Skip to main content
Log in

Ground states of a ternary system including attractive and repulsive Coulomb-type interactions

  • Published:
Calculus of Variations and Partial Differential Equations Aims and scope Submit manuscript

Abstract

We study a variational model where two interacting phases are embedded in a third neutral phase. The energy of the system is the sum of a local interfacial contribution and a nonlocal interaction of Coulomb type. Such models are e.g. used to describe systems of copolymer–homopolymer blends or of surfactants in water solutions. We establish existence and regularity properties of global minimizers, together with a full characterization of minimizers in the small mass regime. Furthermore, we prove uniform bounds on the potential of minimizing configurations, which in turn imply some qualitative estimates about the geometry of minimizers in the large mass regime. One key mathematical difficulty in the analysis is related to the fact that two phases have to be minimized simultaneously with both attractive and repulsive interaction present.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Acerbi, E., Fusco, N., Morini, M.: Minimality via second variation for a nonlocal isoperimetric problem. Commun. Math. Phys. 322, 515–557 (2013)

    Article  MathSciNet  MATH  Google Scholar 

  2. Alberti, G., Choksi, R., Otto, F.: Uniform energy distribution for an isoperimetric problem with long-range interactions. J. Am. Math. Soc. 22, 569–605 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  3. Almgren Jr., F.J.: Existence and regularity almost everywhere of solutions to elliptic variational problems with constraints. Mem. Am. Math. Soc. 4, 199 (1976)

    MathSciNet  MATH  Google Scholar 

  4. Ambrosio, L., Fusco, N., Pallara, D.: Functions of Bounded Variation and Free Discontinuity Problems. Oxford Mathematical Monographs, The Clarendon Press, Oxford University Press, New York (2000)

    MATH  Google Scholar 

  5. Barbosa, J.L., do Carmo, M.: Stability of hypersurfaces with constant mean curvature. Math. Z. 185, 339–353 (1984)

    Article  MathSciNet  MATH  Google Scholar 

  6. Bonacini, M., Cristoferi, R.: Local and global minimality results for a nonlocal isoperimetric problem on \(\mathbb{R}^N\). SIAM J. Math. Anal. 46, 2310–2349 (2014)

    Article  MathSciNet  MATH  Google Scholar 

  7. Bonacini, M., Knüpfer, H., Röger, M.: Optimal distribution of oppositely charged phases: perfect screening and other properties. SIAM J. Math. Anal. 48, 1128–1154 (2016)

    Article  MathSciNet  MATH  Google Scholar 

  8. Choksi, R., Peletier, M.A.: Small volume fraction limit of the diblock copolymer problem: I. Sharp-interface functional. SIAM J. Math. Anal. 42, 1334–1370 (2010)

    Article  MathSciNet  MATH  Google Scholar 

  9. Choksi, R., Peletier, M.A.: Small volume-fraction limit of the diblock copolymer problem: II. Diffuse-interface functional. SIAM J. Math. Anal. 43, 739–763 (2011)

    Article  MathSciNet  MATH  Google Scholar 

  10. Choksi, R., Ren, X.: On the derivation of a density functional theory for microphase separation of diblock copolymers. J. Stat. Phys. 113, 151–176 (2003)

    Article  MathSciNet  MATH  Google Scholar 

  11. Choksi, R., Ren, X.: Diblock copolymer/homopolymer blends: derivation of a density functional theory. Phys. D 203, 100–119 (2005)

    Article  MathSciNet  MATH  Google Scholar 

  12. Choksi, R., Sternberg, P.: On the first and second variations of a nonlocal isoperimetric problem. J. Reine Angew. Math. 611, 75–108 (2007)

    MathSciNet  MATH  Google Scholar 

  13. Cicalese, M., Spadaro, E.: Droplet minimizers of an isoperimetric problem with long-range interactions. Commun. Pure Appl. Math. 66, 1298–1333 (2013)

