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Variation of micellization, thermodynamic, and surface properties of sodium dodecyl sulfate in aqueous media using 1,3-disulfo-2-alkyl imidazolium chloride ionic liquids

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Abstract

Three direct –NSO3H functionalized Brønsted acidic ionic liquids of 2-alkyl-1,3-disulfo imidazolium chloride with varied sizes of alkyl substituents (Me-, Et-, nBu-) were utilized to explore the effects of ionic liquids on aggregation behavior of anionic surfactant sodium dodecyl sulfate in aqueous media at various concentrations of ionic liquids and temperatures (288.15 K, 293.15 K, 298.15 K, 303.15 K, and 308.15 K). Critical micelle concentrations (CMCs) of the IL-surfactant systems obtained from conductivity measurement were found to be in good agreement with the CMC values of surface tension and UV–visible spectroscopy techniques. These CMCs values were used to calculate the thermodynamic parameters of IL-surfactant solutions such as standard free energy of micellization (ΔG°m), standard enthalpy of micellization (ΔH°m), and standard entropy of micellization (ΔS°m). Continuous decrease of the CMC values was observed with increasing concentrations of the ILs as well as temperatures. Packing parameters calculated from the surface tension measurement displayed small spherical shape for all the mixed micellar systems. Structural changes of the IL-surfactant solutions were also observed using FT-IR spectroscopic method. Increased positive inductive effect (+ I) of 2-alkyl substituent of the imidazolium cation of ionic liquid showed stabilizing effect on the micelle formation by lowering of more negative zeta potential values of the IL-surfactant systems.

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Data availability

The authors declare that the data supporting the findings of this study are available within the paper and its supplementary information file.

Abbreviations

SDS:

Sodium dodecyl sulfate

CMC:

Critical micelle concentration

ILs:

Ionic liquids

BAILs:

Brønsted acidic ionic liquids (BAILs)

BDSIM:

2-Butyl-1,3-disulfoimidazolium (BDSIM)

EDSIM:

2-Ethyl-1,3-disulfoimidazolium

MDSIM:

2-Methyl-1,3-disulfoimidazolium

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Acknowledgements

The authors are thankful to Sophisticated Analytical Instrumentation Centre, Tezpur University, for providing various facilities to carry out experimental works and University Grants Commission (UGC) for providing Senior Research Fellowship to Debanga Bhusan Bora.

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  1. Department of Chemical Sciences, Tezpur University, Napaam-784028, Tezpur, Assam, India

    Debanga Bhusan Bora, Bhaskar Ranjan Bora, Subham Paul, Sangeeta Kalita, Niharika Kashyap & Ruli Borah

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D.B. B. and R. B. wrote the main manuscript text. All the prime experiments were performed by D. B. B. and B. R. B. The analysis and interpretation of experimental data were done by R.B. and D.B.B. The other co-authors S.P., S. K., and N. K. synthesized and characterized the required ionic liquids. Validation experiments were conducted by S.P., S. K., and N. K. The corresponding author R.B. initiated the original idea of manuscript and supervised the work. All authors approved the final version of manuscript.

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Correspondence to Ruli Borah.

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Bora, D.B., Bora, B.R., Paul, S. et al. Variation of micellization, thermodynamic, and surface properties of sodium dodecyl sulfate in aqueous media using 1,3-disulfo-2-alkyl imidazolium chloride ionic liquids. Colloid Polym Sci (2024). https://doi.org/10.1007/s00396-024-05247-w

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