Abstract
Three kinds of membranes were prepared from suspensions containing polyacrylonitrile, dimethyl sulfoxide, polyethylene glycol and different amount of Fe3O4 by the phase inversion process. The rejection rate and the flux of membrane were investigated in the filtration of pig blood solution. SEM also studied the morphologies of fouled membranes. The permeate flux and the rejection rate decline fast in the initial several minutes and then change slowly. The magnetized membrane has a higher flux and a relative flux than the corresponding non-magnetized membrane. And the magnetized membrane containing about 3 wt% Fe3O4 has a prominent anti-fouling performance with above 52% relative flux. The results indicate that the magnetized ferrosoferric oxide–polyacrylonitrile membranes are promising in the recovery of blood proteins in the slaughterhouse effluents. In addition, the hydraulic resistance model explained results and the fouling mechanism was also given.
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Abbreviations
- A :
-
membrane area (m2)
- C f :
-
concentration of feed (mg L−1)
- C p :
-
concentration of permeate (mg L−1)
- J b :
-
pig blood solution flux (L m−2 h−1)
- J bp :
-
pure water flux through a fouled membrane (L m−2 h−1)
- J p :
-
pure water flux (L m−2 h−1)
- J r :
-
relative water flux (%)
- R 0 :
-
apparent membrane rejection rate (%)
- R a :
-
hydraulic resistance of the absorbed layer (m−1)
- R b :
-
rejection rate of pig blood solution (%)
- R m :
-
hydraulic membrane resistance (m−1)
- t :
-
filtration time
- V :
-
permeate volume (L)
- μ :
-
water viscosity at 25°C (0.0089 Pa s)
- ΔP :
-
operation pressure (P a)
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The National Natural Science Foundation of China (Project No.20476023) and the Education Department of Hubei Province (Project No. 2001A02003) funded this work.
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Huang, ZQ., Guo, XP., Guo, CL. et al. Magnetization influence on the performance of ferrosoferric oxide: polyacrylonitrile membranes in ultrafiltration of pig blood solution . Bioprocess Biosyst Eng 28, 415–421 (2006). https://doi.org/10.1007/s00449-006-0050-7
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DOI: https://doi.org/10.1007/s00449-006-0050-7