Kinetic Spectrophotometric Determination of Total Iron in Natural Water by Flow Injection Analysis Using On-Line Preconcentration

Abstract.

A new flow injection catalytic spectrophotometric method for on-line preconcentration and determination of total iron in natural water is described. The method is based on a combination of iron-catalyzed oxidation of diaminoditolyl by potassium bromate and the use of on-line preconcentration of iron onto 8-hydroxy-quinoline immobilized on silica gel. The corresponding calibration graph is linear over the range of 2.0–110 ng mL⁻¹ for Fe(III) using a time-based technique for 5 min preconcentration. The relative standard deviation of 11 measurements of 60 ng mL⁻¹ Fe(III) was 0.67%. The method was applied to the determination of iron in natural water. The results obtained by the proposed method were compared with those obtained by ICP-AES. The t-test showed no significant differences between the two methods at a confidence level of 95%.