Abstract
This paper demonstrates a promising and low-cost method for fabricating PZT nano-dot array by using sol–gel template method combined with laser interference lithography. ZrO2 template with the pitch of 1 μm is firstly fabricated by sol–gel method and laser interference with a 325 nm He-Cd laser. Afterwards, PZT nano dot array with diameter of 500 nm and thickness of 20 nm is prepared on the ZrO2 template. Atomic force microscope results show that the PZT nano dot array is uniform and highly ordered. Ferroelectric properties of PZT nano dot array are in situ measured through online-operation of TF analyzer and AFM. A ferroelectric hysteresis loop is obtained for the PZT nano dot.
Similar content being viewed by others
References
Alexe M, Gruverman A (2004) Nanoscale characterisation of ferroelectric materials. Springer, Berlin Heidelberg, pp 181–188
Alexe M, Harnagea C, Hesse D, Gösele U (2000) 100-nm lateral size ferroelectric memory cells fabricated by electron-beam direct writing. Appl Phys A 70:247–251
Alexe M, Harnagea C, Visinoiu A, Visinoiu A, Pignolet A, Hesse D, Gösele U (2001a) Patterning and switching of nano-size ferroelectric memory cells. Scripta Mater 44:1175–1179
Alexe M, Harnagea C, Hesse D, Gösele U (2001b) Polarization imprint and size effects in mesoscopic ferroelectric structures. Appl Phys Lett 79:242–244
Alexe M, Harnagea C, Hesse D (2004) Non-conventional micro- and nanopatterning techniques for electroceramics. J Electro Ceram 12:69–88
Buhlmann S, Dwir B, Baborowski J, Muraltb P (2002) Size effect in mesoscopic epitaxial ferroelectric structures: Increase of piezoelectric response with decreasing feature size. Appl Phys Lett 80:3195–3197
Ganpule CS, Stanishevsky A, Aggarwal S, Melngailis J, Williams E, Ramesh R, Joshi V, de Araujo CP (1999) Scaling of ferroelectric and piezoelectric properties in Pt/SrBi2Ta2O9/Pt thin films. Appl Phys Lett 75:3874–3876
Lee W, Han H, Lotnyk A, Schubert MA, Senz S, Alexe M, Hesse D, Baik S, Gösele U (2008) Individually addressable epitaxial ferroelectric nanocapacitor arrays with near Tb inch-2 density. Nat Nanotechnol 3:402–407
Luo Y, Szafraniak I, Zakharov ND, Nagarajan V, Steinhart M, Wehrspohn RB, Wendorff JH, Ramesh R, Alexe M (2003) Nanoshell tubes of ferroelectric lead zirconate titanate and barium titanate. Appl Phys Lett 83:440–442
Ren SQ, Briber RM, Wuttiga M (2009) Self-organized two-dimensional onions. Appl Phys Lett 94:173507
Schmitza T, Prume K, Reichenberg B, Roelofs A, Waser R, Tiedke S (2004) In situ compensation of the parasitic capacitance for nanoscale hysteresis measurements. J Eur Ceram Soc 24:1145–1147
Stanishevsky A, Nagaraj B, Melnggailis J, Ramesh R, Khriachtchev L, McDaniel E (2002) Radiation damage and its recovery in focused ion beam fabricated ferroelectric capacitors. J Appl Phys 92:3275–3278
Stefanita CG, Pramanik S, Banerjee A, Sievert M, Baski AA, Bandyopadhyay S (2004) Electrochemically self-assembled nanostructure arrays. J Cryst Growth 268:342–345
Tiedke S, Schmitz T, Prume K, Roelofs A, Schneller T, Kall U, Waser R, Ganpule CS, Nagarajan V, Stanishevsky A, Ramesh R (2001) Direct hysteresis measurements of single nanosized ferroelectric capacitors contacted with an atomic force microscope. Appl Phys Lett 79:3678–3680
Zhao GY, Zhang WH, Xu GM, XiaoC Deng, Jiang BL, Zhao W (2006) Fabrication of sub-micro size PZT array and their ferroelectric properties. Sci China Ser E 49:693–700
Zhao GY, Zhang WH, Wang ZZ, Zhao W, Jiang BL (2007) Fabrication of photosensitive thin films and 2-D Bragg gratings. Prog Nat Sci 17:276–280 (in Chinese)
Zhukov AA, Filby ET, Ghanem MA, Bartlett PN, Groot PAJ (2004) Superconducting anti-dot arrays from self-assembly template methods. Phys C 404:455–459
Acknowledgments
This work is supported by the National Natural Science Foundation of China (No. 51072163) and the the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20096118110002). It is also supported by the Special Funds for the Construction of Key Disciplines Project of Shaanxi Province.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhao, G., Wang, Z., Xu, G. et al. Fabrication of PZT nano dot array and their ferroelectric properties. Microsyst Technol 18, 531–535 (2012). https://doi.org/10.1007/s00542-012-1479-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00542-012-1479-z