Skip to main content
Log in

Rapid crystallization of the Animikie Red Ace Pegmatite, Florence county, northeastern Wisconsin: inclusion microthermometry and conductive-cooling modeling

  • Original Paper
  • Published:
Contributions to Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

We evaluated the crystallization regime of a zoned pegmatite dike and the degree of magma undercooling at the onset of crystallization by analyzing coeval fluid and melt inclusion assemblages. The liquidus temperature of the pegmatite magma was ~720°C, based on re-melting of crystallized-melt inclusions in heating experiments. The magma crystallized sequentially starting with a thin border zone, which formed in less than one day at an average temperature of ~480°C based on primary fluid inclusions, meaning 240°C undercooling. The primary inclusions from the outer zones were postdated by secondary inclusions trapped between 580 and 720°C, representing fluid exsolved from hotter, still crystallizing inner pegmatite units. The huge temperature contrast between the pegmatite’s inner and outer zones was simulated by conductive-heat numerical modeling. A 2.5 m wide dike emplaced in 220°C rocks cools entirely to <400°C in less than 50 days. Unidirectional and skeletal textures also indicate rapid, disequilibrium crystallization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Bayley RW, Dutton CE, Lamey CA, Treves SB (1966) Geology of the Menominee iron-bearing district, Dickinson County, Michigan, and Florence and Marinette counties, Wisconsin (US Geological Survey Professional Paper 513). US Geological Survey, Reston, VA, p 96

    Google Scholar 

  • Bodnar RJ, Student JJ (2006) Melt inclusions in plutonic rocks: petrography and microthermometry. In: Webster JD (ed) Melt inclusions in plutonic rocks, vol 36. Mineralogical Association of Canada, Quebec, pp 1–25

    Google Scholar 

  • Bouhifd MA, Whittington ARJ, Roux J, Richet P (2006) Effect of water on the heat capacity of polymerized aluminosilicate glasses and melts. Geochim Cosmochim Acta 70:711–722

    Article  Google Scholar 

  • Brown PE, Hagemann SG (1995) MacFlinCor and its application to fluids in Archean lode-gold deposits. Geochim Cosmochim Acta 59:3943–3952

    Article  Google Scholar 

  • Brown PE, Lamb WM (1989) P–V–T–X properties if fluids in the system H2O–CO2–NaCl: new graphical presentations and implications for fluid inclusion studies. Geochim Cosmochim Acta 53:1209–1221

    Article  Google Scholar 

  • Cameron EM, Jahns RH, McNair AH, Page LR (1949) Internal structure of granitic pegmatites. Economic Geology Monograph 2, p 115

    Google Scholar 

  • Černý P (1993a) Rare-element granitic pegmatites. Part I: anatomy and internal evolution of pegmatite deposits. In: Sheahan PA, Cherry ME (eds) Ore deposit models (Geoscience Canada reprint series, vol 6). Geological Association of Canada, St. John’s, Newfoundland, pp 29–47

    Google Scholar 

  • Černý P (1993b) Rare-element granitic pegmatites. Part II: regional to global environments and petrogenesis. In: Sheahan PA, Cherry ME (eds) Ore deposit models (Geoscience Canada reprint series, vol 6). Geological Association of Canada, St. John’s, Newfoundland, pp 49–62

    Google Scholar 

  • Černý P, Ercit S (2005) The classification of granitic pegmatites revisited. Can Mineral 43:2005–2026

    Article  Google Scholar 

  • Černý P, Blevin PL, Cuney M, London D (2005) Granite-related ore deposits. In: Hedenquist J, Thompson JFH, Goldfarb RJ, Richards JP (eds) Economic geology 100th anniversary volume. Society of Economic Geologists, Littleton, pp 337–370

    Google Scholar 

  • Chapman DS, Furlong KP (1992) Thermal state of the continental crust. In: Fountain DM, Arculus RJ, Kay RW (eds) Continental Lower Crust, vol. 23. Elsevier, New York, pp 179–199

