Skip to main content

Advertisement

Log in

Hydrogeochemical temporal variations related to changes of seismic activity at Tenerife, Canary Islands

  • Research Article
  • Published:
Bulletin of Volcanology Aims and scope Submit manuscript

Abstract

This work presents the results of a hydrogeochemical study conducted in two galleries on the island of Tenerife: Fuente del Valle and San Fernando, during a 2-year period with weekly sampling (July 2016 to July 2018). Groundwater temperature, pH, and electrical conductivity exhibited stable values throughout the study period, while significant temporal variations were observed in the total alkalinity, SO42−/Cl ratio (in meq·L−1), and isotopic composition (δ18O and δD). δ13CTDIC values showed an endogenous signature for both galleries, while δ18O and δD values indicated a meteoric origin with interaction with endogenous gases, mainly CO2. Changes in isotopic ratios coincided with variations observed in alkalinity and SO42−/Cl ratio. On October 2, 2016, a seismic swarm of long-period events was recorded on Tenerife followed by a general increase of the seismic activity in and around the island. A correlation was observed between some hydrogeochemical parameters in the groundwaters of the galleries related to observed changes of the seismic activity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  • Ancochea E, Fuster JM, Ibarrola E, Cendrero A, Coello J, Hernan F, Cantagrel JM, Jamond C (1990) Volcanic evolution of the island of Tenerife (Canary Islands) in the light of new K-Ar data. J Volcanol Geoth Res 44:231–249

    Article  Google Scholar 

  • Capasso G, Inguaggiato S (1998) A simple method for the determination of dissolved gases in natural waters: an application to thermal waters from Vulcano Island. Appl Geochem 13:631–642

    Article  Google Scholar 

  • Chiodini G (2006) Resolving magmatic vs. hydrothermal fluid components at volcanoes. En: Garavolcán-Conferencia Internacional Conmemorativa del 300 Aniversario de la Erupción Volcánica de Arenas Negras en 1706, Tenerife, Islas Canarias, España. Held in Garachico, May 22-27, 2006

  • Consejo Insular de Aguas de Tenerife (CIATF) (2018) Censo de instalaciones subterráneas, galerías y pozos, de la Isla de Tenerife. https://www.aguastenerife.org/9_OCAS/pdf/OCAS_InfGeneral_2018_corto.pdf

  • Coplen TB, Wildman JD (1991) Improvements in the gaseous hydrogen-water equilibration technique for hydrogen isotope ratio analysis. Anal Chem 63:910–912

    Article  Google Scholar 

  • Craig H (1961) Isotopic variations in meteoric waters. Science 133:1702–1703

    Article  Google Scholar 

  • Custodio E (1986) Groundwater characteristics and problems in volcanic rock terrains Isotope techniques in the study of hydrology of fractured and fissured rocks Proceedings of An Advisor Group Meeting. Agencia Internacional de la Energía Atómica Viena

  • Custodio E (1988) Hidrogeochemistry of Tenerife Island. Revista Española de Hidrogeología. Asociación Española de Hidrogeología Subterránea 3:1–19

  • Custodio E (2009) Estimation of aquifer recharge by means of atmospheric chloride deposition balance in the soil. Contributions to Science I 5:2

    Google Scholar 

  • Custodio E, Llamas MR (1976) Hidrología Subterránea, 2nd edn. Omega, Barcelona, pp 1974–1983

    Google Scholar 

  • Custodio E, Cabrera MC, Poncela R, Puga LO, Skupien E, Villar A (2016) Groundwater intensive exploitation and mining in Gran Canaria and Tenerife, Canary Islands, Spain: hydrogeological, environment, economic and social aspects. Sci Total Environ 557-558:425–437

    Article  Google Scholar 

  • D’Auria L, Barrancos J, Padilla GD, Pérez NM, Hernández PA, Melián G, Padron E, Asensio-Ramos M, García-Hernández R (2019) The 2016 Tenerife (Canary Islands) long-period seismic swarm. J Geophys Res 124:8739–8752

