Skip to main content
Log in

Dissipative soft modes in viscous nematodynamics

  • Original Contribution
  • Published:
Rheologica Acta Aims and scope Submit manuscript

Abstract

The paper analyses a possible occurrence of soft and semi-soft viscous modes in slow (low Reynolds number) flows of uniaxially anisotropic nematic liquids as described by the five parametric Leslie-Ericksen-Parodi (LEP) constitutive equations (CEs). As in the similar elastic case, the soft viscous modes theoretically cause no resistance to flow, nullifying the corresponding components of the viscous part of the total stress tensor, and do not contribute to the dissipation. That is why these modes can also be called dissipative soft modes. In some flows, these dissipative soft modes may cause the effect of “nematic superfluidity”. As in the theories of nematic elastic solids, this effect is caused by a marginal thermodynamic stability. The analysis is simplified in a specific local, rotating orthogonal coordinate system whose one axis is directed along the director. We demonstrate that depending on closeness of material parameters to the marginal stability conditions, LEP CEs describe the entire variety of soft, semi-soft and harder behaviors of nematic viscous liquids. When the only shearing dissipative modes are soft, the viscous part of stress tensor is symmetric, and LEP CE for stress, scaled with isotropic viscosity is reduced to a one-parametric, stress-strain rate anisotropic relation. When additionally the elongation dissipative mode is also soft, this scaled relation has no additional parameters and shows that the dissipation is always less than that in isotropic phase. Simple shearing and simple elongation flows illustrate these possible effects.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Allen SJ, de Silva CN (1966) A theory of transversely isotropic fluids. J Fluid Mech 24:801–821

    Google Scholar 

  • Born M (1920) Über die beveglichkeit der electrolytishen ionen. Z Phys 1:221–249

    Google Scholar 

  • Calderer MC (1991) On multiphase flows of liquid crystal polymers. J Rheol 35:29–47

    Article  Google Scholar 

  • Clark MG, Saunders FC, Shanks IA, Leslie FM (1981) A study of flow-alignment instability during rectilinear oscillatory shear of nematics. Mol Cryst Liq Cryst 70:1473–1500

    Google Scholar 

  • de Gennes PG (1980) In: Helfrich W, Kleppke G (eds) Liquid Crystals in one- and two dimensional order. Springer, Berlin Heidelberg New York, pp 231–237

  • de Gennes PG, Prost G (1993) The physics of liquid crystals, 2nd edn. Clarendon Press, Oxford, chap 5

  • de Groot SR, Mazur P (1962) Non-equilibrium thermodynamics. North-Holland, Amsterdam, chap 12

  • Ericksen JL (1960a) Anisotropic fluids. Arch Ration Mech Anal 4:231–237

    Google Scholar 

  • Ericksen JL (1960b) Transversely isotropic fluids. Kolloid-Z 173(2):117–122

    Google Scholar 

  • Ericksen JL (1991) Liquid crystals with variable degree of orientation. Arch Rational Mech Anal 113:97–120

    Google Scholar 

  • Fradkin LJ, Kamotski IV, Terentjev EM, Zakharov DD (1993) Low-frequency acoustic waves in nematic elastomers. Proc R Soc Lond A 459:2627–2642

    Google Scholar 

  • Geffery GB (1922) The motion of ellipsoidal particles immersed in a viscous fluid. Proc R Soc Lond 102:161–179

    Google Scholar 

  • Golubovich L, Lubensky TC (1989) Nonlinear elasticity of amorphous solids. Phys Rev Lett 63:1082–1085

    Article  Google Scholar 

  • Grad H (1952) Statistical mechanics, thermodynamics, and fluid dynamics of systems with an arbitrary number of integrals. Comm Pure Appl Math 5:455–494

    Google Scholar 

  • Hinch EJ, Leal LG (1973) Time-dependent shear flows of s suspension of particles with weak Brownian rotations. J Fluid Mech 57:753–767

    Google Scholar 

  • Kamensky VG (1984) Nonlinear director dynamics of nematics in a magnetic field (in Russian). JETP 87:1262–1276

    Google Scholar 

  • Kleman M (1983) Points, lines and walls. Wiley

  • Larson RG (1999) The structure and rheology of complex fluids. Oxford University Press, New York

  • Larson RG, Mead DW (1989) Linear viscoelasticity of nematic liquid crystalline polymers. J Rheol 33:185–206

    Article  Google Scholar 

  • Leonov AI (1988) Extremum principles and exact two-side bounds of potential functional and dissipation for slow motions of viscoplastic media. J Non-Newtonian Fluid Mech 28:1–28

    Google Scholar 

  • Leonov AI, Volkov VS (2002) Internal rotations and stress tensor symmetry in theories of nematic liquids and solids. Los Alamos e-print archive: cond.mat/0203265

  • Leonov AI, Volkov VS (2003) Analysis of weak elasticity of nematic solids using a continuum approach. Los Alamos e-print arxive: cond.mat/0307146

  • Leonov AI, Volkov VS (2004) General analysis of linear nematic elasticity. J Eng Phys Thermophys 77:N.2

    Article  Google Scholar 

  • Leslie FM (1968) Some constitutive equations for liquid crystals. Arch Ration Mech Anal 28:265–283

    Article  Google Scholar 

  • Long D, Morse DC (2002) A Rouse-like model of liquid crystalline polymer melts: director dynamics and linear viscoelasticity. J Rheol 49–92

  • Lubensky TC, Mukhopadya R (2002) Symmetries and elasticity of nematic gels. Phys Rev E 66:011702

    Article  Google Scholar 

  • Parodi OJ (1970) Stress tensor for a nematic liquid crystal. J Phys (Fr) 31:581–584

    Google Scholar 

  • Rubin PL (1981) Relaxation processes and the propagation of ultrasound in nematic liquid crystals (in Russian). JETP 81:1756–1762

    Google Scholar 

  • Semenov AN (1993) Domain formation in liquid crystals under oscillating shear flows. J Rheol 37:911–917

    Article  Google Scholar 

  • Sorokin VS (1943) On internal friction of liquids and gases which have a hidden moment of impulse (in Russian) JETP 13:306–312

    Google Scholar 

  • Stephen MJ, Straley JP (1974) Rev Mod Phys 46:617–704

    Article  Google Scholar 

  • Terentjev EM, Warner M (2001) Linear hydrodynamics and viscoelasticity of nematic elastomers. Eur Phys J E 4:343–353

    Article  Google Scholar 

  • Truesdell C, Noll W (1992) The non-linear field theories of mechanics, 2nd edn. Springer, Berlin Heidelberg New York

  • Ugaz VM, Burghard WR (1998) In situ X-ray scattering study of model thermotropic copolyester under shear: evidence and consequences of flow-aligning behavior. Macromolecules 31:8474–8484

    Article  CAS  Google Scholar 

  • Warner M, Terentjev EM (2004) Liquid crystal elastomers. Clarendon Press, Oxford

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. I. Leonov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Leonov, A.I., Volkov, V.S. Dissipative soft modes in viscous nematodynamics. Rheol Acta 44, 331–341 (2005). https://doi.org/10.1007/s00397-004-0386-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00397-004-0386-3

Keywords

Navigation