Abstract
The spatial distribution of residual light non-aqueous phase liquid (LNAPL) is an important factor in reactive solute transport modeling studies. There is great uncertainty associated with both the areal limits of LNAPL source zones and smaller scale variability within the areal limits. A statistical approach is proposed to construct a probabilistic model for the spatial distribution of residual NAPL and it is applied to a site characterized by ultra-violet-induced-cone-penetration testing (CPT–UVIF). The uncertainty in areal limits is explicitly addressed by a novel distance function (DF) approach. In modeling the small-scale variability within the areal limits, the CPT–UVIF data are used as primary source of information, while soil texture and distance to water table are treated as secondary data. Two widely used geostatistical techniques are applied for the data integration, namely sequential indicator simulation with locally varying means (SIS–LVM) and Bayesian updating (BU). A close match between the calibrated uncertainty band (UB) and the target probabilities shows the performance of the proposed DF technique in characterization of uncertainty in the areal limits. A cross-validation study also shows that the integration of the secondary data sources substantially improves the prediction of contaminated and uncontaminated locations and that the SIS–LVM algorithm gives a more accurate prediction of residual NAPL contamination. The proposed DF approach is useful in modeling the areal limits of the non-stationary continuous or categorical random variables, and in providing a prior probability map for source zone sizes to be used in Monte Carlo simulations of contaminant transport or Monte Carlo type inverse modeling studies.
Similar content being viewed by others
References
Alostaz M, Biggar KW, Donahue R, Hall G (2008) Petroleum contamination characterization and quantification using fluorescence emission-excitation matrices (EMMs) and parallel factor analysis (PARAFAC). J Environ Eng Sci 7(3):183–197
American Petroleum Institute (2004) API Interactive LNAPL Guide Version 2. Environmental Systems and Technologies, Blacksburg, VA
Aral MM, Guan J, Masila ML (2001) Identification of contaminant source location and release history in aquifers. J Hydrol Eng 6:225–234
Bridge JS, Leeder MR (1979) A simulation model of alluvial stratigraphy. Sedimentology 26(5):617–644
Campanella RG, Robertson PK (1988) Current status of the piezocone test. In: De Ruiter J (ed) Proceedings of cone penetration testing, vol I, pp 93–116. ISOPT-1, Orlando
Chen MJ, Keller AA, Zhang DX, Lu ZM, Zyvoloski GA (2006) A stochastic analysis of transient two-phase flow in heterogeneous porous media. Water Resour Res 42(3):W03425
Chen MJ, Keller AA, Lu ZM (2009) Stochastic analysis of transient three-phase flow in heterogeneous porous media. Stoch Environ Res Risk Assess 23:93–109
Christ JA, Ramsburg CA, Pennell KD, Abriola LM (2006) Estimating mass transfer from dense nonaqueous phase liquid source zones using upscaled mass transfer coefficients: an evaluation using multiphase numerical simulations. Water Resour Res 42(11):W11420
Cowan E, Beatson R, Ross H, Fright W et al. (2003) Practical implicit geological modeling. In: Proceedings of 5th international mining geology conference, 17–19 November, Bendigo, Victoria, Australia
D’Affonseca FM, Blum P, Finkel M, Melzer R, Grathwohl P (2008) Field-scale characterization and modeling of contaminant release from a coal tar source zone. J Contam Hydrol 102:120–139
Deutsch CV (2002) Geostatistical reservoir modeling. Oxford University Press, New York
Deutsch CV (2006) A sequential indicator simulation program for categorical variables with point and block data. Comput Geosci 32(10):1669–1681
Deutsch CV, Journel AG (1998) GSLIB: geostatistical library and user’s guide, 2nd edn. Oxford University Press, New York
Dillard LA, Essaid HI, Herkelrath WN (1997) Multiphase flow modeling of a crude-oil spill site with a bimodal permeability distribution. J Contam Hydrol 48(1–2):89–119
Essaid HI, Hess KM (1993) Monte Carlo simulations of multiphase flow incorporating spatial variability of hydraulic properties. Ground Water 31(1):123–134
Essaid HI, Herkelrath WN, Hess KM (1993) Simulation of fluid distributions observed at a crude-oil spill site incorporating hysteresis, oil entrapment, and spatial variability of hydraulic properties. Water Resour Res 29(6):1753–1770
