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Micellar size of drag reducing cationic surfactants

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Abstract

Dynamic light scattering was employed to determine the effects of surfactant nature, concentration and counterion ratios, and shear on the hydrodynamic radii of micelles of commercial cationic surfactants which are powerful drag reducers in turbulent flow at high temperatures. Such surfactants are potentially useful for reducing pumping energy losses in district heating and cooling systems.

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References

  1. Zakin JL, Chou LC, Smith BC, Lu B (1993) Molecular variables affecting drag reduction by cationic surfactants. Proc. Int: Conf on Fluid Mechanics and Hydrodynamical Aspects of Biosphere. Academy of Sciences of the Czech Republic

  2. Chara Z, Zakin JL, Severa M, Myska J (1993) Turbulence measurements of drag reducing surfactant systems. Experiments in Fluids 16:36–41

    Article  CAS  Google Scholar 

  3. Chou LC (1991) Drag reducing cationic surfactant solutions for district heating and cooling systems. PhD Dissertation, The Ohio State University, Columbus

    Google Scholar 

  4. Chara Z, Myska J, Severa M, Zakin JL (1994) LDA Investigation of drag reducing surfactant systems. J Hydrol Hydro-mech 42:2–3, 141–150

    CAS  Google Scholar 

  5. Hofmann S, Stern P, Myska J (1994) Rheological behavior and birefringence investigations on drag-reducing surfactant solutions of tallow-(tris-hydroxyethyl)-ammonium acetate/sodium salicylate mixtures. Rheol Acta 33:419–430

    Article  CAS  Google Scholar 

  6. Ohlendorf O, Interthal W, Hoffmann H (1986) Surfactant systems for drag reduction: physico-chemical properties and rheological behaviour. Rheol Acta 25:468–486

    Article  CAS  Google Scholar 

  7. Kalus J, Lindner P, Hoffmann H, Ibel K, Munch Ch, Sandner J, Schmelzer O, Selbach J (1991) Transient small-angle neutron scattering of aligned micelles. Physica B 174:164–169

    Article  CAS  Google Scholar 

  8. Bewersdorff HW, Ohlendorf O (1988) The behaviour of drag-reducing cationic surfactant solutions. Colloid Polym Sci 266:941–953

    Article  CAS  Google Scholar 

  9. Nemoto N, Kuwahara M (1994) Self diffusion and viscoelasticity of elongated micelles from cetyltrimethyl-ammonium bromide in aqueous sodium salicylate solution. II. Temperature effect. Colloid Polym Sci 272:846–854

    Article  CAS  Google Scholar 

  10. Hoffmann H, Hofmann S, personal communication to J Myska, Universitat Bayreuth, 1992

  11. Hofmann S, Rauscher A, Hoffmann H (1991) Shear induced micellar structures. Ber Bunsenges Phys Chem 95:2, 153–164

    CAS  Google Scholar 

  12. Hofmann S (1994) Untersuchung des scherinduzierten Verhaltens mehrkom-ponentiger Tensidlösungen. Dissertation, Universitat Bayreuth

  13. Rehage H, Wunderlich I, Hoffmann H (1986) Shear induced phase transitions in dilute aqueous surfactant solutions. Progr Colloid Polymer Sci 72:51–59

    Article  CAS  Google Scholar 

  14. Hu Y, Wang SQ, Jamieson AM (1992) Kinetic studies of a shear thickening micellar solution. J Colloid Interf Sci 156:31–37

    Article  Google Scholar 

  15. Smith BC (1992) Flow birefringence, nuclear magnetic resonance and corrosion measurements on drag reducing cationic surfactant solutions for district heating and cooling systems. PhD Dissertation, The Ohio State University, Columbus

    Google Scholar 

  16. Schmitt V, Lequeux F, Pousse A, Roux D (1994) Flow behavior and shear induced transition near an isotropic/neumatic transition in equilibrium polymers. Langmuir 10:955–961

    Article  CAS  Google Scholar 

  17. Appell J, Marignan J (1991) Structure of giant micelles: a small angle neutron scattering study, J Phys II, France 1: 1447–1454

    Article  CAS  Google Scholar 

  18. Berret J, Appell J, Porte G (1993) Linear rheology of entangled wormlike micelles. Langmuir 9:2851–2854

    Article  CAS  Google Scholar 

  19. Khatory A, Lequeux F, Kern F, Candau SJ (1993) Linear and non-linear vis-coelasticity of semidilute solutions of wormlike micelles at high salt content. Langmuir 9:1456–1464

    Article  CAS  Google Scholar 

  20. Myska J, Stern P (1992) Properties of a drag reducing micelle system. Colloid Polym Sci 272:542–547

    Article  Google Scholar 

  21. Stern P, Myska J, Lu B, Smith BC, Chou LC, Zakin JL (1994) In: Gallegos P (ed), “Relationship of Flow Birefringence and Normal Stresses of Cationic Surfactant Systems to Their Turbulent Friction Reduction Characteristics.” Proc 4th European Rheology Cangress, Seville, pp 605-608

  22. Rose GD, Foster KL (1989) “Drag Reduction and Rheological Properties of Cationic Viscoelastic Surfactant Formulations.” J Non-Newt Fluid Mechanics 31:59–85

    Article  CAS  Google Scholar 

  23. Myska J, Zakin JL, Stern P, “Viscoelas-ticity of an Additive Used in a District Heating System.” in preparation

  24. Jakes J (1995) Regularized positive exponential sum (REPES) program -a way of inverting La Place transform data obtained by dynamic light scattering. Collection Czech Chem Commun 60:1781–1797

    Article  CAS  Google Scholar 

  25. Myska J, Zakin JL, Chara Z (1996) “Viscoelasticity of a Surfactant and its Drag Reducing Ability.” Appl Scient Research 55:297–3107

    Article  Google Scholar 

  26. Lu B, PhD Dissertation in progress, The Ohio State University, Columbus

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Myska, J., Stepanek, P. & Zakin, J.L. Micellar size of drag reducing cationic surfactants. Colloid Polym Sci 275, 254–262 (1997). https://doi.org/10.1007/s003960050079

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  • DOI: https://doi.org/10.1007/s003960050079

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