Abstract
We report on electron-stimulated desorption (ESD) of O- ions from δ phase O2 physisorbed on graphite. A production of energetic O- ions is observed with an onset at about 13 eV. The measured onset of the yield of O+ ions is however found at about 20 eV. O- ions yields obtained at different ion kinetic energies and kinetic energy (KE) measurements lead us to postulate a substrate mediated ESD mechanism following direct electronic excitation of physisorbed O2.
Similar content being viewed by others
References
Guest, R.J., Goldby, I.M., Palmer, R.E., Bly, D.N., Hartley, D.M., Rous, P.J.: J. Chem. Soc. Faraday Discussions 96, 117 (1993); Palmer, R.E.: Surf. Sci. 307-309, 335 (1994)
Huels, M.A., Parenteau, L., Michaud, M., Sanche, L.: Phys. Rev. A 51, 337 (1995)
Azria, R., Le Coat, Y., Ziesel, J.P., Guillotin, J.P., Mharzi, B., Tronc, M.: Chem. Phys. Lett. 220, 417 (1994)
Azria, R., Parenteau, L., Sanche, L.: Phys. Rev. Lett. 59, 638 (1987)
Sambe, H., Ramaker, D.E., Parenteau, L., Sanche, L.: Phys. Rev. Lett. 59, 236 (1987)
Palmer, R.E.: Prog. Surf. Sci. 41, 51 (1992)
Sanche, L.: Phys. Rev. Lett. 53, 1638 (1984)
Siller, L., Bennett, S.L., MacDonald, M.A., Bennett, R.A., Palmer, R.E., Foord, J.S.: Phys. Rev. Lett. 76, 1960 (1996)
Ying, Z., Ho, W.: Phys. Rev. Lett. 60, 57 (1988)
Buntin, S.A., Richter, L.J., Cavanagh, R.R., King, D.S.: Phys. Rev. Lett. 61, 1321 (1988)
Gadzuk, J.W., Richter, L.J., Buntin, S.A., King, D.S., Cavanagh, R.R.: Surf. Sci. 235, 317 (1990)
Dixon-Warren, St.-J., Jensen, E.T., Polanyi, J.C.: Phys. Rev. Lett. 67, 2395 (1991)
Aumayr, F., Winter, H.: Comments At. Mol. Phys. 29, 275 (1994)
Gadzuk, J.W.: Comments At. Mol. Phys. 5, 219 (1985)
Kleyn, A.W.: Proceedings of the 16th International Conference on the Physics of Electronic and Atomic Collisions. Dalgarno A., Freund, R.S., Koch, P.M., Lubell, M.S., Lucatorto, T.B. (eds). AIP Conf. Proc. NY No. 205, 451 (1989)
Jensen, E.T., Palmer, R.E., Rous, P.J.: Phys. Rev. Lett. 64, 1301 (1990)
Jensen, E.T., Palmer, R.E., Rous, P.J.: Surf. Sci. 237, 153 (1990)
Guest, R.J., Bennett, R.A., Silva, L.A., Sharpe, R.C., Barnard, J.C., Palmer, R.E., MacDonald, M.A.: Desorption induced by electron transitions DIET V. Springer Series in Surface Sciences, Vol. 31.: Burns, A.R., Stechel, E.B., Jennison, D.R. (eds.). Berlin, Heidelberg, New York: Springer 1993
Hall, R.I., Cadez, I., Scherman, C., Tronc, M.: Phys. Rev. A 15, 599 (1977)
Tronc, M., Malegat, L., Azria, R.: Chem. Phys. Lett. 92, 551 (1982)
Locht, R., Momigny, J.: Int. J. Mass Spectrom. Ion Phys. 7, 121 (1971)
Delon, P.: Ph.D. Thesis. Université Pierre et Marie Curie, Paris, France 1979
Huber, K.P., Herzberg, G.: Molecular spectra and molecular structure, vol. 4. New York: Van Nostrand Reinhold 1979
Hotop, H., Lineberger, W.C.: J. Phys. Chem. Ref. Data 147, 31 (1985)
Nilsson, A., Palmer, R.E., Tillborg, H., Hernnas, B., Guest, R.J., Martensson, N.: Phys. Rev. Lett. 68, 982 (1992)
Laitenberger, P., Palmer, R.E.: Chem. Phys. Lett. 246, 79 (1996)
Michels, H.H.: Adv. Chem. Phys. 45, 225 (1981)
Jaffke, T., Hashemi, R., Christophorou, L.G., Illenberger, E., Baumgartel, H., Pinnaduwage, L.A.: Chem. Phys. Lett. 203, 21 (1993)
Pinnaduwage, L.A., Christophorou, L.G.: Phys. Rev. Lett. 70, 754 (1993)
Pinnaduwage, L.A., Christophorou, L.G., Bitouni, A.P.: J. Chem. Phys. 95, 274 (1991)
Bahrim, B., Teillet-Beilly, D., Gauyacq, J.P.: Surf. Sci. 316, 189 (1994)
Bahrim, B., Teillet-Beilly, D., Gauyacq, J.P.: Phys. Rev. Lett. B 50, 7860 (1994)
Tang, K.B.K., Azria, R., Le Coat, Y., Tronc, M., Hedhili, N., Bahrim, B., Palmer, R.E.: (to be published)
Author information
Authors and Affiliations
Additional information
Unité de Recherche associée au CNRS, URA 0281
Unité de Recherche associée au CNRS, URA 0176
Rights and permissions
About this article
Cite this article
Tang, K.B.K., Azria, R., Le Coat, Y. et al. O- ESD from O2 monolayers physisorbed on graphite: a surface mediated mechanism. Z Phys D - Atoms, Molecules and Clusters 38, 41–44 (1996). https://doi.org/10.1007/s004600050061
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s004600050061