    Article  Google Scholar 

  • Deines P, Langmuir D, Harmon RS (1974) Stable carbon isotopes ratios and the existence of a gas phase in the evolution of carbonate groundwater. Geochim Cosmochim 38:1147–1164

    Article  Google Scholar 

  • Eff-Darwich A, Coello J, Viñas R, Soler V, Martin-Luis MC, Farrujia I, Quesada ML, Nuez J (2008) Underground temperature measurements as a tool for volcanic activity monitoring in the island of Tenerife, Canary Islands. Pure Appl Geophys 165:135–145

    Article  Google Scholar 

  • Epstein S, Mayeda T (1953) Variation of 18O contents of waters from natural sources. Geochemica et Cosmochimica 4:213–224

    Article  Google Scholar 

  • Evans WC, Sorey ML, Cook AC, Kennedy M, Shuster DL, Colvard EM, White LD, Huebner MA (2002) Tracing and quantifying magmatic carbon discharge in cold groundwaters: lessons learned from Mammoth Mountain USA. J Volcanol Geotherm Res 114:291–312

    Article  Google Scholar 

  • Federico C, Aiuppa A, Allard P, Bellomo S, Jean-Baptiste J, Parello F, Valenza M (2002) Magma-derived gas influx and water-rock interactions in the volcanic aquifer of Mt. Vesuvius, Italy. Geochim Cosmochim Acta 66:963–981

    Article  Google Scholar 

  • Federico C, Aiuppa A, Favara R, Gurrieri S, Valenza M (2004) Geochemical monitoring of groundwaters (1998-2001) at Vesuvius volcano (Italy). J Volcanol Geotherm Res 133:81–104

    Article  Google Scholar 

  • Galindo I (2005) Estructura Volcano-tectónica y emisión difusa de gases de Tenerife Islas Canarias. Universidad de Barcelona

  • Gambardella B, Cardellini C, Frondini G, Marini F, Ottonello L, Zuccolini M (2004) Fluxes of Deep CO2 in the volcanic areas of central-southern Italy. J Volcanol Geotherm Res 136:31–52

    Article  Google Scholar 

  • García R (1989) Erupciones históricas en Tenerife Los volcanes y la caldera del Parque Nacional del Teide (Tenerife Islas Canarias) Araña V y Coello J (Eds). Publicaciones de ICONA Serie Técnica 7:235-249

  • Giggenbach W (1992) Isotopic shifts in waters from geothermal and volcanic systems along convergent plate boundaries and their origin. Earth Planet Sci Lett 113:495–510

    Article  Google Scholar 

  • Giggenbach W (1997) Relative importance of thermodynamic and kinetic processes in governing the chemical and isotopic composition of carbon gases in high-heatflow sedimentary basins. Geochim Cosmochim Acta 61:3763–3785

    Article  Google Scholar 

  • Grassa F, Capasso G, Favara R, Inguaggiato S (2006) Chemical and isotopic composition of waters and dissolved gasses in some thermal springs of Sicily and adjacent Volcanic Islands, Italy. Pure Appl Geophys 163:781–807

    Article  Google Scholar 

  • Hernández PA, Notsu K, Salazar JM, Mori T, Natale G, Okada H, Virgili G, Shimoike Y, Sato M, Pérez NM (2001) Carbon dioxide degassing by advective flow from Usu Volcano, Japan. Science 292:83–86

    Article  Google Scholar 

  • Hernández PA, Pérez N, Padrón E, Melian G (2006) Continuous monitoring of dissolved gases by means of QMS and radon sensors for Tenerife’s volcanic surveillance, Garavolcan International Meeting. Session 6: Tenerife‘s experience: scientific results and the recent seismicvolcanic crisis, Garachico, Tenerife, Spain

