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Bulletin of Volcanology

, 79:90 | Cite as

Plume composition and volatile flux of Nyamulagira volcano, Democratic Republic of Congo, during birth and evolution of the lava lake, 2014–2015

  • N. Bobrowski
  • G. B. Giuffrida
  • S. Arellano
  • M. Yalire
  • M. Liotta
  • L. Brusca
  • S. Calabrese
  • S. Scaglione
  • J. Rüdiger
  • J. M. Castro
  • B. Galle
  • D. Tedesco
Research Article

Abstract

Very little is known about the volatile element makeup of the gaseous emissions of Nyamulagira volcano. This paper tries to fill this gap by reporting the first gas composition measurements of Nyamulagira’s volcanic plume since the onset of its lava lake activity at the end of 2014. Two field surveys were carried out on 1 November 2014, and 13–15 October 2015. We applied a broad toolbox of volcanic gas composition measurement techniques in order to geochemically characterize Nyamulagira’s plume. Nyamulagira is a significant emitter of SO2, and our measurements confirm this, as we recorded SO2 emissions of up to ~ 14 kt/d during the studied period. In contrast to neighbouring Nyiragongo volcano, however, Nyamulagira exhibits relatively low CO2/SO2 molar ratios (< 4) and a high H2O content (> 92% of total gas emissions). Strong variations in the volatile composition, in particular for the CO2/SO2 ratio, were measured between 2014 and 2015, which appear to reflect the simultaneous variations in volcanic activity. We also determined the molar ratios for Cl/S, F/S and Br/S in the plume gas, finding values of 0.13 and 0.17, 0.06 and 0.11, and 2.3·10−4 and 1·10−4, in 2014 and 2015, respectively. A total gas emission flux of 48 kt/d was estimated for 2014. The I/S ratio in 2015 was found to be 3.6·10−6. In addition, we were able to distinguish between hydrogen halides and non-hydrogen halides in the volcanic plume. Considerable amounts of bromine (18–35% of total bromine) and iodine (8–18% of total iodine) were found in compounds other than hydrogen halides. However, only a negligible fraction of chlorine was found as compounds other than hydrogen chloride.

Keywords

Nyamulagira Plume composition Total gas flux 

Notes

Acknowledgements

The authors thank the staff of the Goma Volcano Observatory and the UN mission of MONUSCO and the South African pilots (MONUSCO) for their support in terms of the helicopter and logistics, as well as financial support from UN. N.B. and J.M.C. thank for financial support from the VAMOS research center at the University of Mainz during the time of writing. Support for running the NOVAC stations came mostly from the Swedish International Development Cooperation Agency (SIDA). We also thank Patrick Allard and Andrew Harris as editors, to Alessandro Aiuppa, Fran Van Wyk de Vries and an anonymous referee for their useful comments, which improved the quality of our manuscript. We thank Mike Cassidy and Tjarda Roberts for improving the language of our manuscript.

Supplementary material

445_2017_1174_MOESM1_ESM.docx (1.7 mb)
ESM 1 (DOCX 1.71 MB).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2017

Authors and Affiliations

  • N. Bobrowski
    • 1
    • 2
  • G. B. Giuffrida
    • 3
  • S. Arellano
    • 4
  • M. Yalire
    • 5
  • M. Liotta
    • 3
  • L. Brusca
    • 3
  • S. Calabrese
    • 6
  • S. Scaglione
    • 6
  • J. Rüdiger
    • 7
  • J. M. Castro
    • 2
  • B. Galle
    • 4
  • D. Tedesco
    • 8
    • 9
  1. 1.Institut für UmweltphysikRuprecht Karls UniversityHeidelbergGermany
  2. 2.Institut für GeowissenschaftenJohannes Gutenberg UniversityMainzGermany
  3. 3.Istituto Nazionale di Geofisica e VulcanologiaSezione di PalermoItaly
  4. 4.Department of Space, Earth and EnvironmentChalmers University of TechnologyGöteborgSweden
  5. 5.OVGGomaCongo
  6. 6.DiSTeMPalermoItaly
  7. 7.Institut für Anorganische und Analytische ChemieMainzGermany
  8. 8.Campania University-Luigi VanvitelliCasertaItaly
  9. 9.INGVRomeItaly

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