    Google Scholar 

  • Clauser C, Huenges E (1995) Thermal conductivity of rocks and minerals. In: Ahrens TJ (ed) Rock physics and phase relations–a handbook of physical constants, AGU reference shelf, vol 3. American Geophysical Union, Washington, DC, pp 105–126

    Google Scholar 

  • Diamond LW (1992) Stability of CO2 clathrate hydrate + CO2 liquid + CO2 vapour + aqueous KCl–NaCl solutions: experimental determination and application to salinity estimates of fluid inclusions. Geochim Cosmochim Acta 56:273–280

    Article  Google Scholar 

  • Dutton CE (1971) Geology of the Florence area, Wisconsin and Michigan, Scale 1:24,000 (US Geological Survey Professional Paper 633). US Geological Survey, Reston, VA, p 54

    Google Scholar 

  • Ercit TS, Groat LA, Gault RA (2003) Granitic pegmatites of the O’Grady batholith, N.W.T., Canada: a case study of the evolution of the elbaite subtype of rare-element granitic pegmatite. Can Mineral 41:117–137

    Article  Google Scholar 

  • Falster AU, Simmons WB (1988) Emplacement, mineralogy, and internal evolution of a highly evolved Li-pegmatite in Florence county, Wisconsin. In: Klasner JS, Hughes JD, Schultz KJ (eds) 34th annual meeting, Institute on Lake Superior Geology proceedings (Marquette, MI, 12–13 May 1988), Part 1, Abstracts, vol 34. Institute on Lake Superior Geology, pp 26–28

  • Falster AU, Simmons WB, Webber KL (1996) The mineralogy and geochemistry of the Animikie Red Ace pegmatite, Florence county, Wisconsin. Rec Res Dev Mineral 1:7–67

    Google Scholar 

  • Falster AU, Simmons WB, Webber KL (2005) Origin of the pegmatites in the Hoskin Lake pegmatite field, Florence county, Wisconsin. In: Pezzotta F (ed) Crystallization Processes in granitic pegmatites, international meeting, Mineralogical Society of America, Cavoli, Elba Island, Italy. http://www.minsocam.org/msa/special/Pig/PIG_articles/PIG_articles.html

  • Falster AU, Simmons WB, Webber KL (1997) Unusual chemistry of tourmaline in the Animikie Red Ace Pegmatite in Florence county, Wisconsin, U.S.A. In: Tourmaline 1997; international symposium on Tourmaline, Czech Republic Ministry of Education

  • Falster AU, Simmons WB, Webber KL (2001) Unorthodox compositional trends in columbite-group minerals from the Animikie Red Ace Pegmatite, Wisconsin, USA. J Czech Geol Soc 46:69–79

    Google Scholar 

  • Geiger CA, Guidotti CV (1989) Precambrian metamorphism in the southern Lake Superior region and its bearing on crustal evolution. Geoscience Wisconsin 13:1–33

    Google Scholar 

  • Goldstein RH, Reynolds TJ (1994) Systematics of fluid inclusions in diagenetic minerals, short course notes 31. SEPM (Society for Sedimentary Geology), Tulsa, OK, p 199

    Google Scholar 

  • Hoffman PF (1989) Precambrian geology and tectonic history of North America. In: Bally AW, Palmer AR (eds) The geology of North America–an overview, vol A. Geological Society of America, Boulder, CO, pp 447–512

    Google Scholar 

  • Holm DK (1998) From accretion to cratonization; new insights from the post-Penokean (1800–1400 Ma) tectonic evolution of the North American midcontinent. In: Anonymous (ed) 14th International Conference on Basement Tectonics, Blacksburg, Virginia, June 1998, 14:104–106