Gorelick SM, Evans BE, Remson I (1983) Identifying sources of groundwater pollution: an optimization approach. Water Resour Res 19(3):779–790
Houlding SW (1994) 3D geoscience modeling: computer techniques for geological characterization. Springer, Berlin
Huntley D, Beckett GD (2002) Persistence of LNAPL sources: relationship between risk reduction and LNAPL recovery. J Contam Hydrol 59:3–26
Journel AG (2002) Combining knowledge from diverse sources: and alternative to traditional data independence hypotheses. Math Geol 34(5):573–596
Journel AG, Gomez-Hernandez JJ (1993) Stochastic imaging of the Wilmington clastic sequence. SPE Form Eval 8(1):33–40
Kueper BH, Gerhard JI (1995) Variability of point source infiltration rates for two-phase flow in heterogeneous porous media. Water Resour Res 31(12):2971–2980
Mahar PS, Datta B (2001) Optimal identification of groundwater pollution sources and parameter estimation. J Water Resour Plan Manag 131(1):45–57
McLennan JA (2007) The decision of stationarity. PhD Thesis, University of Alberta, Edmonton, Alberta, Canada
Neupauer RM, Lin R (2006) Identifying sources of a conservative groundwater contaminant using backward probabilities conditioned on measured concentrations. Water Resour Res 42(3):W03424
Parker JC, Islam M (2000) Inverse modeling to estimate LNAPL plume release timing. J Contam Hydrol 45(3–4):303–327
Parker JC, Park E (2004) Modeling field-scale dense nonaqueous phase liquid dissolution kinetics in heterogeneous aquifers. Water Resour Res 40(5):W05109
Pyrcz M, Catuneanu O, Deutsch CV (2005) Stochastic surface-based modeling of turbidite lobes. AAPG Bull 89(2):177–191
Robertson PK, Campanella RG (1983) Interpretation of cone penetration tests, part I: sand. Can Geotech J 20(4):718–733
Rojas-Avellaneda D, Silvan-Cardenas JL (2006) Performance of geostatistical interpolation methods for modeling sample data with non-stationary mean. Stoch Environ Res Risk Asses 20(6):455–467
Sciortino A, Harmon TC, Yeh WG (2000) Inverse modeling for locating dense nonaqueous pools in groundwater under steady flow conditions. Water Resour Res 36(7):1723–1735
Sidauruk PA, Cheng HD, Ouzar D (1998) Groundwater contaminant source and transport parameter identification by correlation coefficient optimization. Ground Water 26(2):208–214
Snodgrass MF, Kitanidis PK (1997) A geostatistical approach to contaminant source identification. Water Resour Res 33(4):537–546
Sun AY, Painter SL, Wittmeyer GW (2006) A constrained robust least squares approach for contaminant release history identification. Water Resour Res 42(4):W04414
Van Genuchten M (1980) A closed form equation for predicting the hydraulic conductivity of unsaturated soils. Soil Sci Soc Am J 44:892–898
Wagner BJ (1992) Simultaneously parameter estimation and contaminant source characterization for coupled groundwater flow and contaminant transport modeling. J Hydrol 135:275–303
Wilson JL, Liu J (1994) Backward tracking to find the source of pollution. Waste Manag Risk Remediat 1:181–199
Yeh HD, Chang TH, Lin YC (2007) Groundwater contaminant source identification by a hybrid heuristic approach. Water Resour Res 43(9):W09420
Zhang Z, Tumay MT (2003) Non-traditional approaches in soil classification derived from the cone penetration test. In: Van Marcke E, Fenton GA (eds) Probabilistic site characterization at the national geotechnical experimentation sites, pp 101–149. ASCE, Reston VA
Zhu J (2001) Transport and fate of nonaqueous phase liquid (NAPL) in variably saturated porous media with evolving scales of heterogeneity. Stoch Environ Res Risk Assess 15(6):447–461
Acknowledgements
The first author would like to thank the Alberta Ingenuity Fund for providing partial support for this study. Data for the contaminated site was obtained from the University of Alberta Consortium for Research on Natural Attenuation (CORONA) program, jointly sponsored by NSERC and the oil and gas industry.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hosseini, A.H., Deutsch, C.V., Biggar, K.W. et al. Probabilistic data integration for characterization of spatial distribution of residual LNAPL. Stoch Environ Res Risk Assess 24, 735–749 (2010). https://doi.org/10.1007/s00477-009-0360-9
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00477-009-0360-9