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Polycarboxylic microsphere polymer gel for solid phase extraction of trace elements

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Abstract

A simple and sensitive method has been developed for the determination of trace elements (Cd, Co, Cu, Ni, Fe and Pb) in sea water and natural waters by electrothermal atomic absorption spectrometry. The method is based on column solid phase extraction of trace elements on a newly synthesized polycarboxylic gel. The sorbent was prepared by dispersion copolymerization of methacrylic acid (as a monomer) and trimethylolpropane trimethacrylate (as a crosslinking agent) in the form of monodisperse microspheres. It exhibits high regeneration ability, chemical and mechanical resistivity. The influence of pH, flow rates and concentration of the eluent on the degree of sorption of trace elements have been evaluated. The maximum static adsorption capacities of the sorbent at the optimal conditions for lead, nickel, cobalt, iron, cadmium and copper are determined. Detection limits achieved for the elements studied for 100 mL water sample volume were between 0.005 and 0.05 μg L−1. The relative standard deviation varied in the range 5–13% for all elements studied. The validity of the method was checked by an analysis of standard reference material SRLS-3 Riverine Water. Very good agreement between the analytical results and the certified values (t-test at 95% confidence level) was observed. The new polycarboxylic gel was applied to passive sampling procedures due to its high chemical and mechanical stability.

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References

  1. Wang J, Hansen EH (2002) Coupling sequential injection on-line preconcentration using a PTFE beads packed column to direct injection nebulization inductively coupled plasma mass spectrometry. J Anal At Spectrom 17:1278

    Article  CAS  Google Scholar 

  2. Tanaka T, Ando Y, Saitoh T, Hiraide M (2002) Preconcentration of traces of cobalt, nickel, copper and lead in water by thermoresponsive polymer-mediated extraction for tungsten filament electrothermal vaporization-inductively coupled plasma mass spectrometry. J Anal At Spectrom 17:1556

    Article  CAS  Google Scholar 

  3. Ma R, Mol W V, Adams F (1994) Determination of cadmium, copper and lead in environmental samples. An evaluation of flow injection on-line sorbent extraction for flame atomic absorption spectrometry. Anal Chim Acta 285:33

    Article  CAS  Google Scholar 

  4. Matoso E, Kubota LT, Cadore S (2003) Use of silica gel chemically modified with zirconium phosphate for preconcentration and determination of lead and copper by flame atomic absorption spectrometry. Talanta 60:313

    Article  Google Scholar 

  5. Zougagh M, Torres AG, Alonso EV, Pavon JMS (2004) Automatic on line preconcentration and determination of lead in water by ICP-AES using a TS-microcolumn. Talanta 62:503

    Article  CAS  Google Scholar 

  6. Xingguanga S, Meijiab W, Yihuab Z, Jiahuaa Z, Hanqib Z, Qinhan J (2003) Semi-online preconcentration of Cd, Mn and Pb on activated carbon for GFASS. Talanta 59:989

    Article  Google Scholar 

  7. Pena YP, Gallego M, Valcarcel M (1995) On-line sorbent extraction, preconcentration and determination of lead by atomic absorption spectrometry. Talanta 42:211

    Article  Google Scholar 

  8. Fang Z, Guo T, Welz B (1991) Determination of cadmium, lead and copper in water samples by flame atomic-absorption spectrometry with preconcentration by flow-injection on-line sorbent extraction. Talanta 38:267

    Article  Google Scholar 

  9. Su P-G, Huang S-D (1998) Use of 4-(2-pyridylazo)resocinol or 2-(2-pyridylazo)-5-dimethylaminophenol as chelating agent for determination of cadmium in seawater by atomic absorption spectrometry with on-line flow-injection sorbent extraction. Anal Chim Acta 376:305

    Article  CAS  Google Scholar 

  10. Gueguen C, Belin C, Thomas BA, Monna F, Favarger P-Y, Dominic J (1999) The effect of freshwater UV-irradiation prior to resin preconcentration of trace metals. Anal Chim Acta 386:155

    Article  CAS  Google Scholar 

  11. Siriraks A, Kingston H, Riviello JM (1990) Chelation ion chromatography as a method for trace elemental analysis in complex environmental and biological samples. Anal Chem 62:1185

    Article  CAS  Google Scholar 

  12. Roy PK, Rawat AS, Rai PK (2003) Synthesis, characterisation and evaluation of polydithiocarbamate resin supported on macroreticular styrene–divinylbenzene copolymer for the removal of trace and heavy metal ions. Talanta 59:239

    Article  CAS  Google Scholar 

  13. Chattopadhyay P, Sinha C, Pal DK (1997) Preparation and properties of a new chelating resin containing imidazolyl azo groups. Fresenius’ J Anal Chem 357:368

    Article  CAS  Google Scholar 

  14. Kenawy IMM, Hafez MAH, Akl MA, Lashein RR (2000) Determination by AAS of some trace heavy metal ions in some natural and biological samples after their preconcentration using newly chemically modified chloromethylated polystyrene-PAN ion-exchanger. Anal Sci 16:493

    Article  CAS  Google Scholar 

  15. Jarvis NV, Wagener JM, Hancock RD (1995) Evaluation of a diethanolamine chelating resin using two-phase potentiometry. Solvent Extr Ion Exch 13:591

