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Timing of K-alkaline magmatism in the Balkan segment of southeast European Variscan edifice: ID-TIMS and LA-ICP-MS study

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Abstract

The Variscan orogen in southeast Europe is exposed in isolated remnants, affected by a subsequent Alpine tectono-magmatic overprint. Unlike the central European Variscides, in SE Europe the juxtaposition and correlation of the events and products are impeded by the scarcity of Variscan domains with preserved magmatic, metamorphic, sedimentological and structural characteristics. To reveal the particular evolution of the Variscan orogen in Balkan Mts, we present the results of ID-TIMS and LA-ICP-MS dating of three potassic-alkaline intrusions: Svidnya, Buhovo–Seslavtsi and Shipka. The age determinations from the plutons do not permit to establish their unequivocal ages, but they bracket the time interval of emplacements. Based on geochronological, tectonic and stratigraphic evidence the emplacement interval for plutons could be: 317–310 Ma for Svidnya, 330–310 Ma for Buhovo–Seslavtsi and 320–303 Ma for Shipka. These results show that the generation of potassic-alkaline magmas was post-Visean and is contemporaneous with the adjacent numerous calc-alkaline granitoid plutons. Thus, the Variscan orogen in the Balkan Mts is not characterized by a time-dependent geochemical evolution of magma generation. Hence, the observed differences in the rocks’ compositions can be interpreted solely by distinction between the magma sources. The available data for both potassic-alkaline and calc-alkaline rocks indicate that the major episodes of crustal stacking and shearing in the Balkan part of the Variscan edifice are pre-Visean (~330 Ma). The present study reveals that the potassic-alkaline rocks from the Balkan Mts are younger than the central European potassic granitoids (durbachites). It suggests that melting of enriched mantle source took place at different times throughout the Variscan orogen. In spite of the alkaline character of the magmas, the studied zircons show a complex nature, with inherited cores and magmatic overgrowths. The observed heterogeneities in the zircons imply the presence of much older materials in the petrogenesis of the rocks from the potassic-alkaline plutons.

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References

  • Amov B, Arnaudov V, Pavlova M, Dragov P, Baldjieva T, Evstatieva S (1981) Lead isotopic data on the Paleozoic granitoids and ore mineralization from the Western Balkan Mountains and the Trun District (West Bulgaria). I: isotopic ratios and geochronology. Geol Balc 11:3–26

    Google Scholar 

  • Antić M, Peytcheva I, von Quadt A, Kounov A, Trivić B, Serafimovski T, Tasev G, Gerdjikov I, Wetzel A (2016) Pre-Alpine evolution of a segment of the North Gondwanan margin: geochronological and geochemical evidence from the central Serbo-Macedonian Massif. Gondwana Res 36:523–544

    Article  Google Scholar 

  • Balintoni I, Balica C, Cliveti M, Li QL, Hann HP, Chen F, Schuller V (2009) The emplacement age of the Muntele Mare Variscan granite (Apuseni Mountains, Romania). Geol Carpath 60:495–504

    Article  Google Scholar 

  • Bowring J, McLean N, Bowring S (2011) Engineering cyber infrastructure for U–Pb geochronology: Tripoli and U–Pb_Redux. Geochem Geophys Geosyst. doi:10.1029/2010GC003479

    Google Scholar 

  • Buzzi L, Gaggero L, Grozdanov L, Yanev S, Slejko F (2010) High-Mg potassic rocks in the Balkan segment of the Variscan belt (Bulgaria): implications for the genesis of the orogenic lamproite magmas. Geol Mag 147:434–450

    Article  Google Scholar 

  • Carrigan C, Mukasa S, Haydoutov I, Kolcheva K (2005) Age of Variscan magmatism from the Balkan sector of the orogen, central Bulgaria. Lithos 82:125–147

    Article  Google Scholar 

  • Carrigan C, Mukasa S, Haydoutov I, Kolcheva K (2006) Neoproterozoic magmatism and Carboniferous high-grade metamorphism in the Sredna Gora Zone, Bulgaria: an extension of the Gondwana-derived Avalonian–Cadomian belt? Precambrian Res 147:404–416

