Phase behaviour and physical properties of the cationic quaternary system tetradecyldimethylamine oxide hydrochloric acid 1-hexanol water

Abstract

 The phase behaviour and properties of the tetradecyldimethylamine oxide/HCl/hexanol/water quaternary surfactant system have been studied by means of electric conductivity, rheology, freeze-fracture transmission electron microscopy (FF-TEM) and small-angle neutron scattering (SANS). In this system the originally zwitterionic surfactant can become increasingly charged by protonation through the addition of HCl, i.e. the degree of charging can be changed continuously. An interesting, isotropic phase (L₁ ^* phase) of low viscosity was observed for intermediate degrees of charging. From viscosity and conductivity measurements this phase can clearly be distinguished from the conventional L₁ phase that is composed of micelles. Investigation of the structures present by means of FF-TEM and SANS showed that the L₁ ^* phase is made up of unilamellar vesicles of extremely small diameter of 8–10 nm. Evidently such highly curved structures are stabilized by the electrostatic conditions in this system.