Abstract
The localization of nanoclay particles dispersed in the oil phase of a model oil-in-water emulsion depends on the wetting property of layered nanoparticles. Investigation at a single droplet interface shows that nanoclay is located at different interfacial regions depending on the hydrophilic property of the nanoclay surface. Hydrophobic nanoclays do not present Pickering phenomena at the interface and hardly form an interfacial layer. Hydrophilic nanoclay particles quickly move to the interface and form a Pickering interface with a high interfacial shear modulus. With surfactant, poor hydrophilic nanoclays can be located at the interface due to improvement of the wetting behavior caused by the surfactants dissolved in the aqueous continuous phase. With ionic molecules changing the wetting behavior of particles, the interfacial localization of nanoclays can be controlled and improve the mechanical property of emulsion.
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Asekomhe SO, Chiang R, Masliyah JH, Elliot JAW (2005) Some observations on the contraction behavior of a water-in-oil drop with attached solids. Ind Eng Chem Res 44:1241–1249
Behin J, Norouzi S (2011) Influence of water ions and aluminum silicate particles on emulsion resolution of crude oil. Petrol Coal 53(2):115–122
Binks BP (2002) Particles as surfactants-similarities and differences. Curr Opin Colloid Interface Sci 7:21–41
Binks BP, Lumsdon SO (2000) Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica. Langmuir 16:2539–2547
Bousmina M (1999) Effect of interfacial tension on linear viscoelastic behavior of immiscible polymer blends. Rheol Acta 38(3):251–254
Bressy L, Hebraud P, Schmitt V, Bibette J (2003) Rheology of emulsions stabilized by solid interfaces. Langmuir 19:598–604
Cho S, Hong JS, Lee SJ, Ahn KH, Covas JA, Maia JM (2011) Morphology and rheology of polypropylene/polystyrene/clay nanocomposite in batch and continuous melt mixing process. Macromol Mater Eng 296:341–348
Dickinson E (2012) Use of nanoparticles and microparticles in the formation and stabilization of food emulsions. Trends Food Sci Technol 24:4–12
Erni P, Fischer P, Windhab EJ, Kusnezov V, Stettin H, Lauger J (2003) Stress- and strain-controlled measurements of interfacial shear viscosity and viscoelasticity at liquid/liquid and gas/liquid interfaces. Rev Sci Instrum 74(11):4916–4924
Fenouillot F, Cassagnau P, Majeste JC (2009) Uneven distribution of nanoparticles in immiscible fluids: morphology development in polymer blends. Polymer 50:1333–1350
Gelot A, Friesen W, Hamza HA (1984) Emulsification of oil and water in the presence of finely divided solids and surface-active agents. Colloids Surf 12:271–303
Hong JS, Namkung H, Ahn KH, Lee SJ, Kim C (2006) The role of organically modified layered silicate in the breakup and coalescence of droplets in PBT/PE blends. Polymer 47:3967–3975
Hong JS, Kim YK, Ahn KH, Lee SJ, Kim C (2007) Interfacial tension reduction in PBT/PE/clay nanocomposite. Rheol Acta 46:469–478
Hong JS, Kim YK, Ahn KH, Lee SJ (2008) Shear-induced migration of nanoclay during morphology evolution of PBT/PS blend. J Appl Polym Sci 108:565–575
Hussain F, Hojjati M, Okamoto M, Gorga RE (2006) Polymer-matrix nanocomposites, processing, manufacturing, and application: an overview. J Compos Mater 40:1511
Otsubo Y, Prud’homme RK (1994) Rheology of oil-in-water emulsions. Rheol Acta 33(1):29–37
Okamoto M, Nam PH, Maiti P, Kotaka T, Hasegawa N, Usuki A (2001) A house of cards structure in polypropylene/clay nanocomposites under elongational flow. Nano Lett 1:295
Park S, Kashiwagi T, Cao C, Korach CS, Lewin M, Rafailovich MH (2010) Role of surface interactions in the synergizing polymer/clay flame retardant properties. Macromolecules 43(12):5338–5351
Ray SS, Pouliot S, Bousmina M, Utacki LA (2004) Role of organically modified layered silicate as an active interfacial modifier in immiscible polystyrene/polypropylene blends. Polymer 45:8403–8413
Tambe DE, Sharma MM (1993) Factors controlling the stability of colloid-stabilized emulsions. J Colloid Interface Sci 157:244–253
Tsugita A, Takemoto S, Mori K, Yoneya T, Otani Y (1983) Studies on O/W emulsions stabilized with insoluble montmorillonite-organic complexes. J Colloid Interface Sci 95(2):551–560
Vaia RA, Giannelis EP (1997) Polymer melt intercalation in organically-modified layered silicates: model predictions and experiment. Macromolecules 30(25):8000–8009
Vermant J, Cioccolo G, Nair KG, Moldenaers P (2004) Coalescence suppression in model immiscible polymer blends by nano-sized colloidal particles. Rheol Acta 43(5):529–538
Acknowledgements
This study was supported by Mid-career Researcher Program through NRF grant funded by the Korea government (MEST) (No. 20110016890). We would like to thank the CJ Co. for its kind supply of oil and information. P.R. acknowledges financial support from ETH grant ETHIIRA TH 32–1.
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Kim, J.K., Rühs, P.A., Fischer, P. et al. Interfacial localization of nanoclay particles in oil-in-water emulsions and its reflection in interfacial moduli. Rheol Acta 52, 327–335 (2013). https://doi.org/10.1007/s00397-013-0689-3
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DOI: https://doi.org/10.1007/s00397-013-0689-3