    Article  Google Scholar 

  • Cherniak D, Watson E (2001) Diffusion in zircon. Chem Geol 172:5–24

    Article  Google Scholar 

  • Dabovski C, Boyanov I, Khrischev Kh, Nikolov T, Sapunov I, Yanev Y, Zagorchev I (2002) Structure and Alpine evolution of Bulgaria. Geol Balc 32:9–15

    Google Scholar 

  • Dimitrov S (1935) Die eruptivgesteine oberhalb von Seslavtci und Buhovo (nordöstlich von Sofia). Annuaire de l’Universite de Sofia 33:189–246 (in Bulgarian, with German abstract)

    Google Scholar 

  • Dimitrov S (1937) Beitrag zur Kenntnis der kalireichen Alkaligesteine Bulgariens. Die Eruptivegesteine von Svidnja (im Westbalkan). Annuaire de l’Universite de Sofia 33:291–343 (in Bulgarian, with German abstract)

    Google Scholar 

  • Dimitrov S (1938) Egebnisse und problemme der petrographischen forshungen in Bulgaria. Annuaire de l’Universite de Sofia 35:225–253 (in Bulgarian, with German abstract)

    Google Scholar 

  • Dinkov E, Pavlovich M, Petrov D, Angelov V, Darakchiev S (1979) Report on the geology of part of Western Stara planina Mts., between the villages of Osenovlak and Buchin prohod in scale 1:25000. Comm Geol IV:306 (in Bulgarian)

    Google Scholar 

  • Duchesne JC, Liegeois JP, Iancu V, Berza T, Matukov D, Tatu M, Sergeev S (2008) Post-collisional melting of crustal sources: constraints from geochronology, petrology and Sr, Nd isotope geochemistry of the Variscan Sichevita and Poniasca granitoid plutons (South Carpathians, Romania). Int J Earth Sci 97:705–723

    Article  Google Scholar 

  • Dyulgerov M (2005) Le plutonisme de tendance alcaline potassique de Stara planina, Bulgarie: étude pétrologique des complexes de Buhovo-Seslavtzi, Svidnya et Shipka. Dissertation, Université Paris-XI

  • Dyulgerov M, Platevoet B (2013) In situ differentiation and evolution of potassic syenites from Svidnya, Bulgaria. Miner Petrol 107:971–984

    Article  Google Scholar 

  • Dyulgerov M, Peytcheva I, von Quadt A, Nedyalkov R (2006) Source and age heterogeneities between the rocks of Lutzkan pluton. In: “Geosciences 2006”, Proceedings of the national conference of Bulgarian Geological Society and Bulgarian Geophysical Society, Sofia, p 177–180

  • Dyulgerov M, Platevoet B, Schaltegger U (2007) Variscan potassic-alkaline magmatism in Stara planina, Bulgaria—composition, source and geodynamic significance. Conference Abstract Goldschmidt, Cologne, A247

  • Gerdjikov I, Lazarova, A, Ruffet G, Vangelov D, Balkanska E, Bonev K (2010) 40Ar/39Ar geochronological constraints of a Variscan transpression in Central Stara planina Mountain. In: Bulgarian Geological Society, National conference “Geosciences 2010”, p 109–110

  • Gutierrez-Marco J, Yanev S, Sachanski V, Rabano I, Lakova I (2002) New finding of trilobites and Graptolites in the Ordovician in Bulgaria. Rev Bulg Geol Soc 63:51–58

    Google Scholar 

  • Holub FV (1997) Ultrapotassic plutonic rocks of the Durbachite Series in the Bohemian Massif: petrology, geochemistry and petrogenetic interpretation. J Geol Sci Econ Geol Mineral 31:5–26

    Google Scholar 

  • Ivanov Z (1998) Tectonics of Bulgaria. Habilitation thesis. Sofia University “St. Kliment Ohridski”, Sofia, p 634 (in Bulgarian)

  • Ivanov Z, Angelov V (1979) The Palaeozoic in the Iskar gorge. In: Deformation of metamorphic rocks, PK. 9, ANSS, 18–32 (in Russian)

