the Department of Education of Hebei Province (ZD2016085).

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  1. Juntao Wang and Caina Jiao contributed equally to this work.

Authors and Affiliations

  1. College of Food Science and Technology, Hebei Agricultural University, Baoding, 071001, China

    Juntao Wang, Qiuhua Wu & Zhi Wang

  2. College of Science, Hebei Agricultural University, Baoding, Hebei, 071001, China

    Caina Jiao, Menghua Li, Xiaolan Wang, Chun Wang, Qiuhua Wu & Zhi Wang

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  1. Juntao Wang
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  2. Caina Jiao
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  3. Menghua Li
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  4. Xiaolan Wang
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  7. Zhi Wang
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Correspondence to Chun Wang or Zhi Wang.

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Wang, J., Jiao, C., Li, M. et al. Porphyrin based porous organic polymer modified with Fe3O4 nanoparticles as an efficient adsorbent for the enrichment of benzoylurea insecticides. Microchim Acta 185, 36 (2018). https://doi.org/10.1007/s00604-017-2542-3

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