    Article  MathSciNet  MATH  Google Scholar 

  14. Cristoferi, R.: On periodic critical points and local minimizers of the Ohta-Kawasaki functional. Preprint (2015)

  15. Esposito, L., Fusco, N.: A remark on a free interface problem with volume constraint. J. Convex Anal. 18, 417–426 (2011)

    MathSciNet  MATH  Google Scholar 

  16. Figalli, A., Fusco, N., Maggi, F., Millot, V., Morini, M.: Isoperimetry and stability properties of balls with respect to nonlocal energies. Commun. Math. Phys. 336, 441–507 (2015)

    Article  MathSciNet  MATH  Google Scholar 

  17. Frank, R.L., Lieb, E.H.: A compactness lemma and its application to the existence of minimizers for the liquid drop model. SIAM J. Math. Anal. 47, 4436–4450 (2015)

    Article  MathSciNet  MATH  Google Scholar 

  18. Fuglede, B.: Stability in the isoperimetric problem. Bull. London Math. Soc. 18, 599–605 (1986)

    Article  MathSciNet  MATH  Google Scholar 

  19. Fuglede, B.: Stability in the isoperimetric problem for convex or nearly spherical domains in \({ R}^n\). Trans. Am. Math. Soc. 314, 619–638 (1989)

    MathSciNet  MATH  Google Scholar 

  20. Fusco, N., Maggi, F., Pratelli, A.: The sharp quantitative isoperimetric inequality. Ann. Math. 168(2), 941–980 (2008)

    Article  MathSciNet  MATH  Google Scholar 

  21. Gelbart, W.M., Ben-Shaul, A., Roux, D.: Micelles, Membranes, Microemulsions, and Monolayers. Springer-Verlag, New York (1994)

    Book  Google Scholar 

  22. Gilbarg, D., Trudinger, N.S.: Elliptic Partial Differential Equations of Second Order. Classics in Mathematics, Springer-Verlag, Berlin (2001)

    MATH  Google Scholar 

  23. Goldman, D., Muratov, C.B., Serfaty, S.: The \({\Gamma }\)-limit of the two-dimensional Ohta-Kawasaki energy. I. Droplet density. Arch. Ration. Mech. Anal. 210, 581–613 (2013)

    Article  MathSciNet  MATH  Google Scholar 

  24. Goldman, D., Muratov, C.B., Serfaty, S.: The \(\Gamma \)-limit of the two-dimensional Ohta-Kawasaki energy. II. Droplet arrangement via the renormalized energy. Arch. Ration. Mech. Anal. 212, 445–501 (2014)

    Article  MathSciNet  MATH  Google Scholar 

  25. Gonzalez, E., Massari, U., Tamanini, I.: Minimal boundaries enclosing a given volume. Manuscripta Math. 34, 381–395 (1981)

    Article  MathSciNet  MATH  Google Scholar 

  26. Ito, A.: Domain patterns in copolymer–homopolymer mixtures. Phys. Rev. E 58, 6158–6165 (1998)

    Article  Google Scholar 

  27. Julin, V.: Isoperimetric problem with a Coulomb repulsive term. Indiana Univ. Math. J. 63, 77–89 (2014)

    Article  MathSciNet  MATH  Google Scholar 

  28. Julin, V., Pisante, G.: Minimality via second variation for microphase separation of diblock copolymer melts. J. Reine Angew. Math. (2016)

  29. Knüpfer, H., Muratov, C.B.: On an isoperimetric problem with a competing non-local term. I. The planar case. Commun. Pure Appl. Math. 66, 1129–1162 (2013)

    Article  MATH  Google Scholar 

  30. Knüpfer, H., Muratov, C.B.: On an isoperimetric problem with a competing non-local term. II. The general case. Commun. Pure Appl. Math. 67, 1974–1994 (2014)

    Article  MATH  Google Scholar 

  31. Knüpfer, H., Muratov, C.B., Novaga, M.: Low density phases in a uniformly charged liquid. Commun. Math. Phys. 345, 141–183 (2016)

