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Effect of Mg doping on ZnO fabricated using aqueous leaf extract of Ziziphus mauritiana Lam. for antioxidant and antibacterial studies

Abstract

Aqueous leaf extract of Ziziphus mauritiana Lam. was successfully used to synthesize zinc oxide (ZnO) and magnesium-doped ZnO (Mg-doped ZnO) particles and acted as capping and stabilizing agent. UV–Vis diffuse reflectance spectra showed that optical band gap energy of ZnO has narrowed from 3.11 to 3.08 eV and 3.03 eV when doped with 1% Mg and 5% Mg, respectively. Powder X-ray diffraction and X-ray photoelectron spectroscopy studies confirmed the purity and crystalline nature of the synthesized materials. FT-IR spectroscopy revealed the presence of phytochemicals coated on the surface of synthesized materials. The synthesized materials were found to effectively scavenge DPPH radicals in the presence of visible light in comparison to the dark. The antibacterial properties of the synthesized materials were evaluated against Staphylococcus aureus and Escherichia coli. The obtained results revealed that Staphylococcus aureus seemed to be more sensitive to the green synthesized ZnO and Mg-doped ZnO than Escherichia coli.

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Acknowledgements

Authors would like to acknowledge the FIC block grant UBD/RSCH/1.4/FICBF(b)/2018/012 received from Universiti Brunei Darussalam, Brunei Darussalam.

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AR: Methodology, investigation, data curation, writing–original draft. MHH: Supervision, writing, review & editing. ALT: Supervision, writing, review & editing. NA: Supervision, review & editing particularly the antibacterial section. MH: Resources & formal analysis. MMK: Supervision, conceptualization, funding acquisition, writing, review & editing.

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Correspondence to Mohammad Mansoob Khan.

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Rahman, A., Harunsani, M.H., Tan, A.L. et al. Effect of Mg doping on ZnO fabricated using aqueous leaf extract of Ziziphus mauritiana Lam. for antioxidant and antibacterial studies. Bioprocess Biosyst Eng 44, 875–889 (2021). https://doi.org/10.1007/s00449-020-02496-1

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Keywords

  • Ziziphus mauritiana Lam.
  • Zinc oxide
  • ZnO
  • Mg-doped ZnO
  • Aqueous leaf extract
  • Antioxidant activities
  • Antibacterial studies