Abstract
Amphiphile + aliphatic alcohol lyotropic systems with addition of water can form micelles with normal, mixed, and inverse type. Such systems display various types of mesophases and exhibit interesting structural, physical, and physicochemical properties. Therefore, lyotropic systems are important objects from both fundamental and application points of view. In this work, shape of anisometric micelles has been determined, and also, the magneto-morphologic properties of textures and optical refractive properties of mesophase have been investigated in hexadecyltrimethylammonium bromide (HDTMABr) + 1-decanol (DeOH) lyotropic system with various additions of water (H2O). Dependences of the magneto-morphologic properties vs. time have been obtained. Temperature and concentration dependences of the optical refractive index have been investigated. The effect of the DeOH/H2O concentration ratio on the refractive properties has been studied.
Similar content being viewed by others
References
Ekwall P (1975) Composition, properties and structures of liquid crystalline phases in systems of amphiphilic compounds. In: Brown GH (ed) Advances in liquid crystals, vol 1. Academic Press, New York/San Francisco/London, pp. 1–145
Lingmann B, Wennerström H (1980) Amphiphile aggregation in aqueous solutions, In: Micelles, Springer-Verlag, Berlin–Heidelberg–New York
Bartusch G, Dörfler HG, Hoffmann H (1992) Behavior and properties of lyotropic-nematic and lyotropic-cholesteric phases. Progr Colloid Polym Sci 89:307–315. doi:10.1007/BFb0116336
Petrov AG (1999) The Lyotropic state of matter. Molecular physics and living matter physics. Gordon & Breach Science Publishers, London–New York
Burducea G (2004) Lyotropic liquid crystals. I. Specific structures. Rom Rep Phys 56:66–86
Figueiredo Neto AM, Salinas SRA (2005) The physics of Lyotropic liquid crystals: phase transitions and structural properties. Oxford University Press, Oxford
Nesrullajev A (2007) Lyotropic liquid crystals. Amphiphilic systems. Mugla University Press, Mugla
Mukherjee P, Cardinal JP (1976) On micellization processes in aqueous solutions. J Phys Chem 78:882–893. doi:10.1021/j100602a007
Vedenov AA (1984) Physics of solutions. Science Publ, Moscow
Tanford C (1974) Theory of micelle formation in aqueous solutions. J Phys Chem 78:2469–2479
Southall NT, Dill KA, Haymet ADJ (2002) A view of the hydrophobic effect. J Phys Chem B 106:521–533. doi:10.1021/jp02010r
Hertel G, Hoffmann H (1988) Lyotropic nematic phases of double chain surfactants. Progr Colloid Polym Sci 76:123–131. doi:10.1007/BFb0114182
Hertel G (1989) Lyotrope nematische Phasen. Der Zusammenhang zwischen Molekülstruktur und Phasenverhalten, PhD Dissertation, Bayreuth University, Bayreuth
Auvray X, Petipas C, Anthore R, Ricco I, Lattes A (1989) X-ray diffraction study of mesophases of cetyltrimethylammonium bromide in water, formamide, and glycerol. Journ Phys Chem 93:7458–7464. doi:10.1021/j100358a040
Wolf T, Klauβner B, Von Bünau G (1990) Reversible light-induced phase-transition in the system cetyltrimethylammonium bromide–water containing a crown-ether-bearing azobenzene. Progr Colloid Polym Sci 83:176–180
Cortés AB, Valiente M, Rodenas E (1999) Properties of the L and lyotropic phases in CTAB/glycerol/water and CTAB/glyceraldehyde/water systems. Langmuir 15:6658–6603. doi:10.1021/la9817516
Canãdas O, Valiente M, Rodenas E (1998) Study of the cetyltrimethylammonium bromide/1,6-hexanediol/water system. J Colloid Interface Sci 203:294–298. doi:10.1006/jcis.1998.5507
Hiltrop K (2001) Phase chirality of micellar lyotropic liquid crystals. In: Kitzerow H-S, Bahr C (eds) Chirality in liquid crystals. Springer, Berlin, pp. 447–480
Nativ-Roth E, Regev O, Yerushalmi-Rozen R (2008) Shear-induced ordering of micellar arrays in the presence of single-walled carbon nanotubes. Chem Comm:2037–2039. doi:10.1039/b18148e