    Article  CAS  Google Scholar 

  16. Yebra-Biurrun MC, Bermejo-Barrera A, Bermejo-Barrera MP (1991) Application of a poly(dithiocarbamate) resin with macroreticular support to the determination of trace amounts of cadmium and lead in non-saline waters. Analyst 116:1033

    Article  CAS  Google Scholar 

  17. Yebra-Biurrun MC, Garcia-Dopazo MC, Bermejo-Barrera A, Bermejo-Barrera MP (1992) Preconcentration of trace amounts of manganese from natural waters by means of a macroreticular poly(dithiocarbamate) resin. Talanta 39:671

    Article  CAS  Google Scholar 

  18. Veselova IA, Shekhovtsova TN (2000) Visual determination of lead(II) by inhibition of alkaline phosphatase immobilized on polyurethane foam. Anal Chim Acta 413:95

    Article  CAS  Google Scholar 

  19. Mallaa ME, Alvareza MB, Batistoni DA (2002) Evaluation of sorption and desorption characteristics of cadmium, lead and zinc on Amberlite IRC-718 iminodiacetate chelating ion exchanger. Talanta 57:277

    Article  Google Scholar 

  20. Cekic SD, Filik H, Apak R (2004) Use of an o-aminobenzoic acid-functionalized XAD-4 copolymer resin for the separation and preconcentration of heavy metal(II) ions. Anal Chim Acta 505:15

    Article  CAS  Google Scholar 

  21. Tewari PK, Singh AK (2002) Preconcentration of lead with Amberlite XAD-2 and Amberlite XAD-7 based chelating resins for its determination by flame atomic absorption spectrometry. Talanta 56:735

    Article  CAS  Google Scholar 

  22. Akman S, Tokman N (2003) Determination of lead and nickel in Apple- Leaves and sea-water by electrothermal atomic absorption spectrometry after solid-phase extraction using Chromosorb-107 filled in a syringe. Talanta 60:199

    Article  CAS  Google Scholar 

  23. Bakircioglu Y, Bakircioglu D, Tokman N (2005) A novel preconcentration method for determination of iron and lead using Chromosorb-103 and flame atomic absorption spectrometry. Anal Chim Acta 547:26

    Article  CAS  Google Scholar 

  24. Kagoz H, Ozgumu S, Orbay M (2003) Modified polyacrylamide hydrogels and their application in removal of heavy metal ions. Polymer 44:1785

    Article  Google Scholar 

  25. Yei L, Cormack PAG, Mosbach K (2001) Molecular imprinting on microgel spheres. Anal Chim Acta 435:187

    Article  Google Scholar 

  26. Dakova I, Karadjova I, Ivanov I, Georgieva V, Evtimova B, Georgiev G (2007) Solid phase selective separation and preconcentration of Cu(II) by Cu(II)-imprinted polymethacrylic microbeads. Anal Chim Acta 584:196

    Article  CAS  Google Scholar 

  27. Miller ML (1964) Encyclopedia of polymer science and technology, vol. 1. Wiley, New York, p 217

  28. Suleiman JS, Hu B, Pu X, Huang C, Jiang Z (2007) Nanometer-sized zirconium dioxide microcolumn separation/preconcentration of trace metals and their determination by ICP-OES in environmental and biological samples. Microchim Acta 159:379

    Article  Google Scholar 

  29. Lian N, Chang X, Zheng H, Wang S, Cui Y, Zhai Y (2005) Application of dithizone-modified TiO2 nanoparticles in the preconcentration of trace chromium and lead from sample solution and determination by inductively coupled plasma atomic emission spectrometry. Microchim Acta 151:81

    Article  CAS  Google Scholar 

  30. Liang P, Cao J, Liu R, Liu Y (2007) Determination of trace rare earth elements by inductively coupled plasma optical emission spectrometry after preconcentration with immobilized nanometer titanium dioxide. Microchim Acta 159:35

    Article  CAS  Google Scholar 

  31. Wang Z-H, Zhang Z-P, Wang Z-P, Liu L-W, Yan X-P (2004) Acrylic acid grafted polytetrafluoroethylene fiber as new packing for flow injection on-line microcolumn preconcentration coupled with flame atomic absorption spectrometry for determination of lead and cadmium in environmental and biological samples. Anal Chim Acta 514:151

    Article  CAS  Google Scholar 

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Acknowledgement

The authors gratefully acknowledge the financial support provided by University of Sofia Scientific Foundation (Grant 032/2007), The Black Sea Ecotoxicity Assessment (BSEA) Joint Research Project IB7320-110933/1 The Black Sea Ecotoxicity Assessment (BSEA) within the framework of the SCOPES Program and Swiss National Science Foundation.

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Authors and Affiliations

  1. Department of Chemistry, Sofia University, 1164, Sofia, Bulgaria

    Ivanka G. Dakova, Irina B. Karadjova, Ventsislava T. Georgieva & George S. Georgiev

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  1. Ivanka G. Dakova
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  2. Irina B. Karadjova
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  3. Ventsislava T. Georgieva
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  4. George S. Georgiev
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Correspondence to Ivanka G. Dakova.

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Dakova, I.G., Karadjova, I.B., Georgieva, V.T. et al. Polycarboxylic microsphere polymer gel for solid phase extraction of trace elements. Microchim Acta 164, 55–61 (2009). https://doi.org/10.1007/s00604-008-0031-4

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  • DOI: https://doi.org/10.1007/s00604-008-0031-4

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