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Temperature dependent elastic repulsion of colloidal nanoparticles with a polymer adsorption layer

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Abstract

The model of pairwise elastic repulsion of contacting colloidal nanoparticles with a rigid core and deformable shell is discussed. A simple analytical equation is applied for the energy of elastic repulsion of nanoparticles with arbitrary sizes and the elasticity moduli of self-healing polymer adsorption layers. The model is based on the representation of the absorption layer as a continuous medium that is elastically deformed upon the contact of nanoparticles. The major characteristic of this medium is the elasticity modulus. The magnitude of the elasticity modulus is determined from the condition of balance of the van der Waals attractive forces of nanoparticles and the elastic repulsion of their adsorption layers in the contact area, taking into account the temperature variations. We employed the kinetic approach to describe the dependence of the elasticity modulus on both the temperature and the rate of its change.

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Funding

The reported research was funded by the Russian Foundation for Basic Research, the government of the Krasnoyarsk territory and Krasnoyarsk Regional Fund of Science, grant 18-42-243023, the RF Ministry of Science and Education, the State contract with Siberian Federal University for scientific research in 2017–2019, and SB RAS Program No II.2P (0358-2015-0010).

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Authors and Affiliations

  1. Institute of Computational Modeling SB RAS, 660036, Krasnoyarsk, Russia

    Anatoly P. Gavrilyuk, Valeriy S. Gerasimov & Alexander E. Ershov

  2. Institute of Mathematics and Computer Science, Siberian Federal University, Krasnoyarsk, 660041, Russia

    Anatoly P. Gavrilyuk

  3. Laboratory of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russia

    Valeriy S. Gerasimov, Alexander E. Ershov & Sergey V. Karpov

  4. Federal Research Center KSC SB RAS, Kirensky Institute of Physics, 660036, Krasnoyarsk, Russia

    Sergey V. Karpov

  5. Siberian State University of Science and Technology, Krasnoyarsk, 660014, Russia

    Sergey V. Karpov

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  1. Anatoly P. Gavrilyuk
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  2. Valeriy S. Gerasimov
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  3. Alexander E. Ershov
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  4. Sergey V. Karpov
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Correspondence to Anatoly P. Gavrilyuk.

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Gavrilyuk, A.P., Gerasimov, V.S., Ershov, A.E. et al. Temperature dependent elastic repulsion of colloidal nanoparticles with a polymer adsorption layer. Colloid Polym Sci 296, 1689–1697 (2018). https://doi.org/10.1007/s00396-018-4383-y

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  • DOI: https://doi.org/10.1007/s00396-018-4383-y

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