Xsu R, Pank W, Yu J, Huo Q (2007) J. Chen, Chemistry of zeolites and related porous materials: synthesis and structure, Wiley, Singapore
Demus D, Richter L (1980) Textures of liquid crystals. Weinheim, Verlag Chemie
Dierking I (2003) Textures of liquid crystals. Weinheim, Wiley–VCH Verlag
Zimmer JE, White JL (1982) Disclination structures in the carbonaceous mesophase. Adv Liq Cryst 5:157–213
Götz KG, Heckmann K (1958) The shape of soap micelles and other polyions as obtained from anisotropy of electrical conductivity. J Colloid Sci 13:266–272. doi:10.1016/0095-8522
Heckmann K, Götz KG (1958) Die Bestimmung der Form gelöster Polyionen aus dem Leitfähigkeitsanisotropie-Effekt. Z für Elektrochem 62:281–288. doi:10.1002/bbpc.19580620312
Rehage H (1982) Rheologische Untersuchungen an viskoelastischen Tensidlösungen, PhD Dissertation, Bayreuth University, Bayreuth
Schwarz G (1956) Zur Theorie der Leifahigkeitsanisotropie von Polyelectroliten in Lösung. Z für Phys 145:563–584. doi:10.1007/BF01332278
Nesrullajev A, Rustamov FA (1989) Electrophysical properties of lyotropic liquid crystalline systems. Colloid J (Sov) 51:778–781
Nesrullajev A. (1992) Mesomorphism and electrophysics of lyotropic liquid crystalline systems, DSc Dissertation, Institute of Physics, Academy of Sciences, Baku
Tsvetkov VN (1986) Rigid chain polymer molecules. Science Publ, Moscow
Frolov YG (1982) Course of colloid chemistry: surface effects and disperse systems. Science Publ, Moscow
Nesrullajev A (2014) Comparative investigations of phase states, mesomorphic and morphologic properties in hexadecyltrimethyl ammonium bromide/water and hexadecyltrimethyl ammonium bromide/water/1-decanol lyotropic liquid crystalline systems. J Mol Liq 200:425–430. doi:10.1016/j.molliq.2014.10.036
Steers M, Kleman M, Williams CE (1974) Rẻsultats d’observations au microscope polarisant de la phase smectique du diẻthyl-4-4′-axoxydibenzoate. J de Phys Lett 35:L21–L38. doi:10.1051/jphyslet:0197400350202100
Asher SA, Pershan DS (1979) Alignment and defect structures in oriented phosphatidylcholine multilayers. Biophys J 27:393–422. doi:10.1016/S0006-3495(79)85225-X
Candau F, Ballet F, Debauvais F, Wittmann JC (1982) Structural properties and topological defects of swollen polymeric mesophase: low angle X-ray diffraction and optical microscopic studies. J Colloid Interface Sci 87:356–374. doi:10.1016/0021-9797(82)90333-2
Saupe A (1977) Textures, deformations, and structural order of liquid crystals. J Colloid Interface Sci 58:549–558. doi:10.1016/0021-9797(77)90164-3
Kurik VM, Lavrentovich OD (1988) Review of topical problems: defects in liquid crystals: homotopy theory and experimental studies. Sov Phys Usp 31:196–224. doi:10.1070/PU1988v031n03ABEH005710
Kurik VM, Lavrentovich OD (1989) Defects in liquid crystals: homeotropic theory and experimental investigations. Usp Fiz Nauk (Sov) 154:381–431. doi:10.1070/PU1988v031n03ABEH005710
Boltenhagen P, Lavrentovich O, Kleman M (1991) Oily streaks and focal conic domains in Lα lyotropic liquid crystals. J de Phys II 1:1233–1252. doi:10.1051/jp2:1991130
Chistyakov IG (1966) Liquid crystals. Science Publ, Moscow
Sonin AS (1984a) Introduction to the physics of liquid crystals. Science Publ, Moscow
Schneider MB, Webb WW (1984) Undulating paired disclinations (oily streaks) in lyotropic liquid crystals. J de Phys 45:393–422. doi:10.1051/jphys:01984004502037300
Basappa G, Suneel Kumaran V, Nott PR, Ramaswami S, Naik VM, Rout D (1999) Structure and rheology of the defect–gel states of pure and particle–dispersed lyotropic lamellar phases. Europ Phys J B 12:269–276. doi:10.1007/s100510051004
Özden P, Nesrullajev A, Oktik Ş (2010) Phase states and thermo-morphologic, thermotropic and magneto-morphologic properties of lyotropic mesophases: sodium lauryl sulphate/water/1-decanol liquid crystalline system, Phys. Rev. E 82: 061701 (1-8). DOI: 10.1103/PhysRevE.82.061701.
