Abstract
A facile, one-step and template-free method has been developed for the electrodeposition of well-dispersed platinum nanoparticles (Pt-NPs) on a glassy carbon electrode. The effects of various inorganic anions and overpotential on the morphologies and dimensions of the final products were investigated. The resulting Pt-NPs show high electrocatalytic activity towards methanol oxidation and are less easily poisoned by carbon monoxide.
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Feng JJ, Gernert U, Sezer M, Kuhlmann U, Murgida DH, David C, Richter M, Knorr A, Hildebrandt P, Weidinger IM (2008) Novel Au–Ag hybrid device for electrochemical SE(R)R spectroscopy in a wide potential and spectral range. Nano Lett 9:298
Feng JJ, Gernert U, Hildebrandt P, Weidinger IM (2010) Induced SER-activity in nanostructured Ag–silica–Au supports via long-range plasmon coupling. Adv Funct Mater 20:1954
Feng JJ, Lu YH, Gernert U, Hildebrandt P, Murgida DH (2010) Electrosynthesis of SER-active silver nanopillar electrode arrays. J Phys Chem C 114:7280
Xia YN, Xiong YJ, Lim B, Skrabalak SE (2009) Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? Angew Chem Int Ed 48:60
Wiley B, Sun YG, Xia YN (2007) Synthesis of silver nanostructures with controlled shapes and properties. Acc Chem Res 40:1067
Fang YM, Lin ZB, Zeng YM, Chen WK, Chen GN, Sun JJ, Ren B, Tian ZQ (2010) Facile electrochemical preparation of Ag Nanothorns and their growth mechanism. Chem Eur J 16:6766
Sun YG, Xia YN (2002) Shape-controlled synthesis of gold and silver nanoparticles. Science 298:2176
Narayanan R, El-Sayed MA (2004) Shape-dependent catalytic activity of platinum nanoparticles in colloidal solution. Nano Lett 4:1343
Liu HS, Song CJ, Zhang L, Zhang JJ, Wang HJ, Wilkinson DP (2006) A review of anode catalysis in the direct methanol fuel cell. J Power Sources 155:95
Yu XW, Pickup PG (2008) Recent advances in direct formic acid fuel cells (DFAFC). J Power Sources 182:124
Antolini E (2007) Catalysts for direct ethanol fuel cells. J Power Sources 170:1
Lee H, Habas SE, Kweskin S, Butcher D, Somorjai GA, Yang P (2006) Morphological control of catalytically active platinum nanocrystals. Angew Chem Int Ed 45:7824
Ahmadi TS, Wang ZL, Green TC, Henglein A, El-Sayed MA (1996) Shape-controlled synthesis of colloidal platinum nanoparticles. Science 272:1924
Hu XG, Wang T, Dong SJ (2006) Rapid synthesis of cubic Pt nanoparticles and their use for the preparation of Pt nanoagglomerates. J Nanosci Nanotechnol 6:2056
Wang C, Daimon H, Lee Y, Kim J, Sun SH (2007) Synthesis of monodisperse pt Nanocubes and their enhanced catalysis for oxygen reduction. J Am Chem Soc 129:6974
Chen JY, Herricks T, Geissler M, Xia YN (2004) Single-crystal Nanowires of platinum can be synthesized by controlling the reaction rate of a polyol process. J Am Chem Soc 126:10854
Kijima T, Yoshimura T, Uota M, Ikeda T, Fujikawa D, Mouri S, Uoyama S (2004) Noble-metal nanotubes (Pt, Pd, Ag) from lyotropic mixed-surfactant liquid-crystal templates. Angew Chem Int Ed 43:228
Teng XW, Yang H (2005) Synthesis of platinum multipods: an induced anisotropic growth. Nano Lett 5:885
Chen JY, Herricks T, Xia YN (2005) Polyol synthesis of platinum nanostructures: control of morphology through the manipulation of reduction kinetics. Angew Chem Int Ed 44:2589
Lee EP, Peng ZM, Cate DM, Yang H, Campbell CT, Xia YN (2007) Growing Pt nanowires as a densely packed array on metal gauze. J Am Chem Soc 129:10634
Narayanan R, El-Sayed MA (2005) Effect of colloidal nanocatalysis on the metallic nanoparticle shape: the suzuki reaction. Langmuir 21:2027
Narayanan R, Tabor C, El-Sayed M (2008) Can the observed changes in the size or shape of a colloidal nanocatalyst reveal the nanocatalysis mechanism type: homogeneous or heterogeneous? Top Catal 48:60
Mahmoud TCE, El-Sayed MA, Ding Y, Wang ZL (2008) A new catalytically active colloidal platinum nanocatalyst: the multiarmed nanostar single crystal. J Am Chem Soc 130:4590
Tian N, Zhou ZY, Sun SG, Ding Y, Wang ZL (2007) Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity. Science 316:732
Liang ZX, Zhao TS (2007) New DMFC anode structure consisting of platinum nanowires deposited into a nafion membrane. J Phys Chem C 111:8128