  • Holm DK, Van Schmus WR, MacNeill LC, Boerboom TJ, Schweitzer D, Schneider D (2005) U-Pb zircon geochronology of Paleoproterozoic plutons from the northern midcontinent, USA: evidence for subduction flip and continued convergence after Geon 18 Penokean orogenesis. Geol Soc Am Bull 117:259–275

    Article  Google Scholar 

  • Jenkins DM, Clare AK (1990) Comparison of the high-temperature and high-pressure stability limits of synthetic and natural tremolite. Am Mineral 75:358–366

    Google Scholar 

  • Koehler SR (1990) Geological setting and geochemistry of the Bush Lake Granite in relation to rare-element pegmatites, Florence county, Wisconsin. In: Fralick PW (ed) Institute on Lake Superior Geology, 36th annual meeting, vol 36. Institute on Lake Superior Geology, p 51

  • London D (1984) Experimental phase equilibria in the system LiAlSiO4–Si2O–H2O: a petrogenetic grid for lithium-rich pegmatites. Am Mineral 69:995–1004

    Google Scholar 

  • London D (2005) Granitic pegmatites: an assessment of current concepts and directions for the future. Lithos 2005:281–303

    Article  Google Scholar 

  • Luth WC, Jahns RH, Tuttle OF (1964) The granite system at pressures of 4 to 10 kilobars. J Geophys Res 69:759–773

    Article  Google Scholar 

  • Marshall DD, Groat LA, Falck H, Giuliani G, Neufeld H (2004) The Lened emerald prospect, Northwest Territories, Canada: insights from fluid inclusions and stable isotopes, with implications for Northern Cordilleran emerald. Can Mineral 42:1523–1539

    Article  Google Scholar 

  • Morgan GBV, London D (1999) Crystallization of the Little Three layered pegmatite-aplite dike, Ramona District, California. Contrib Mineral Petrol 136:310–330

    Article  Google Scholar 

  • Nabelek PI, Sirbescu M-LC (2006) A kinetic model for crystallization of very low temperature pegmatitic melts. Eos transactions of the American Geophysical Union 87, Joint Assembly Supplement, Abstract V53A-02

  • Robertson EC (1988) Thermal properties of rocks. US Geological Survey open file report 88–441, p 106

  • Roedder E (1984) Fluid inclusions. In: Ribbe PH (eds) Reviews of mineralogy, vol 12. Mineralogical Society of America, Washington, DC, p 646

    Google Scholar 

  • Schneider DA, Bickford ME, Cannon WF, Schulz KJ, Hamilton MA (2002) Age of volcanic rocks and syndepositional iron formations, Marquette range supergroup: implications for the tectonic setting of paleoproterozoic iron formations of the Lake Superior region. Can J Earth Sci 39:999–1012

    Article  Google Scholar 

  • Shepherd TJ, Rankin AH, Alderton DHM (1985) A practical guide to fluid inclusions studies. Blackie, Glasgow, p 239

    Google Scholar 

  • Sims PK, Peterman ZE, Schulz KJ (1985) Dunbar gneiss-granitoid dome: implications for Proterozoic tectonic evolution of northern Wisconsin. Geol Soc Am Bull 96:1101–1112

    Article  Google Scholar 

  • Sims PK, Schulz KJ, Peterman ZE (1992) Geology and geochemistry of early proterozoic rocks in the Dunbar area, northeastern Wisconsin (US Geological Survey Professional Paper 1517). US Geological Survey, Reston, VA, p 65

    Google Scholar 

  • Sims PK, Van Schmus W (1988) Geologic map of the Dunbar and Dunbar NE quadrangles. In: U.S. Geological Survey miscellaneous investigations series map, vol I-1714, scale 1:24,000. US Geological Survey, Reston, VA

  • Sirbescu M-LC, Nabelek PI (2003) Crustal melts below 400°C. Geology 31:685–688

    Article  Google Scholar 

  • Smirnov SZ, Thomas VG, Demin SP, Drebushchak VA (2005) Experimental study of boron solubility and speciation in the Na2O–B2O3–SiO2–H2O system. Chem Geol 223:16–34