Sonin AS (1987) Lyotropic nematics. Usp Fiz Nauk 153:273–310. doi:10.1070/PU1987v030n10ABEH002967
Muniandy SV, Kan CS, Lim SC, Radiman S (2003) Fractal analysis of lyotropic lamellar liquid crystal textures. Physica A 323:107–123. doi:10.1016/S0378-4371(03)00026-8
Friberg S (1992) Organized solutions: surfactants in science and technology. CRC Press, New York
Nesrullajev A (2013) Structural peculiarities of micelles in lamellar mesophase of lyotropic liquid crystalline systems: shape, sizes and anisometricity. J Mol Liq 187:337–342. doi:10.1016/j.molliq.2013.08.017
Nesrullajev A (2016) Amphiphile/water/decanol lyotropic liquid crystalline system: study of thermal states of anisometric micelles in nematic-calamitic and nematic-discotic mesophases. Tenside Surf Det 53:265–272
Yu LJ, Saupe A (1982) Deuteron resonance of D2O of nematic disodium cromoglycate-water system. Mol Cryst Liq Cryst 80:129–134. doi:10.1080/00268948208071026
Amaral LQ, Gulik IR, Mariani P (1992) Micellar hexagonal phases in lyotropic liquid-crystal. Rev A 46:3548–3550. doi:10.1103/PhysRevA.46.3548
Itri R, Amaral LQ, Mariani P (1996) Structure of the hexagonal phase of the sodium dodecyl sulfate and water system. Phys Rev E 54:5211–5216. doi:10.1103/PhysRevE.54.5211
Santin Fulho O, Itri R, Amaral LQ (2000) Decanol effect on the structure of the hexagonal phase in a lyotropic liquid crystal. J Phys B 104:959–964
Amaral LQ (2002) Changes in aggregate form, size and flexibility along phase sequences in lyotropic liquid crystals. Braz J Phys 32:540–547. doi:10.1590/S0103-97332002000300014
Sonin AS (1984b) Introduction to physics of liquid crystals. Science Publ, Moscow
Dierking I, Russell C (2003) Universal scaling laws for the anisotropic growth of SmA liquid crystal batonnets. Physica B 325:281–286. doi:10.1016/S092-4526(02)01540-5
Acknowledgements
This work has been partially supported by the Research Foundation of Mugla Sitki Koçman University, Grant No. BAP 15/124.
Funding
This study was funded by the Research Foundation of Mugla Sitki Koçman University, Grant No. BAP 15/124.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The author declares that he has no conflict of interest.
Rights and permissions
About this article
Cite this article
Nesrullajev, A. Lyotropic mesophase in amphiphile + aliphatic alcohol mixtures with additions of water: mesomorphic, thermomorphologic, and optical refracting properties. Colloid Polym Sci 295, 837–847 (2017). https://doi.org/10.1007/s00396-017-4068-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-017-4068-y