Skip to main content
SpringerLink
Log in

Dipyridylamine-modified nanoporous silicas as new sorbents for the separation and pre-concentration of palladium

  • Original Paper
  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

Nanoporous silicas of the type SBA-15 (Santa Barbara Amorphous) and MCM-48 (Mobile Composition of Material) were modified with dipyridylamine (dipy) and used as solid phases for the extraction of Pd(II) ions. The experimental conditions (pH, sample and eluent flow rates, type and quantity of eluent) were optimized. The recovery values were ~ 99.7 and ~ 93.4% for dipy-MCM-48 and dipy-SBA-15, respectively, the limits of detection were <0.08 and <0.11 ng L−1, the pre-concentration factors were 725 and 550, and the adsorption capacity was >78 mg g−1. The procedure was applied to the preconcentration of Pd(II) in real samples.

Nanoporous silicas of the type SBA-15 and MCM-48 were modified with dipyridylamine and used as solid-phase for the extraction of Pd(II) ions. The experimental conditions were optimized and the recovery values were determined. The procedure was applied to the pre-concentration of Pd(II) in real samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Sari A, Mendil D, Tuzen M, Soylak M (2009) Biosorption of palladium(II) from aqueous solution by moss (Racomitrium lanuginosum) biomass: Equilibrium, kinetic and thermodynamic studies. J Hazard Mater 162:874

    Article  CAS  Google Scholar 

  2. Yoshida H, Nakajima T, Yazawa Y, Hattori T (2007) Support effect on methane combustion over palladium catalysts. Appl Catal B 71:70

    Article  CAS  Google Scholar 

  3. Tripodia P, Gioacchinob D, Darja Vinko J (2009) AC electrical resistance measurements of Pd samples versus composition. J Alloy Compd 486:55

    Article  Google Scholar 

  4. Doucet H, Hierso J (2007) Palladium coupling catalysts for pharmaceutical applications. Curr Opin Endocrinol Diab 10:672

    CAS  Google Scholar 

  5. Edmiston Ch, Goheen MP, Seabrook GR, Johnson Ch, Lewis B, Brown KR, Towne JB (2006) Impact of selective antimicrobial agents on staphylococcal adherence to biomedical devices. Am J Surg 192:344

    Article  CAS  Google Scholar 

  6. Zhu Y, Khan Z, Masel RI (2005) The behavior of palladium catalysts in direct formic acid fuel cells (205). J Power Sources 139:15

    Article  CAS  Google Scholar 

  7. Hooda PS, Miller A, Edwards AC (2007) The distribution of automobile catalysts cast platinum, palladium and rhodium in soils adjacent to roads and their uptake by grass. Sci Total Environ 374:384

    Google Scholar 

  8. Sures B, Zimmermann S (2007) Impact of humic substances on the aqueous solubility, uptake and bioaccumulation of platinum, palladium and rhodium in exposure studies with Dreissena polymorpha. Environ Pollut 146:444

    Article  CAS  Google Scholar 

  9. Shemirani F, Rahnama Kozani R, Jamali MR, Assadi Y, Milani Hosseini MR (2006) Cloud-point extraction, preconcentration, and spectrophotometric determination of palladium in water samples. Int J Environ Anal Chem 86:1105

    Article  CAS  Google Scholar 

  10. Wataha JC, Hanks CT (1996) Biological effects of palladium and risk of using palladium in dental casting alloys. J Oral Rehabil 23:309

    Article  CAS  Google Scholar 

  11. Tokalioğlul S, Yılmaz V, Kartal S, Delibaş A, Soykan C (2009) Solid phase extraction of Pd(II) on a newly synthesized chelating resin prior to determination by flame atomic absorption spectrometry. Microchim Acta 165:347

    Article  Google Scholar 

  12. Jamali MR, Assadi Y, Shemirani F, Salavati-Niasari M (2007) Application of thiophene-2-carbaldehyde-modified mesoporous silica as a new sorbent for separation and preconcentration of palladium prior to inductively coupled plasma atomic emission spectrometric determination. Talanta 71:1524

    Article  CAS  Google Scholar 

  13. Mohamadi M, Mostafavi A (2010) A novel solidified floating organic drop microextraction based on ultrasound-dispersion for separation and preconcentration of palladium in aqueous samples. Talanta 81:309

    Article  CAS  Google Scholar 

  14. Soylak M, Nilgun DE (2006) Copper(II)–rubeanic acid coprecipitation system for separation–preconcentration of trace metal ions in environmental samples for their flame atomic absorption spectrometric determinations. J Hazard Mater 137:1035

    Article  CAS  Google Scholar 

  15. Oguria K, Shimodab G, Tatsumi Y (1999) Quantitative determination of gold and the platinum-group elements in geological samples using improved NiS fire-assay and tellurium coprecipitation with inductively coupled plasma-mass spectrometry (ICP-MS). Chem Geol 157:189

    Article  Google Scholar 

  16. Pearson DG, Woodland SJ (2000) Solvent extraction/anion exchange separation and determination of PGEs (Os, Ir, Pt, Pd, Ru) and Re–Os isotopes in geological samples by isotope dilution ICP-MS. Chem Geol 165:87

    Article  CAS  Google Scholar 

  17. Igarashi Sh, Ide N, Takagai Y (2000) High-performance liquid chromatographic–spectrophotometric determination of copper(II) and palladium(II) with 5,10,15,20-tetrakis(4 N-pyridyl)porphine following homogeneous liquid–liquid extraction in the water–acetic acid–chloroform ternary solvent system. Anal Chim Acta 424:263

    Article  CAS  Google Scholar 

  18. Philippeit G, Angerer J (2001) Determination of palladium in human urine by high-performance liquid chromatography and ultraviolet detection after ultraviolet photolysis and selective solid-phase extraction. J Chromatogr B 760:237

