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Stopped-flow spectrophotometric determination of nM level of Pb(II) using 5,10,15,20-terakis(1-methylpyridinium-4-yl)porphine

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Abstract.

A spectrophotometric determination method for nM levels of Pb(II) has been developed using a stopped-flow spectrophotometer with cationic water-soluble porphyrin. The stopped-flow spectrophotometer allows the monitoring of the incorporation reaction of the Pb(II) ion into 5,10,15,20-terakis(1-methylpyridinium-4-yl)porphine (TMPYP) within a narrow time window (2.5 s) at pH 10.5–12.0 before the Pb-TMPYP complex is replaced with other foreign metal ions, since usually the Pb-TMPYP complex is very labile and readily replaced with other metal ions. This improved the selectivity of Pb(II) determination as compared to the conventional spectrophotometric determination of Pb(II) using water-soluble porphyrins.

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 980-8579, Aoba, Sendai, Japan

    Kunio Kawamura, Shukuro Igarashi & Takao Yotsuyanagi

  2. Present address: Department of Applied Chemistry, Osaka Prefecture University, 599-8531, Sakai, Osaka, Japan

    Kunio Kawamura

  3. Present address: Department of Materials Science, Faculty of Engineering, Ibaraki University, 4-12-1 Nakanarusawa, 316-8511, Hitachi 316, Ibaraki, Japan

    Shukuro Igarashi

  4. Present address: Miyagi National College of Technology, Medeshima Shiote, Nodayama 48, 981-1239, Natori, Miyagi, Japan

    Takao Yotsuyanagi

Authors
  1. Kunio Kawamura
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  2. Shukuro Igarashi
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  3. Takao Yotsuyanagi
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Correspondence to Kunio Kawamura.

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Kawamura, K., Igarashi, S. & Yotsuyanagi, T. Stopped-flow spectrophotometric determination of nM level of Pb(II) using 5,10,15,20-terakis(1-methylpyridinium-4-yl)porphine. Microchim Acta 157, 87–91 (2007). https://doi.org/10.1007/s00604-006-0573-2

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  • DOI: https://doi.org/10.1007/s00604-006-0573-2

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