    Article  MathSciNet  MATH  Google Scholar 

  32. Landkof, N.S.: Foundations of Modern Potential Theory. Springer-Verlag, New York-Heidelberg (1972)

    Book  MATH  Google Scholar 

  33. Lieb, E.H., Loss, M.: Analysis. Graduate Studies in Mathematics, vol. 14, 2nd edn. American Mathematical Society, Providence, RI (2001)

    MATH  Google Scholar 

  34. Lu, J., Otto, F.: Nonexistence of minimizers for Thomas-Fermi-Dirac-von Weizsäcker model. Commun. Pure Appl. Math. 67, 1605–1617 (2014)

    Article  MathSciNet  MATH  Google Scholar 

  35. Lussardi, L., Peletier, M.A., Röger, M.: Variational analysis of a mesoscale model for bilayer membranes. J. Fixed Point Theory Appl. 15, 217–240 (2014)

    Article  MathSciNet  MATH  Google Scholar 

  36. Maggi, F.: Sets of Finite Perimeter and Geometric Variational Problems. Cambridge Studies in Advanced Mathematics, vol. 135. Cambridge University Press, Cambridge (2012)

    Book  Google Scholar 

  37. Morini, M., Sternberg, P.: Cascade of minimizers for a nonlocal isoperimetric problem in thin domains. SIAM J. Math. Anal. 46, 2033–2051 (2014)

    Article  MathSciNet  MATH  Google Scholar 

  38. Muratov, C.B., Zaleski, A.: On an isoperimetric problem with a competing non-local term: quantitative results. Ann. Glob. Anal. Geom. 47, 63–80 (2015)

    Article  MathSciNet  MATH  Google Scholar 

  39. Ohta, T., Ito, A.: Dynamics of phase separation in copolymer–homopolymer mixtures. Phys. Rev. E 52, 5250–5260 (1995)

    Article  Google Scholar 

  40. Ohta, T., Kawasaki, K.: Equilibrium morphology of block copolymer melts. Macromolecules 19, 2621–2632 (1986)

    Article  Google Scholar 

  41. Peletier, M.A., Röger, M.: Partial localization, lipid bilayers, and the elastica functional. Arch. Ration. Mech. Anal. 193, 475–537 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  42. Ren, X., Wei, J.: A double bubble in a ternary system with inhibitory long range interaction. Arch. Ration. Mech. Anal. 208, 201–253 (2013)

    Article  MathSciNet  MATH  Google Scholar 

  43. Simon, L.: Lectures on geometric measure theory. In: Proceedings of the Centre for Mathematical Analysis, vol. 3. Australian National University, Australian National University Centre for Mathematical Analysis, Canberra (1983)

  44. Sternberg, P., Topaloglu, I.: On the global minimizers of a nonlocal isoperimetric problem in two dimensions. Interfaces Free Bound. 13, 155–169 (2011)

    Article  MathSciNet  MATH  Google Scholar 

  45. van Gennip, Y., Peletier, M.A.: Copolymer-homopolymer blends: global energy minimisation and global energy bounds. Calc. Var. Partial Differ. Equ. 33, 75–111 (2008)

    Article  MathSciNet  MATH  Google Scholar 

  46. van Gennip, Y., Peletier, M.A.: Stability of monolayers and bilayers in a copolymer–homopolymer blend model. Interfaces Free Bound. 11, 331–373 (2009)

    Article  MathSciNet  MATH  Google Scholar 

Download references

Acknowledgments

MB is member of the INdAM-GNAMPA Project 2015 “Critical Phenomena in the Mechanics of Materials: a Variational Approach”. MB and HK would like to thank the Mathematics Center Heidelberg (MATCH) for support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Marco Bonacini.

Additional information

Communicated by L. Ambrosio.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bonacini, M., Knüpfer, H. Ground states of a ternary system including attractive and repulsive Coulomb-type interactions. Calc. Var. 55, 114 (2016). https://doi.org/10.1007/s00526-016-1047-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00526-016-1047-y

Mathematics Subject Classification

Navigation