  • Hernández PA, Padilla G, Barrancos J, Melián G, Padrón E, Asensio-Ramos M, Rodríguez F, Pérez NM, Alonso M, Calvo D (2017) Geochemical evidences of seismo-volcanic unrests at the NW rift zone of Tenerife, Canary Islands, inferred from diffuse CO2 emission. Bull Volcanol 79:1–21

    Article  Google Scholar 

  • Inguaggiato S, Pecoriano G, D’Amore F (2000) Chemical and isotopical characterization of fluid manifestations of Ischia Island (Italy). J Volcanol Geoth Res 99:151–178

    Article  Google Scholar 

  • Inguaggiato S, Martin-Del Pozzo AL, Aguayo A, Capasso G, Favara R (2005) Isotopic, chemical and dissolved gas constraints on spring water from Popocatepetl volcano (México): evidence of gas-water interaction between magmatic component and shallow fluids. J Volcanol Geoth Res 141:91–108

    Article  Google Scholar 

  • Jasim A, Hemmings B, Mayer K, Scheu B (2018) Groundwater flow and volcanic unrest. In: Neuberg J, Scheu B (eds) Gottsmann J. Springer, Volcanic Unrest, pp 83–89

    Google Scholar 

  • King CY (1986) Gas geochemistry applied to earthquake prediction: an overview. J Geophys Res 91(B12):12269–12281

    Article  Google Scholar 

  • López C, Blanco M, Carreño E (2006) Analysis of IGN seismic series in Tenerife that triggered the 2004 seismovolcanic alert. Garavolcan International Meeting Session 6: Tenerife’s experience: scientific result and the recent seismovolcanic crisis

  • Marrero R (2010) Modelo Hidrogeoquímico del acuífero de Las Cañadas del Teide Tenerife Islas Canarias Universidad Politécnica de Cataluña

  • Marrero R, Lopez D, Hernandez PA, Pérez NM (2008) Carbon dioxide discharged through Las Cañadas aquifer Tenerife Canary Islands. Pure Appl Geophys 165:147–172

    Article  Google Scholar 

  • Marrero R, López D, Pérez NM, Custodio E, Sumino H, Melián G, Padrón E, Hernández PA, Calvo D, Barrancos J, Padilla GD, Sortino F (2015) Carbon dioxide and helium dissolved gases in groundwater at central Tenerife Island Canary Islands: chemical and isotopic characterization. Bull Volcanol 77:1–18

    Google Scholar 

  • Martí J, Mitjavila J, Araña V (1994) Stratigraphy structure and geochronology of the Las Cañadas caldera (Tenerife Canary Islands). Geol Mag 131:715–727

    Article  Google Scholar 

  • Martín-del-Pozo AL, Inguaggiato S, Aceves F, Saenz H, Aguayo A (2002) Spring water and CO2 interaction at Popocatépetl volcano, Mexico. Geofis int 41:345-351

  • Melián G, Tassi F, Pérez NM, Hernández PA, Sortino F, Vaselli O, Padrón E, Nolasco D, Barrancos J, Padilla GD, Rodríguez F, Dionis S, Calvo D, Notsu K, Sumino HA (2012) Magmatic source for fumaroles and diffuse degassing from the summit crater of Teide volcano (Tenerife Canary Islands): a geochemical evidence for the 2004–2005 seismic–volcanic crisis. Bull Volcanol 74:1465–1483

    Article  Google Scholar 

  • Melián G, Hernández PA, Padrón E, Pérez NM, Barrancos J, Padilla G, Dionis S, Rodríguez F, Calvo D, Nolasco D Spatial and temporal variations of diffuse CO2 degassing at El Hierro volcanic system: relation to the 2011–2012 submarine eruption. J Geophys Res Solid Earth 119:6976–6991

  • Instituto Volcanológico de Canarias (INVOLCAN) (2017) Monthly Bulletin. http://www.involcan.org/wp-content/uploads/2017/02/bol_2017_01.pdf

