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Electrodeposition of monodispersed platinum nanoparticles on a glassy carbon electrode for sensing methanol

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Abstract

A facile, one-step and template-free method has been developed for the electrodeposition of well-dispersed platinum nanoparticles (Pt-NPs) on a glassy carbon electrode. The effects of various inorganic anions and overpotential on the morphologies and dimensions of the final products were investigated. The resulting Pt-NPs show high electrocatalytic activity towards methanol oxidation and are less easily poisoned by carbon monoxide.

In this study, we have developed a simple, environmentally benign, controllable, and template-free method for the electrodeposition of monodispersed Pt NPs on a glassy carbon electrode. The resulting Pt NPs display high catalytic activity towards methanol oxidation, and are less easily poisoned by carbon monoxide.

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References

  1. Feng JJ, Gernert U, Sezer M, Kuhlmann U, Murgida DH, David C, Richter M, Knorr A, Hildebrandt P, Weidinger IM (2008) Novel Au–Ag hybrid device for electrochemical SE(R)R spectroscopy in a wide potential and spectral range. Nano Lett 9:298

    Article  Google Scholar 

  2. Feng JJ, Gernert U, Hildebrandt P, Weidinger IM (2010) Induced SER-activity in nanostructured Ag–silica–Au supports via long-range plasmon coupling. Adv Funct Mater 20:1954

    Article  CAS  Google Scholar 

  3. Feng JJ, Lu YH, Gernert U, Hildebrandt P, Murgida DH (2010) Electrosynthesis of SER-active silver nanopillar electrode arrays. J Phys Chem C 114:7280

    Article  CAS  Google Scholar 

  4. Xia YN, Xiong YJ, Lim B, Skrabalak SE (2009) Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? Angew Chem Int Ed 48:60

    Article  CAS  Google Scholar 

  5. Wiley B, Sun YG, Xia YN (2007) Synthesis of silver nanostructures with controlled shapes and properties. Acc Chem Res 40:1067

    Article  CAS  Google Scholar 

  6. Fang YM, Lin ZB, Zeng YM, Chen WK, Chen GN, Sun JJ, Ren B, Tian ZQ (2010) Facile electrochemical preparation of Ag Nanothorns and their growth mechanism. Chem Eur J 16:6766

    Article  CAS  Google Scholar 

  7. Sun YG, Xia YN (2002) Shape-controlled synthesis of gold and silver nanoparticles. Science 298:2176

    Article  CAS  Google Scholar 

  8. Narayanan R, El-Sayed MA (2004) Shape-dependent catalytic activity of platinum nanoparticles in colloidal solution. Nano Lett 4:1343

    Article  CAS  Google Scholar 

  9. Liu HS, Song CJ, Zhang L, Zhang JJ, Wang HJ, Wilkinson DP (2006) A review of anode catalysis in the direct methanol fuel cell. J Power Sources 155:95

    CAS  Google Scholar 

  10. Yu XW, Pickup PG (2008) Recent advances in direct formic acid fuel cells (DFAFC). J Power Sources 182:124

    Article  CAS  Google Scholar 

  11. Antolini E (2007) Catalysts for direct ethanol fuel cells. J Power Sources 170:1

    Article  CAS  Google Scholar 

  12. Lee H, Habas SE, Kweskin S, Butcher D, Somorjai GA, Yang P (2006) Morphological control of catalytically active platinum nanocrystals. Angew Chem Int Ed 45:7824

    Article  CAS  Google Scholar 

  13. Ahmadi TS, Wang ZL, Green TC, Henglein A, El-Sayed MA (1996) Shape-controlled synthesis of colloidal platinum nanoparticles. Science 272:1924

    Article  CAS  Google Scholar 

  14. Hu XG, Wang T, Dong SJ (2006) Rapid synthesis of cubic Pt nanoparticles and their use for the preparation of Pt nanoagglomerates. J Nanosci Nanotechnol 6:2056

    Article  CAS  Google Scholar 

  15. Wang C, Daimon H, Lee Y, Kim J, Sun SH (2007) Synthesis of monodisperse pt Nanocubes and their enhanced catalysis for oxygen reduction. J Am Chem Soc 129:6974