  • Jackson S, Pearson N, Griffin W, Belousova E (2004) The application of laser ablation inductively coupled plasma mass spectrometry to in situ U–Pb zircon geochronology. Chem Geol 211:47–69

    Article  Google Scholar 

  • Janoušek V, Gerdes A (2003) Timing the magmatic activity within the Central Bohemian Pluton, Czech Pepublic: convential U–Pb ages for the Sazava and Tabor intrusions and their geotectonic significance. J Czech Geol Soc 48:70–71

    Google Scholar 

  • Kalvacheva R, Prokop R (1988) Fossil evidence (Devonian Crinoids) for the age of metamorphic rocks in Šipka Balkan Mountains, Bulgaria. C R Acad Bulg Sci 41:91–94

    Google Scholar 

  • Kamenov B, von Quadt A, Peycheva I (2002) New insight into petrology, geochemistry and dating of the Vejen pluton, Bulgaria. Geochem Mineral Petrol 39:3–26

    Google Scholar 

  • Kostov I (1950) Mineral and chemical compositions of tne alkalic igneous rocks of the Shipka Mountain. Annuaire de l’Universite de Sofia 46(3):1–37 (in Bulgarian, with English abstract)

    Google Scholar 

  • Kotkova J, Schaltegger U, Leichmann J (2003) 338–335 Ma old intrusions in the E Bohemian massif—a relic of the orogen-wide durbachitic magmatism in European Variscides. J Czech Geol Soc 48:80–81

    Google Scholar 

  • Kovarikova P, Siebel W, Jelinek E, Stemprokc M, Kachlık V, Holub F, Blecha V (2007) Petrology, geochemistry and zircon age for redwitzite at Abertamy, NW Bohemian Massif (Czech Republic): tracing the mantle component in Late Variscan intrusions. Chem Erde 67:151–174

    Article  Google Scholar 

  • Langer C, Hegner E, Alther R, Satir M, Henjes-Kunst F (1995) Carboniferous granitoids from the Odenwald, the Shwarzwald and the Vosges—constraints on magma source. Terra Nostra 95(8):114

    Google Scholar 

  • Lazarova A (2008) Shallow-level post-tectonic emplacement of Vezhen pluton, Central Stara Planina Mountains. C R Acad bulg Sci 61:1315–1322

    Google Scholar 

  • Lazarova A, Gerdjikov I (2008) Structure of sheared granitoids at Zlatishka Stara Planina Mountain: indicators for the frictional-viscous transition. Rev Bulg Geol Soc 69:7–20 (in Bulgarian with English abstract)

    Google Scholar 

  • Lilov P, Grozdanov L, Peeva I (1968) On the absolute age for the magmatic rocks from the deposits of Svidnya and Seslavtzi. Bull Geol Inst 17:79–82 (in Bulgarian)

    Google Scholar 

  • Ludwig K (2005) Isoplot/Ex. V. 3. USGS Open-File Rep

  • Malinov O, von Quadt A, Peytcheva I, Aladjov T, Aladjov A, Naydenova S, Djambazov S (2004) The Klissura granite in the Western Balkan - questions and answers from new field and isotope studies. In: Proceedings annual scientific conference on BGS “Geology 2004”, Dec 16–17, Sofia, p 51–53

  • Marinova R, Grozdev V, Ivanova D, Sinjovski D, Milovanov P, Petrov I, Popov A (2010) Tsarvena Jabuka, Vlasotince and Tran-North and Tran-South 1:50,000 scale maps sheets: explanatory notes. Sofia. Ministry of Environment and Water 77 (in Bulgarian)

  • Mattinson J (2005) Zircon U–Pb chemical abrasion (“CA-TIMS”) method: combined annealing and multi-step partial dissolution analysis for improved precision and accuracy of zircon ages. Chem Geol 220:47–66

    Article  Google Scholar 

  • Milicevic V (1992) Palaeomagnetic study of Phanerozoic sedimentary rocks in Serbia. Comptes Rendus Societe Serbe Geologique, Livre Jubilaire 243–250 (in Serbian, with English abstract)