  • O’Neil JR, King C-Y (1981) Variations in stable-isotope ratios of ground waters in seismically active regions of California. Geophys Res Lett 8:429–432

  • Padrón E, Melián G, Marrero R, Nolasco D, Barrancos J, Padilla G, Hernández PA, Pérez NM (2008) Changes on diffuse CO2 emission and relation to seismic activity in and around El Hierro, Canary Islands, Spain. PAGEOPH Topical Volume, Terrestrial Fluids, Earthquakes and Volcanoes: The Hiroshi Wakita Volume III (in press).

  • Paternoster M, Liotta M, Favar R (2008) Stable isotope ratios in meteoric recharge an groundwater at Mt Vultere volcano southern Italy. J Hidrol 348:87–97

    Article  Google Scholar 

  • Pérez NM and Hernández PA (2007) Earthquake forecasting research in active volcanic areas by means of diffuse CO2 emission studies. Geochemical Precursors for Earthquakes, MacMillan Advanced Research Series 94–103

  • Pérez NM, Williams SN, Sano Y, Carracedo JC, Coello J, Wakita H (1992) Helium-3 emission from the canarian volcanoes Spain, III Congreso Geológico de España y VIII Congreso Latinoamericano de Geología. Salamanca Actas Tomo 1:469–472

    Google Scholar 

  • Pérez NM, Nakai S, Wakita H, Hernández PA, Salazar JM (1996a) Helium-3 emissions distribution in and around Teide volcano Tenerife Canary Islands Spain. Geophys Res Lett 23:3531–3534

    Article  Google Scholar 

  • Pérez NM, Sturchio NC, Arehart G, Hernandez PA, Wakita H (1996b) Short-term secular variations of carbon and radon isotopes and relation to seismic activity in the Canary Islands Spain. Bull Lab Earthquake Chem 31-33

  • Pérez NM, Sturchio NC, Williams SN, Carracedo JC, Coello J (1998) Geochemical characteristics of the volcanic-hydrothermal gases in Teide Timanfaya Taburiente and Teneguia volcanoes, Canary Islands, Spain. III Congreso Geológico de España y VIII Congreso Latinoamericano de Geología. Salamanca Actas tomo 1:463–468

    Google Scholar 

  • Pérez NM, Salazar JML, Navarro JM, Chiodini G, Hernández PA (1999) Hydrogeochemical monitoring of the seismic-volcanic activity at Mt Teide Tenerife Canary Islands Spain IUGG. Fall Meeting Abstract B94

  • Pérez NM, Hernández PA, Padrón E, Melián G, Marrero R, Padilla G, Barrancos J, Nolasco D (2007) Precursory subsurface 222Rn and 220Rn degassing signatures of the 2004 seismic crisis at Tenerife Canary Islands. Pure Appl Geophys 164:2431–2448

    Article  Google Scholar 

  • Pérez NM, Hernández PA, Igarashi G, Trujillo I, Nakai S, Sumino H, Wakita H (2008) Searching and detecting earthquake geochemical precursors in CO2-rich groundwaters from Galicia, Spain. Geochem J 42:75–83

    Article  Google Scholar 

  • Pérez NM, Hernández PA, Padrón E, Melián G, Nolasco D, Barrancos J, Padilla GD, Calvo D, Rodriguez F, Dionis S, Chiodini G (2013) An increasing trend of diffuse CO2 emission from Teide volcano (Tenerife Canary Islands): geochemical evidence of magma degassing episodes. J Geol Soc Lon 170:585–592

    Article  Google Scholar 

  • Pérez NM, Melián G, Asensio-Ramos M, Padrón E, Hernández PA, Alonso M, Rodríguez F, Padilla GD, Amonte C, García-Merino M, Burns F, Morales C, García E, Vela V, Pérez A, García R, Barrancos J, Calvo D (2017) Observed anomalous changes on diffuse CO2 emission at the summit crater of Teide volcano (Tenerife Canary Islands Spain): a geochemical evidence of volcanic unrest? European Geosciences Union Meeting, Viena