    Article  CAS  Google Scholar 

  16. Chen JY, Herricks T, Geissler M, Xia YN (2004) Single-crystal Nanowires of platinum can be synthesized by controlling the reaction rate of a polyol process. J Am Chem Soc 126:10854

    Article  CAS  Google Scholar 

  17. Kijima T, Yoshimura T, Uota M, Ikeda T, Fujikawa D, Mouri S, Uoyama S (2004) Noble-metal nanotubes (Pt, Pd, Ag) from lyotropic mixed-surfactant liquid-crystal templates. Angew Chem Int Ed 43:228

    Article  CAS  Google Scholar 

  18. Teng XW, Yang H (2005) Synthesis of platinum multipods: an induced anisotropic growth. Nano Lett 5:885

    Article  CAS  Google Scholar 

  19. Chen JY, Herricks T, Xia YN (2005) Polyol synthesis of platinum nanostructures: control of morphology through the manipulation of reduction kinetics. Angew Chem Int Ed 44:2589

    Article  CAS  Google Scholar 

  20. Lee EP, Peng ZM, Cate DM, Yang H, Campbell CT, Xia YN (2007) Growing Pt nanowires as a densely packed array on metal gauze. J Am Chem Soc 129:10634

    Article  CAS  Google Scholar 

  21. Narayanan R, El-Sayed MA (2005) Effect of colloidal nanocatalysis on the metallic nanoparticle shape: the suzuki reaction. Langmuir 21:2027

    Article  CAS  Google Scholar 

  22. Narayanan R, Tabor C, El-Sayed M (2008) Can the observed changes in the size or shape of a colloidal nanocatalyst reveal the nanocatalysis mechanism type: homogeneous or heterogeneous? Top Catal 48:60

    Article  CAS  Google Scholar 

  23. Mahmoud TCE, El-Sayed MA, Ding Y, Wang ZL (2008) A new catalytically active colloidal platinum nanocatalyst: the multiarmed nanostar single crystal. J Am Chem Soc 130:4590

    Article  CAS  Google Scholar 

  24. Tian N, Zhou ZY, Sun SG, Ding Y, Wang ZL (2007) Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity. Science 316:732

    Article  CAS  Google Scholar 

  25. Liang ZX, Zhao TS (2007) New DMFC anode structure consisting of platinum nanowires deposited into a nafion membrane. J Phys Chem C 111:8128

    Article  CAS  Google Scholar 

  26. Wasmus S, Kuver A (1999) Methanol oxidation and direct methanol fuel cells: a selective review. J Electroanal Chem 461:14

    Article  CAS  Google Scholar 

  27. Liu JY, Cao JY, Huang QH, Li XW, Zou ZQ, Yang H (2008) Methanol oxidation on carbon-supported Pt–Ru–Ni ternary nanoparticle electrocatalysts. J Power Sources 175:159

    Article  CAS  Google Scholar 

  28. Lee JK, Choi J, Kang SJ, Lee JM, Tak Y, Lee J (2007) Influence of copper oxide modification of a platinum cathode on the activity of direct methanol fuel cell. Electrochim Acta 52:2272

    Article  CAS  Google Scholar 

  29. Lee EP, Peng ZM, Chen W, Chen SW, Yang H, Xia YN (2008) Electrocatalytic properties of Pt nanowires supported on Pt and W gauzes. ACS Nano 2:2167

    Article  CAS  Google Scholar 

  30. Yin J, Jia JB, Zhu LD (2009) Double-template synthesis of platinum nanomaterials for oxygen reduction. Microchim Acta 166:151

    Article  CAS  Google Scholar 

  31. Yang B, Wang SQ, Tian SB, Liu LZ (2009) Determination of hydrogen sulfide in gasoline by Au nanoclusters modified glassy carbon electrode. Electrochem Commun 11:1230

    Article  CAS  Google Scholar 

  32. Kawasaki H, Yonezawa T, Watanabe T, Arakawa R (2007) Platinum nanoflowers for surface-assisted laser desorption/ionization mass spectrometry of biomolecules. J Phys Chem C 111:16278

    Article  CAS  Google Scholar 

  33. Jana S, Pande S, Sinha AK, Sarkar S, Pradhan M, Basu M, Saha S, Pal T (2009) A green chemistry approach for the synthesis of flower-like Ag-doped MnO2 nanostructures probed by surface-enhanced Raman spectroscopy. J Phys Chem C 113:1386