  • Milicevic V (1994) Preliminary palaeomagnetic results for Ordovician of Zvonyachka banya, Dgerchek and Zrna reka (Eastern Serbia). Proc Geoinst 29:13–22 (in Serbian, with English abstract)

    Google Scholar 

  • Nedialkov R, Platevoet B, Peytcheva I, von Quadt A, Vangelova V (2007) Geochemistry and U–Pb zircon dating of the Mezdreya granitic pluton. In: Proceedings of the national conference of BGS “Geoscience 2007”, 13–4 Dec 2007, Sofia, Bulgaria, p 101–102

  • Nozharov P, Petkov N, Yanev S, Kropachek V, Krs P, Pruner P (1980) A palaeomagnetic and petromagnetic study of Upper Carboniferous, Permian and Triassic sediments, NW Bulgaria. Studia Geophysica et Geodaetica Praha 24:252–284

    Article  Google Scholar 

  • Peytcheva I, von Quadt A, Malinov O, Tacheva E (2006) Petrochan and Klissura plutons in Western Balkan: relationships, precise U–Pb dating and isotope tracing. Geosciences 2006 221–224 (Sofia)

  • Peytcheva I, von Quadt A, Dyulgerov M, Nedialkov R (2010) Age and source heterogeneities in the rocks of Lutzkan and Ruy plutons, Bulgaria: some thoughts about their relations to the Au-mineralization at “Zlata” deposit. In :Geologica balcanica, vol. 39, Bulgarian academy of sciences, Sofia, p 306–307

  • Purvanova M, Marinova-Chipchakova S (1952) Alkalishe ganggesteine in der umgebung von Tran (Westbulgarien). Annuaire Direction Generale des Recherches Geologique et Minieres V:203–219 (in Bulgarian, with German abstract)

    Google Scholar 

  • Sabatier A (1991) Vaugnerites: special lamprophyre-derived mafic enclaves in some Hercynian granites from Western and Central Europe. In: Didier J, Barbarin B (eds) Enclaves and granite petrology, Series Developments in Petrology vol 13. Elsevier, pp 63–81

  • Schaltegger U, Schneider J, Maurin C, Corfu F (1996) Precise U–Pb Chronometry of 345–340 Ma old magmatism related to syn-convergence extension in the southern Vosges (Central Variscan Belt). Earth Planet Sci Lett 144:403–419

    Article  Google Scholar 

  • Schmitz M, Schoene B (2007) Derivation of Isotope ratios, errors, and error correlations for U–Pb geochronology using 205Pb–235U-(233U)-spiked Isotope Dilution Thermal Ionization Mass Spectrometric data. Geochem Geophys Geosyst. doi:10.1029/2006GC001492

    Google Scholar 

  • Siebel W, Chen F, Satir M (2003) Late-Variscan magmatism revisited: new implications from Pb-evaporation zircon ages on the emplacement of redwitzites and granites in NE Bavaria. Int J Earth Sci 52:36–53

    Google Scholar 

  • Sørensen H (1974) The alkaline rocks. Wiley, New York, p 622

    Google Scholar 

  • Spassov C (1960) Stratigraphie des Ordoviziums und Silurs im Kern der Svoge-Antiklinale. Travaux sur la Geologie de Bulgarie, Serie Stratigraphie et Tectonique 1:161–202 (in Bulgarian with German abstract)

    Google Scholar 

  • Stacey J, Kramers J (1975) Approximation of terrestrial lead isotope evolution by a two-stage model. Earth Planet Sci Lett 26:207–211

    Article  Google Scholar 

  • Stampfli G, von Raumer J, Borel G (2002) Paleozoic evolution of pre-Variscan terranes and from Gondwana to the Variscan collision. In: Martinez Catalan J, Hatcher R, Arenas R, Diaz Garcia F (eds) Variscan—Appalachian dynamics and the building of the late Paleozoic basement, vol 364. Geological Society of America Special Paper, Boulder, pp 263–280

