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Thermal annealing effects on the stress stability in silicon dioxide films grown by plasma-enhanced chemical vapor deposition

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Abstract

The stress stability in plasma-enhanced chemical vapor deposition (PECVD) silicon dioxide (SiO2) films is a key factor of device performance. In this study, the PECVD SiO2 films are annealed at 400–1000 °C in a nitrogen (N2) or oxygen (O2) ambience for 2 h. The influences of annealing parameters on the stress state and stress stability in PECVD SiO2 films are investigated. The bonding nature and surface morphology of the films are also studied to analyze the physical mechanism involved. It is demonstrated that the stress stability is first deteriorated and then improved with increasing annealing temperature. In addition, O2 ambience is more appropriate to improve stress stability than N2, and the stress in PECVD SiO2 film can be stabilized when it is annealed at 1000 °C in O2 ambience. These results should be able to provide important insights into the design of device fabrication processes.

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References

  • Alayo MI, Pereyra I (1997) Improvement of the structural properties of near stoichiometric PECVD SiO2. Br J Phys 27(4):146–149

    Google Scholar 

  • Andres ES, Prado AD, Martnez FL (2000) Rapid thermal annealing effects on the structural properties and density of defects in SiO2 and SiNx: H films deposited by electron cyclotron resonance. J Appl Phys 87(3):1187–1192

    Article  Google Scholar 

  • Au V, Charles C, Boswell RW (2006) Interface creation and stress dynamics in plasma-deposited silicon dioxide films. Appl Phys Lett 88:234103

    Article  Google Scholar 

  • Bakos T, Rahkeev SN, Pantelides ST (2004) H2O and O2 molecules in amorphous SiO2: defect formation and annihilation mechanisms. Phys Rev B: Condens Matter 69:195206

    Article  Google Scholar 

  • Brenner A, Senderoff S (1949) Calculation of stress in eletrodeposits from the curvature of a plated strip. J Res Natl Bur Stand 42:105–123

    Article  Google Scholar 

  • Chen XY, Lu YF, Tang LJ, Wu YH, Cho BJ (2005) Annealing and oxidation of silicon oxide films prepared by plasma-enhanced chemical vapor deposition. J Appl Phys 97:014913

    Article  Google Scholar 

  • Fitch JT, Kim SS, Lucovsky G (1990) Thermal stabilization of device quality films deposited at low temperatures. J Vac Sci Technol, A 8(3):1871–1877

    Article  Google Scholar 

  • Fu JY, Shang HP, Shi HT, Li ZG, Ou Y, Chen DP, Zhang QC (2016) Optical sensitivity non-uniformity analysis and optimization of a tilt optical readout focal plane array. J Micromech Microeng 26:025001

    Article  Google Scholar 

  • Guan D, Bruccoleri AR, Heilmann RK, Schattenburg ML (2014) Stress control of plasma enhanced chemical vapor deposited silicon oxide film from tetraethoxysilane. J Micromech Microeng 24:027001

    Article  Google Scholar 

  • Haque MS, Naseem HA, Brown WD (1997) Post-deposition processing of low temperature PECVD silicon dioxide films for enhanced stress stability. Thin Solid Films 308–309:68–73

    Article  Google Scholar 

  • Lopez JAL, Lopez JC, Falcony C (2009) FTIR and photoluminescence of annealed silicon rich oxide films. Superficies y Vacio 22(1):11–14

    Google Scholar 

  • Martinez FL, Martil I, Diaz GG (1998) Influence of rapid thermal annealing processes on the properties of SiNx: H films deposited by the electron cyclotron resonance method. J Non-Cryst Solids 227–230:523–527

    Article  Google Scholar 

  • Moon SE, Choi NJ, Lee HK, Lee J, Yang WS (2013) Semiconductor-type MEMS gas sensor for real-time environmental monitoring applications. ETRI J 35(4):617–624

    Article  Google Scholar 

  • Park Y, Lee JK, Jung I, Heo SB, Lee JY (1999) Evolution of residual stress in plasma-enhanced chemical-vapor-deposited silicon dioxide film exposed to room air. Appl Phys Lett 75:3811–3813

    Article  Google Scholar 

  • Plummer JD, Deal MD, Griffin PB (2000) Silicon VLSI technology fundamentals, practice and modeling. Prentice Hall, New Jersey

    Google Scholar 

  • Shang HP, Fu JY, Xie CQ, Li ZG, Chen DP (2016) Improving stress stability in low-pressure chemical vapor deposited silicon dioxide films by ion implantation. Thin Solid Films 598:103–108

    Article  Google Scholar 

  • Viana CE, Morimoto NI, Bonnaud O (2000) Annealing effects in the PECVD SiO2 thin films deposited using TEOS, Ar and O2 mixture. Microelectron Reliab 40:613–616

    Article  Google Scholar 

  • Zhang L, Zhang H, Ma JW, Zhang XW, Jiang XY, Zhang ZL (2010) Copper phthalocyanine thin-film field-effect transistor with SiO2/Ta2O5/SiO2 multilayer insulator. Thin Solid Films 518:6134–6136

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No. 61306141).

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Correspondence to Jianyu Fu.

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Fu, J., Shang, H., Li, Z. et al. Thermal annealing effects on the stress stability in silicon dioxide films grown by plasma-enhanced chemical vapor deposition. Microsyst Technol 23, 2753–2757 (2017). https://doi.org/10.1007/s00542-016-3005-1

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  • DOI: https://doi.org/10.1007/s00542-016-3005-1

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