    Article  CAS  Google Scholar 

  34. Liu QY, Guo XH, Li Y, Shen WJ (2009) Hierarchical growth of Co nanoflowers composed of nanorods in polyol. J Phys Chem C 113:3436

    Article  CAS  Google Scholar 

  35. Qian L, Yang XR (2006) Polyamidoamine dendrimers-assisted electrodeposition of gold-platinum bimetallic nanoflowers. J Phys Chem B 110:16672

    Article  CAS  Google Scholar 

  36. Domı’nguez-Crespo MA, Ramı’ez-Meneses E, Montiel-Palma V, Torres HAM, Dorantes RH (2009) Synthesis and electrochemical characterization of stabilized nickel nanoparticles. Int J Hydrogen Energy 34:1664

    Article  Google Scholar 

  37. Xie JP, Zhang QB, Lee JY, Wang DIC (2008) The synthesis of SERS-active gold nanoflower tags for in vivo applications. ACS Nano 2:2473

    Article  CAS  Google Scholar 

  38. Jia JB, Cao LY, Wang ZH (2008) Platinum-coated gold nanoporous film surface: electrodeposition and enhanced electrocatalytic activity for methanol oxidation. Langmuir 24:5932

    Article  CAS  Google Scholar 

  39. Finot MO, Braybrook GD, McDermott MT (1999) Characterization of electrochemically deposited gold nanocrystals on glassy carbon electrodes. J Electroanal Chem 466:234

    Article  CAS  Google Scholar 

  40. Schmidt U, Donten M, Osteryoung JG (1997) Gold electrocrystallization on carbon and highly oriented pyrolytic graphite from concentrated solutions of LiCl. J Electrochem Soc 114:2013

    Article  Google Scholar 

  41. El-Deab MS (2009) On the preferential crystallographic orientation of Au nanoparticles: effect of electrodeposition time. Electrochim Acta 54:3720

    Article  CAS  Google Scholar 

  42. Gunawardena G, Hills G, Montenegro I, Scharifker B (1982) Electrochemical nucleation. Part I. General considerations. J Electroanal Chem 138:225

    Article  CAS  Google Scholar 

  43. Du Y, Xu JJ, Chen HY (2009) Ultrathin platinum film covered high-surface-area nanoporous gold for methanol electro-oxidation. Electrochem Commun 11:1717

    Article  CAS  Google Scholar 

  44. Jiang H, Geng B, Kuai L, Wang S (2011) Simultaneous reduction-etching route to Pt/ZnSnO3 hollow polyhedral architectures for methanol electrooxidation in alkaline media with superior performance. Chem Commun ASAP

  45. Zhang JT, Liu PP, Ma HY, Ding Y (2007) Nanostructured porous gold for methanol electro-oxidation. J Phys Chem C 111:10382

    Article  CAS  Google Scholar 

  46. Li YX, Chen YL, Xian HY, Zhou Y, Wang L (2010) Cysteamine monolayer inducing the formation of platinum nanoclusters for methanol electrocatalytic oxidation. Microchim Acta 169:93

    Article  CAS  Google Scholar 

  47. Ye JS, Cui HF, Wen Y, Zhang WD, Xu GQ, Sheu FS (2006) Electrodeposition of platinum nanoparticles on multi-walled carbon nanotubes for electrocatalytic oxidation of methanol. Microchim Acta 152:267

    Article  CAS  Google Scholar 

  48. Wen Y, Ye JS, Zhang WD, Sheu FS, Xu GQ (2008) Electrocatalytic oxidation of methanol on a platinum modified carbon nanotube electrode. Microchim Acta 162:235

    Article  CAS  Google Scholar 

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Acknowledgements

This work was financially supported by the Natural Science Foundation of China (Nos. 20805011, 20905021).

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Correspondence to Jiu-Ju Feng.

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Feng, JJ., Li, AQ., Wang, AJ. et al. Electrodeposition of monodispersed platinum nanoparticles on a glassy carbon electrode for sensing methanol. Microchim Acta 173, 383–389 (2011). https://doi.org/10.1007/s00604-011-0566-7

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  • DOI: https://doi.org/10.1007/s00604-011-0566-7

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