Abstract
The effect of grain growth on the cation exchange between synthesized forsterite aggregates (i.e., dunite) and nickel-rich aqueous fluid was evaluated experimentally at 1.2 GPa and 1,200°C. The grain boundary (GB) migration caused nickel enrichment in the area swept by the GBs in a fashion similar to that reported for stable isotope exchange in the quartz aggregates. The progress of the grain growth resulted in an increase in the average nickel concentration in the dunites of up to ~80 times that was calculated for a system having stationary GBs. The overall diffusivity of the nickel along the wet GBs and interconnected fluid networks was found to be 6.5 × 10−19–6.7 × 10−18 m3/s, which is 4–5 orders of magnitude higher than the grain boundary diffusivity in the dry dunite. These results show that the grain growth rate is a fundamental factor in the evaluation of the time scale of chemical homogenization in the upper mantle.
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References
Balluffi RW, Cahn JW (1981) Mechanism for diffusion induced grain boundary migration. Acta Metall 29:493–500
Brenan JM (1993) Diffusion of chlorine in fluid-bearing quartzite: effects of fluid composition and total porosity. Contrib Miner Petrol 115:215–224
Chongmo L, Hillart M (1982) Diffusion induced grain boundary migration in Cu–Zn. Acta Metall 30:1133–1145
Cmíral M, Fitz Gerald JD, Faul UH, Green DH (1998) A close look at dihedral angles and melt geometry in olivine-basalt aggregates: a TEM study. Contrib Miner Petrol 130:336–345
Cole DR, Chakraborty S (2001) Rates and mechanisms of isotope exchange. In: Valley JW, Cole DR (eds) Stable isotope geochemistry, reviews in mineralogy, vol. 43, Mineralogical Society of America, pp 83–233
Costa F, Chakraborty S (2008) The effect of water on Si and O diffusion rates in olivine and implications for transport properties and processes in the upper mantle. Phys Earth Planet Inter 166:11–29
Dohmen R, Chakraborty S, Becker H-W (2002) Si and O diffusion in olivine and implications for characterizing plastic flow in the mantle. Gephys Res Lett 29:2030. doi:10.1029/2002GL015480
Evans B, Hay RS, Shimizu N (1986) Diffusion-induced grain boundary migration in calcite. Geology 14:60–63
Farver JR, Yund RA, Rubie DC (1994) Magnesium grain boundary diffusion in forsterite aggregates at 1,000–1,300° and 0.1 MPa to 10 GPa. J Geophys Res 99:19809–19819
Faul UH, Fitz Gerald JD (1999) Grain misorientations in partially molten olivine aggregates: an electron backscatter diffraction study. Phys Chem Miner 26:187–197
Fisher JC (1951) Calculation of diffusion penetration curves for surface and grain boundary diffusion. J Appl Phys 22:74–77
Grimmer H (1979) The distribution of disorientation angles if all relative orientations of neighbouring grains are equally probable. Scr Metall 13:161–164
Hillert M, Purdy GR (1978) Chemically induced grain boundary migration. Acta Metall 26:333–340
Hiraga T, Anderson IM, Kohlstedt DL (2003) Chemistry of grain boundaries in mantle rocks. Am Miner 88:1015–1019
Holzapfel C, Chakraborty S, Rubie DC, Frost DJ (2007) Effect of pressure on Fe–Mg, Ni and Mn diffusion in (Fe x Mg1−x )2SiO4 olivine. Phys Earth Planet Inter 162:186–198
Hsueh CH, Evans AG, Coble RL (1982) Microstructure development during final/intermediate stage sintering. I. pore/grain boundary separation. Acta Metal 30:1269–1279
Ichinose H, Ishida Y (1989) High-resolution in situ observation of moving grain boundaries in gold by high-resolution electron microscopy. Philos Mag A 60:555–562
Kohlstedt DL, Keppler H, Rubie DC (1996) Solubility of water in the α, β and γ phases of (Mg, Fe)2SiO4. Contrib Miner Petrol 123:345–357
Kushiro I (1969) The system forsterite-diopside-silica with and without water at high pressures. Am J Sci 267:269–294
McCaig A, Covey-Crump SJ, Ismail WB, Lloyd GE (2006) Fast diffusion along mobile grain boundaries in calcite. Contrib Miner Petrol 153:159–175
Mishin YM, Razumovskii IM (1992) A model for diffusion along a moving grain boundary. Acta Metall Mater 40:839–845