Wasmus S, Kuver A (1999) Methanol oxidation and direct methanol fuel cells: a selective review. J Electroanal Chem 461:14
Liu JY, Cao JY, Huang QH, Li XW, Zou ZQ, Yang H (2008) Methanol oxidation on carbon-supported Pt–Ru–Ni ternary nanoparticle electrocatalysts. J Power Sources 175:159
Lee JK, Choi J, Kang SJ, Lee JM, Tak Y, Lee J (2007) Influence of copper oxide modification of a platinum cathode on the activity of direct methanol fuel cell. Electrochim Acta 52:2272
Lee EP, Peng ZM, Chen W, Chen SW, Yang H, Xia YN (2008) Electrocatalytic properties of Pt nanowires supported on Pt and W gauzes. ACS Nano 2:2167
Yin J, Jia JB, Zhu LD (2009) Double-template synthesis of platinum nanomaterials for oxygen reduction. Microchim Acta 166:151
Yang B, Wang SQ, Tian SB, Liu LZ (2009) Determination of hydrogen sulfide in gasoline by Au nanoclusters modified glassy carbon electrode. Electrochem Commun 11:1230
Kawasaki H, Yonezawa T, Watanabe T, Arakawa R (2007) Platinum nanoflowers for surface-assisted laser desorption/ionization mass spectrometry of biomolecules. J Phys Chem C 111:16278
Jana S, Pande S, Sinha AK, Sarkar S, Pradhan M, Basu M, Saha S, Pal T (2009) A green chemistry approach for the synthesis of flower-like Ag-doped MnO2 nanostructures probed by surface-enhanced Raman spectroscopy. J Phys Chem C 113:1386
Liu QY, Guo XH, Li Y, Shen WJ (2009) Hierarchical growth of Co nanoflowers composed of nanorods in polyol. J Phys Chem C 113:3436
Qian L, Yang XR (2006) Polyamidoamine dendrimers-assisted electrodeposition of gold-platinum bimetallic nanoflowers. J Phys Chem B 110:16672
Domı’nguez-Crespo MA, Ramı’ez-Meneses E, Montiel-Palma V, Torres HAM, Dorantes RH (2009) Synthesis and electrochemical characterization of stabilized nickel nanoparticles. Int J Hydrogen Energy 34:1664
Xie JP, Zhang QB, Lee JY, Wang DIC (2008) The synthesis of SERS-active gold nanoflower tags for in vivo applications. ACS Nano 2:2473
Jia JB, Cao LY, Wang ZH (2008) Platinum-coated gold nanoporous film surface: electrodeposition and enhanced electrocatalytic activity for methanol oxidation. Langmuir 24:5932
Finot MO, Braybrook GD, McDermott MT (1999) Characterization of electrochemically deposited gold nanocrystals on glassy carbon electrodes. J Electroanal Chem 466:234
Schmidt U, Donten M, Osteryoung JG (1997) Gold electrocrystallization on carbon and highly oriented pyrolytic graphite from concentrated solutions of LiCl. J Electrochem Soc 114:2013
El-Deab MS (2009) On the preferential crystallographic orientation of Au nanoparticles: effect of electrodeposition time. Electrochim Acta 54:3720
Gunawardena G, Hills G, Montenegro I, Scharifker B (1982) Electrochemical nucleation. Part I. General considerations. J Electroanal Chem 138:225
Du Y, Xu JJ, Chen HY (2009) Ultrathin platinum film covered high-surface-area nanoporous gold for methanol electro-oxidation. Electrochem Commun 11:1717
Jiang H, Geng B, Kuai L, Wang S (2011) Simultaneous reduction-etching route to Pt/ZnSnO3 hollow polyhedral architectures for methanol electrooxidation in alkaline media with superior performance. Chem Commun ASAP
Zhang JT, Liu PP, Ma HY, Ding Y (2007) Nanostructured porous gold for methanol electro-oxidation. J Phys Chem C 111:10382
Li YX, Chen YL, Xian HY, Zhou Y, Wang L (2010) Cysteamine monolayer inducing the formation of platinum nanoclusters for methanol electrocatalytic oxidation. Microchim Acta 169:93
Ye JS, Cui HF, Wen Y, Zhang WD, Xu GQ, Sheu FS (2006) Electrodeposition of platinum nanoparticles on multi-walled carbon nanotubes for electrocatalytic oxidation of methanol. Microchim Acta 152:267
Wen Y, Ye JS, Zhang WD, Sheu FS, Xu GQ (2008) Electrocatalytic oxidation of methanol on a platinum modified carbon nanotube electrode. Microchim Acta 162:235
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This work was financially supported by the Natural Science Foundation of China (Nos. 20805011, 20905021).
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Feng, JJ., Li, AQ., Wang, AJ. et al. Electrodeposition of monodispersed platinum nanoparticles on a glassy carbon electrode for sensing methanol. Microchim Acta 173, 383–389 (2011). https://doi.org/10.1007/s00604-011-0566-7
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DOI: https://doi.org/10.1007/s00604-011-0566-7