    Article  Google Scholar 

  • Student JJ, Bodnar RJ (1999) Synthetic fluid inclusions XIV: coexisting silicate melt and aqueous fluid inclusions in the haplogranite-H2O-NaCl-KCl system. J Petrol 40:1509–1525

    Article  Google Scholar 

  • Thiery R, Van Den Kerkhof AM, Dubessy J (1994) VX properties of CH4–CO2 and CO2–N2 fluid inclusions: modelling for T < 31°C and P < 400 bars. Eur J Mineral 6:753–771

    Google Scholar 

  • Thomas R, Webster JD, Heinrich W (2000) Melt inclusions in pegmatite quartz: complete miscibility between silicate melts and hydrous fluids at low pressure. Contrib Mineral Petrol 139:394–401

    Article  Google Scholar 

  • Thomas R, Foerster H-J, Rickers K, Webster JD (2005) Formation of extremely F-rich hydrous melt fractions and hydrothermal fluids during differentiation of highly evolved tin-granite magmas; a melt-fluid-inclusion study. Contrib Mineral Petrol 148:582–601

    Article  Google Scholar 

  • Touret JLR, Smirnov SZ, Thomas VG, Peretyazhko IS, Zagorsky VYe (2007) Magmatic/hydrothermal transition in tourmaline-bearing miarolitic pegmatites: hydrosaline fluids or silica gels? In: Granitic pegmatites: the state of the art—international symposium, Porto, Portugal, abstract 2p

  • Van Schmus WR (1976) Early and middle Proterozoic history of the Great Lakes area, North America. R Soc Lond Philos Trans 280:605–628

    Article  Google Scholar 

  • Veksler IV, Thomas R (2002) An experimental study of B-, P- and F-rich synthetic granite pegmatite at 0.1 and 0.2 GPa. Contrib Mineral Petrol 143:673–683

    Article  Google Scholar 

  • Webber KL, Simmons WB, Falster AU, Foord EE (1999) Cooling rates and crystallization dynamics of shallow level pegmatite-aplite dikes, San Diego County, California. Am Mineral 84:708–717

    Google Scholar 

  • Wohletz K, Civetta L, Orsi G (1999) Thermal evolution of the Phlegraean magmatic system. Volcanism in the Campi Flegrei. J Volc Geotherm Res 91:381–414

    Article  Google Scholar 

  • Zhang Y-G, Frantz JD (1987) Determination of the homogenization temperatures and densities of supercritical fluids in the system NaCl–KCl–CaCl2–H2O using synthetic fluid inclusions. Chem Geol 64:335–350

    Article  Google Scholar 

Download references

Acknowledgments

We thank Dave Jenkins, Bill Blackburn, and Tim Lowenstein at Binghamton University for support with hydrothermal experiments, EMPA analysis, and use of the microscopy lab. Phil Oshel at Central Michigan University (CMU) assisted with the SEM analyses. Two CMU Office of Research and Sponsored Programs grants to Sirbescu and undergraduate student Hartwick supported this project. Al Falster and the Wisconsin Department of Natural Resources are thanked for information about how to access and releasing access to the ARA pegmatite, respectively. The manuscript benefited from thoughtful comments and remarks from Jacques Touret and from thorough suggestions by an anonymous reviewer.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mona-Liza C. Sirbescu.

Additional information

Communicated by T. L. Grove.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sirbescu, ML.C., Hartwick, E.E. & Student, J.J. Rapid crystallization of the Animikie Red Ace Pegmatite, Florence county, northeastern Wisconsin: inclusion microthermometry and conductive-cooling modeling. Contrib Mineral Petrol 156, 289–305 (2008). https://doi.org/10.1007/s00410-008-0286-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00410-008-0286-0

Keywords

Navigation