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Comb-like polysiloxanes with oligo(oxyethylene) and sulfonate groups in side chains for solvent-free dimethoxysilyl-terminated polypropylene oxide waterborne emulsions

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Abstract

The paper provided a new nonionic-anionic silicone surfactant—comb-like polysiloxanes with oligo(oxyethylene) and sulfonate groups (ESPS) in side chains, which was synthesized by successive hydrosilylation of poly(dimethylhydro)siloxane with allyl poly(ethylene glycol) acetic ester (M n = 540) and allyl glycidyl ether, then ring-opening reaction of oxirane groups with sodium bisulfite. 1H NMR, FT-IR, and gel permeation chromatography (GPC) were used to confirm the chemical structure of the surfactant. The thermal transition behavior of ESPS studied with differential scanning calorimetry (DSC) analysis showed that the surfactant had low glass-transition temperature of − 59.3 °C. Surface tension measurement result indicated that the the surface tension at the critical micelle concentration (cmc, 69.8 mg L−1) was 29.4 mN m−1, which was much lower than those of conventional hydrocarbon surfactants, indicating the higher surface activity of ESPS. The solvent-free dimethoxysilyl-terminated polypropylene oxide waterborne emulsions were prepared using ESPS as the single emulsifier via phase-inversion emulsification technique. An obvious abrupt changing point appearing at the conductivity curves indicated that the phase inversion was completely accomplished. The emulsions prepared with about 3.0 wt% ESPS content in oil phase exhibited excellent storage stability at 50 °C for 42 days and freeze-thaw stability.

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Funding

This study was funded by the National Natural Science Funds of China (grant number 21606138).

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Fine Chemicals, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, 250353, People’s Republic of China

    Jing Xu, Honglei Teng & Chuanfeng Gu

  2. College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, 250014, People’s Republic of China

    Zhaosheng Hou

  3. Shandong Meitai Pharmaceutical Co., Ltd., Jinan, 250101, China

    Lianlian Zhu

Authors
  1. Jing Xu
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  2. Honglei Teng
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  3. Zhaosheng Hou
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  4. Chuanfeng Gu
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  5. Lianlian Zhu
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Correspondence to Zhaosheng Hou.

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Xu, J., Teng, H., Hou, Z. et al. Comb-like polysiloxanes with oligo(oxyethylene) and sulfonate groups in side chains for solvent-free dimethoxysilyl-terminated polypropylene oxide waterborne emulsions. Colloid Polym Sci 296, 157–163 (2018). https://doi.org/10.1007/s00396-017-4237-z

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  • DOI: https://doi.org/10.1007/s00396-017-4237-z

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