    Article  CAS  Google Scholar 

  19. Fang J, Jiang Y, Yan XP (2005) Selective quantification of trace palladium in road dusts and roadside soils by displacement solid-phase extraction online coupled with electrothermal atomic absorption spectrometry. Environ Sci Technol 39:288

    Article  CAS  Google Scholar 

  20. Pyrzynska K (1998) Recent advances in solid-phase extraction of platinum and palladium. Talanta 47:841

    Article  CAS  Google Scholar 

  21. Anitha Mary T, Murty DSR (2008) Solid phase extraction and preconcentration of gold, palladium, and silver on chitin for their determination in silicate rocks by Flame Atomic Absorption Spectrometry. At Spectrosc 29:69

    Google Scholar 

  22. Armenta S, Garrigues S, dela Guardia M (2008) Green analytical chemistry. TrAC Trends Anal Chem 27:497

    Article  CAS  Google Scholar 

  23. Venkatesh G, Singh AK (2007) Enrichment and flame atomic absorption spectrometric determination of palladium using chelating matrices designed by functionalizing Amberlite XAD-2/16 and silica gel. Microchim Acta 159:149

    Article  CAS  Google Scholar 

  24. Moawed EA (2006) Preparation of novel ion exchange polyurethane foam and its application for separation and determination of palladium in environmental samples. Anal Chim Acta 580:263

    Article  CAS  Google Scholar 

  25. Tavallali H, Yazdandoust S, Yazdandoust M (2010) Cloud point extraction for the preconcentration of silver and palladium in real samples and determination by Atomic Absorption Spectrometry. Clean Soil Air Water 38:242

    Article  CAS  Google Scholar 

  26. Zheng H, Zhang D, Wang WY, Fan YQ, Li J, Han HP (2007) Highly selective determination of palladium(II) after preconcentration using Pd(II)-imprinted functionalized silica gel sorbent prepared by a surface imprinting technique. Microchim Acta 157:7

    Article  CAS  Google Scholar 

  27. Yousefi R, Shemirani F, Jamali MR, Salavati-Niasari M (2010) Extraction and preconcentration of ultra trace amounts of beryllium from aqueous samples by nanometer mesoporous silica functionalized by 2,4-dihydroxybenzaldehyde prior to ICP OES determination. Microchim Acta 169:241

    Article  CAS  Google Scholar 

  28. Guliants VV, Carreon MA, Lin YS (2004) Ordered mesoporous and macroporous inorganic films and membranes. J Membr Sci 235:53

    Article  CAS  Google Scholar 

  29. Hartmann M, Bischof Ch (1999) Mechanical Stability of Mesoporous Molecular Sieve MCM-48 Studied by Adsorption of Benzene, n-Heptane, and Cyclohexane. J Phys Chem B 103:6230

    Article  CAS  Google Scholar 

  30. Zhao D, Huo Q, Feng J, Chmelka B, Stucky G (1998) Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures. J Am Chem Soc 120:6024

    Article  CAS  Google Scholar 

  31. Johnson JS, Stein A (2001) Surface Modification of Mesoporous, Macroporous, and Amorphous Silica with Catalytically Active Polyoxometalate Clusters. Inorg Chem 40:801

    Article  CAS  Google Scholar 

  32. Pirouzmand M, Amini MM, Safari N (2008) Immobilization of iron tetrasulfophthalocyanine on functionalized MCM-48 and MCM-41 mesoporous silicas: catalysts for oxidation of styrene. J Colloid Interface Sci 319:199

    Article  CAS  Google Scholar 

  33. Daniel S, Rao PP, Rao TP (2005) Investigation of different polymerization methods on the analytical performance of palladium(II) ion imprinted polymer materials. Anal Chim Acta 536:197

    Article  CAS  Google Scholar 

  34. Ebrahimzadeh H, Tavassoli M, Amini MM, Fazaeli Y, Abedi H (2010) Determination of very low levels of gold and palladium in wastewater and soil samples by atomic absorption after preconcentration on modified MCM-48 and MCM-41 silica. Talanta 81:1183

    Article  CAS  Google Scholar 

  35. Ghaedi M, Shokrollahi A, Niknam Kh, Niknam E, Najibi A, Soylak M (2009) Cloud point extraction and flame atomic absorption spectrometric determination of cadmium(II), lead(II), palladium(II) and silver(I) in environmental samples. J Hazard Mater 168:1022

    Article  CAS  Google Scholar 

  36. Tavakoli L, Yamini Y, Ebrahimzadeh H, Nezhadali A, Nourmohammadian F (2008) Development of cloud point extraction for simultaneous extraction and determination of gold and palladium using ICP-OES. J Hazard Mater 152:737

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Islamic Azad University, Science and Research Branch, Tehran, Iran

    Kheyrollah Mehrani

  2. Department of Chemistry, Tarbiat Modarres University, Tehran, Iran

    Azadeh Mehrani

  3. Department of Chemistry, Shahid Beheshti University, G.C., Evin, Tehran, Iran

    Mostafa M. Amini, Omid Sadeghi & Najmeh Tavassoli

Authors
  1. Kheyrollah Mehrani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Azadeh Mehrani
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mostafa M. Amini
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Omid Sadeghi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Najmeh Tavassoli
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mostafa M. Amini.

Electronic supplementary materials

Below is the link to the electronic supplementary material.

ESM 1

(DOC 84 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mehrani, K., Mehrani, A., Amini, M.M. et al. Dipyridylamine-modified nanoporous silicas as new sorbents for the separation and pre-concentration of palladium. Microchim Acta 173, 521–527 (2011). https://doi.org/10.1007/s00604-011-0590-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00604-011-0590-7

Keywords

Search

Navigation