    Chapter  Google Scholar 

  • Stefanova M, Pavlova M, Amov B (1974) Geochemistry and isotope composition of lead in the potassium-alkaline rocks of lamproite character. Min Genes Sofia 23:333–348 (in Bulgarian)

  • Tacheva E, Nedyalkov R, Peytcheva I (2006) Magma mingling and mixing in Petrochan pluton (Western Balkan): preliminary field, petrological and geochemical evidence. In: Proceedings joint conference of bulgarian geophysical and geological societies “Geosciences 2006”, 30 Nov–1 Dec, Sofia, p 161–164

  • Tchounev D (1968) Upper Palaeozoic voncanics. In: Tsankov V, Spasov Chr (eds) Stratigraphy of Bulgaria. Nauka i izkustvo, Sofia, pp 155–165 (in Bulgarian)

  • Tenchov Y (1966) Lithostratigraphy and structure of the Svoge Carboniferous. Bull Bulg Geol Inst 15:243–268 (in Bulgarian with English abstract)

    Google Scholar 

  • Trashlieva J (1985) On the rock types in Carboniferous in Svoge coal basin. In: Nachev I, Tsvetkov K (eds) Laboratory studies of mineral raw materials. Technika, Sofia, pp 15–21 (in Bulgarian)

  • Ulianov A, Müntener O, Schaltegger U, Bussy F (2012) The data treatment dependent variability of U–Pb zircon ages obtained using mono-collector, sector field, laser ablation ICP-MS. J Anal Atom Spectrom 27:663–676

    Article  Google Scholar 

  • Vaskovic N, Koroneos A, Christofides G, Sreckovic-Batocanin D, Milovanovic D (2004) Mineralogy and petrology of the Brnjica granitoids (Eastern Serbia). Bull Geol Soc Greece 36:615–624

    Google Scholar 

  • Vassilev L (1993) Pre-Late Cretaceous collides in Bulgaria. Rev Bulg Geol Soc 53(3):1–19 (in Bulgarian with English abstract)

    Google Scholar 

  • Vladykin N, Grozdanov L, Bonev I (2001) Chemical composition and geochemical characteristics of the Svidnya magmatic potassic-alkaline association, Western Stara Planina Mountain. Geochem Mineral Petrogr 38:3–22

    Google Scholar 

  • Von Raumer J, Finger F, Vesela P, Stampfli G (2014) Durbachites–Vaugnerites—a geodynamic marker in the central European Variscan orogen. Terra Nova 26:85–95

    Article  Google Scholar 

  • Watson B (1979) Zircon saturation in Felsic liquids: experimental results and applications to trace element geochemistry. Contrib Mineral Petrol 70:407–419

    Article  Google Scholar 

  • Watson B, Harrison T (1983) Zircon saturation revisited; temperature and composition effects in the variety of crustal magma types. Earth Planet Sci Lett 64:295–304

    Article  Google Scholar 

  • Wenzel T, Mercolli I, Oberhasli R (1991) The plutonic rocks of the Meissen Massif (Germany): evidence for open and closed system fractionation processes. Schweiz Miner Petrol 71:371–390

    Google Scholar 

  • Wilson M (1989) Igneous petrogenesis: a global tectonic approach. Chapman & Hall, London, p 466

    Book  Google Scholar 

  • Yanev S (2000) Palaeozoic terranes of the Balkan Peninsula in the framework of Pangea assembly. Palaeogeogr Palaeocl 161:151–177

    Article  Google Scholar 

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Acknowledgements

This paper benefited constructive comments of N. Georgiev and one anonymous reviewer. Editorial help and constructive suggestions of Wolf-Christian Dullo greatly improved the manuscript. M. D. acknowledge Sofia University—Geneva University bilateral cooperation for scientific exchange which made possible M. D. stay at Geneva University.

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Dyulgerov, M., Ovtcharova-Schaltegger, M., Ulianov, A. et al. Timing of K-alkaline magmatism in the Balkan segment of southeast European Variscan edifice: ID-TIMS and LA-ICP-MS study. Int J Earth Sci (Geol Rundsch) 107, 1175–1192 (2018). https://doi.org/10.1007/s00531-017-1527-0

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