    Google Scholar 

  • Plan Hidrológico de Tenerife (PHT) (2015) Decreto 319/1996 de 23 de diciembre. Boletín Oficial de Canarias

  • Plan Hidrológico Insular (PHI) (1996) Decreto 319/1996 de 23 de diciembre. Boletín Oficial de Canarias

  • Romero C (1992) Estudio geomorfológico de los volcanes históricos de Tenerife Aula de cultura de Tenerife Cabildo Insular 265

  • Salazar JML, Pérez NM, Hernández PA, Soriano T, Barahona F, Olmos R, Cartagena R, López D, Lima N, Melián G, Galindo I, Padrón E, Sumino H, Notsu K (2002) Precursory diffuse carbon dioxide degassing signature related to a 5.1 magnitude earthquake in El Salvador, Central America. Earth Planet Sci Lett 205:81–89

    Article  Google Scholar 

  • Sinclair AJ (1974) Selection of thresholds in geochemical data using probability graphs. J Geochem Explor 3:129–149

    Article  Google Scholar 

  • Tennant C, White M (1959) Study of the distribution of some geochemical data. Ec Geol 54:1281–1290

    Article  Google Scholar 

  • Thomas D (1988) Geochemical precursors to seismic activity. Pure Appl Geophys 126:241–265

    Article  Google Scholar 

  • Veeger A.I (1991) Geochemical methods for evaluating the origin and evolution of ground water in volcanic rocks. Tesis Doctoral, University of Arizona 241

  • Wakita H, Fuji N, Matsuo S, Notsu K, Nagao K, Takaoka N (1978) “Helium spots”: caused by a diapiric magma from the upper mantle. Science 200:430–432

    Article  Google Scholar 

  • Zaliapin I, Ben-Zion Y (2013) Earthquake clusters in southern California I: identification and stability. J Geophys Res Solid Earth 118:2847–2864

    Article  Google Scholar 

  • Zhang W (1994) Research on hydrogeochemical precursors of earthquakes. J Earthq Prediction Res 3:170–182

    Google Scholar 

  • Zhang J, Quay PD, Wilbur DO (1995) Carbon isotope fractionation during gas-water exchange and dissolution of CO2. Geochimica et Cosmochimica 59:107–114

    Article  Google Scholar 

Download references

Acknowledgements

We thank Dr. Matthew James Pankhurst for his contribution to improve the quality of this paper. We also thank the Community of Waters of Fuente del Valle and San Fernando for the logistic support. We also want to express our acknowledgment to the help of the handling editor (Yves Moussallam) as well as the reviewers, whose useful comments and constructive suggestions greatly improved the manuscript.

Funding

This research was financially supported by the projects (i) TFvolcano and (ii) TFaguas from TFinnova Program of the Cabildo Insular de Tenerife (Spain) and (iii) SPITERM from the Ministry of Economy, Industry and Competitiveness of the Spanish Government (RTC-2016-4699-2).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Cecilia Amonte.

Additional information

Editorial responsibility: Y. Moussallam

Supplementary Information

ESM 1

(DOCX 69 kb)

ESM 2

(PDF 160 kb)

ESM 3

(PDF 140 kb)

ESM 4

(PDF 206 kb)

ESM 5

(PDF 149 kb)

ESM 6

(PDF 150 kb)

ESM 7

(PDF 145 kb)

ESM 8

(PDF 102 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Amonte, C., Asensio-Ramos, M., Melián, G.V. et al. Hydrogeochemical temporal variations related to changes of seismic activity at Tenerife, Canary Islands. Bull Volcanol 83, 24 (2021). https://doi.org/10.1007/s00445-021-01445-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00445-021-01445-4

Keywords

Navigation