Morioka M (1981) Cation diffusion in olivine-II: Ni–Mg, Mn–Mg, Mg and Ca. Geochim Cosmochim Acta 45:1573–1580
Mosenfelder JL, Deligne NI, Asimow PD, Rossman GR (2006) Hydrogen incorporation in olivine from 2 to 12 GPa. Am Miner 91:285–294
Nakamura M, Watson EB (2001) Experimental study of aqueous fluid infiltration into quartzite: implications for the kinetics of fluid redistribution and grain growth driven by interfacial energy reduction. Geofluids 1:73–89
Nakamura M, Yurimoto H, Watson EB (2005) Grain growth control of isotope exchange between rocks and fluids. Geology 33:829–832
Ohuchi T (2006) A new chemical etching technique for peridotites using molten anhydrous borax. Am Miner 91:579–583
Ohuchi T, Nakamura M (2006) Microstructure evolution of aqueous fluid-bearing wehrlites: implications for the fluid distribution in polymineralic rocks. J Geophys Res 111. doi:10.1029/2004JB003340
Ohuchi T, Nakamura M (2007a) Grain growth in forsterite–diopside system. Phys Earth Planet Inter 160:1–21
Ohuchi T, Nakamura M (2007b) Grain growth in the system forsterite–diopside–water. Phys Earth Planet Inter 161:281–304
Paterson MS (1982) The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials. Bull Miner 105:20–29
Petry C, Chakraborty S, Palme H (2004) Experimental determination of Ni diffusion coefficients in olivine and their dependence on temperature, composition, oxygen fugacity, and crystallographic orientation. Geochim Cosmochim Acta 68:4179–4188
Pizaolo S, Bestmann M, Prior DJ, Spiers CJ (2006) Temperature dependent grain boundary migration in deformed-then-annealed material: observations from experimentally deformed synthetic rocksalt. Tectonophys 427:55–71
Ree J-H, Park Y (1997) Static recovery and recrystallization microstructures in sheared octachloropropane. J Struct Geol 19:1521–1526
Schmidt NH, Olesen NO (1989) Computer-aided determination of crystal lattice orientation from electron channeling patterns in the SEM. Can Miner 27:15–22
Toriumi M (1982) Grain boundary migration in olivine at atmospheric pressure. Phys Earth Planet Inter 30:26–35
Tullis J, Yund RA (1982) Grain growth kinetics of quartz and calcite aggregate. J Geol 90:301–331
Watson EB (1991) Diffusion in fluid-bearing and slightly-melted rocks: experimental and numerical approaches illustrated by iron transport in dunite. Contrib Miner Petrol 107:417–434
Watson EB (1996) Surface enrichment and trace-element uptake during crystal growth. Geochim Cosmochim Acta 60:5013–5020
Watson EB, Wark DA (1997) Diffusion of dissolved SiO2 in H2O at 1 GPa, with implications for mass transport in the crust and upper mantle. Contrib Miner Petrol 130:66–80
Xu Y, Menzzies MA, Vroon P, Mercier JC, Lin C (2005) Texture–temperature–geochemistry relationships in the upper mantle as revealed from spinel peridotite xenoliths from Wangqing, NE China. J Petrol 39:469–493
Yamazaki D, Kato T, Ohtani E, Toriumi M (1996) Grain growth rate of MgSiO3-perovskite and periclase under lower mantle conditions. Science 274:2052–2054
Yund RA (1997) Rates of grain boundary diffusion through enstatite and forsterite reaction rims. Contrib Miner Petrol 126:224–236
Acknowledgments
T.O. carried out the experiments and interpretation of the results. M.N. contributed to the theoretical calculations and discussion, and K.M. contributed to the EBSD analysis. We thank R. Dohmen and T. Hiraga for their critical reviews. This work was financially supported by the JSPS Postdoctoral Fellowship for Research Abroad awarded to T.O., a Grant-in-Aid for scientific research to M.N., the Global COE program of Ehime University, and the 21st century COE and the Global COE programs of Tohoku University.
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Communicated by H. Keppler.
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Ohuchi, T., Nakamura, M. & Michibayashi, K. Effect of grain growth on cation exchange between dunite and fluid: implications for chemical homogenization in the upper mantle. Contrib Mineral Petrol 160, 339–357 (2010). https://doi.org/10.1007/s00410-009-0481-7
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DOI: https://doi.org/10.1007/s00410-009-0481-7