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Double-charged ionic liquid-functionalized layered double hydroxide nanomaterial as a new fiber coating for solid-phase microextraction of phenols

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Abstract

Double-charged diazabicyclo[2.2.2]octane (DABCO) was immobilized on the inner surface of a nanomaterial composed of the layered double hydroxides (LDHs) of Zn(II) and Cr(III). The resulting material was characterized by SEM, FT-IR and XRD techniques. This novel nanocomposite has been used as a highly porous fiber coating for solid-phase microextraction (SPME) of phenol and various chloro-, nitro- and aminophenols. The LDH nanocomposite was deposited on a stainless steel wire and then evaluated with respect to the extraction of phenolic compounds from water samples. The effects of temperature, extraction time, ionic strength, stirring rate, pH, and desorption temperature and time on the extraction were optimized. The compounds were then separated and quantified by GC-MS. Under optimum conditions, the repeatability for a single fiber (for n = 3 and expressed as the relative standard deviation) is between 2.3 and 7.2 %. The detection limits are between 0.02 and 6.3 pg mL−1. The method is simple, rapid, and inexpensive. The fiber is thermally stable and its use gives high recoveries.

Double-charged diazabicyclo[2.2.2]octane (DABCO) was immobilized on the inner surface of a nanomaterial composed of the layered double hydroxides (LDHs) of Zn(II) and Cr(III). This novel nanocomposite has been used as a highly porous fiber coating for solid-phase microextraction (SPME) of phenol and various chloro-, nitro- and aminophenols.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, 55181-83111, Iran

    Mir Mahdi Abolghasemi & Vahid Yousefi

  2. Research Center for Pharmaceutical Nanotechnology, Tabriz University of Medical Sciences, Tabriz, Iran

    Marzieh Piryaei

  3. Faculty of Pharmacy, Tabriz University of Medical Sciences, Tabriz, Iran

    Marzieh Piryaei

Authors
  1. Mir Mahdi Abolghasemi
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  2. Vahid Yousefi
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  3. Marzieh Piryaei
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Correspondence to Mir Mahdi Abolghasemi.

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Abolghasemi, M.M., Yousefi, V. & Piryaei, M. Double-charged ionic liquid-functionalized layered double hydroxide nanomaterial as a new fiber coating for solid-phase microextraction of phenols. Microchim Acta 182, 2155–2164 (2015). https://doi.org/10.1007/s00604-015-1553-1

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