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The study of preconcentration and separation of vanadium(V) using microcrystalline triphenylmethane loaded with crystal violet and the determination of vanadium(V) in water samples by spectrophotometry

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Abstract.

The paper describes a novel method for vanadium(V) preconcentration using microcrystalline triphenylmethane loaded with crystal violet (CV) prior to the determination by spectrophotometry. The effects of different parameters, such as the amounts of crystal violet and triphenylmethane, acidity, stirring time, various salts and metal ions etc on the enrichment yield of V(V) have been investigated to select the experimental conditions. V(V) can be completely separated from Cd(II), Pb(II), Mn(II), Co(II), Cu(II), Fe(III), Ni(II), Al(III), Zn(II) and Hg(II) by controlling acidity. Under the optimum conditions, V(V) can be totally adsorbed on the surface of microcrystalline triphenylmethane. The possible reaction mechanism of the enrichment of V(V) is discussed in detail in this paper. The detection limit of this proposed method is 0.023 µg L−1 with the preconcentration factor of 200. The recovery is in a range of 96.0–104%. The proposed method has been successfully applied to the determination of trace vanadium in various water samples with satisfactory results.

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Authors and Affiliations

  1. College of Chemistry and Environmental Science, Henan Normal University, The Key Laboratory of Environmental Pollution Control Technology of Henan Province, 453007, Xinxiang, Henan, P.R. China

    Quanmin Li, Xiaohong Zhao, Kai Jiang & Guoguang Liu

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  1. Quanmin Li
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  2. Xiaohong Zhao
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  3. Kai Jiang
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  4. Guoguang Liu
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Correspondence to Quanmin Li.

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Li, Q., Zhao, X., Jiang, K. et al. The study of preconcentration and separation of vanadium(V) using microcrystalline triphenylmethane loaded with crystal violet and the determination of vanadium(V) in water samples by spectrophotometry. Microchim Acta 158, 123–130 (2007). https://doi.org/10.1007/s00604-006-0693-8

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