Abstract
Dynamics of ortho-kintetic flocculation of PSL particles with long-chain polycation of low charge density was studied together with the adsorption process of polyelectrolyte near isoelectric point as a function of ionic strength. Within the range of investigation, the initial rate of flocculation was found to take the maximum value immediately after the onset of mixing, but the flocculation gradually slows down with the progress of adsorption. The initial rate of flocculation goes through the minimum as ionic strength increases. Without salt addition, the rate of flocculation is about three times faster than that of salt-induced rapid coagulation. With slightly increasing ionic strength the rate of flocculation slows down because of the reductions of the stiffness and the size of polymer coil in solution and also of the smooth rearrangement of adsorbed chains. The adsorption process monitored by the electrophoresis demonstrates that the zero mobility appears much earlier than the time predicted by collision process in the presence of salt (KCl 100 mM). This trend can be explained by the concept of electrokinetically stagnant layer and by smooth spreading of polyelectrolyte on the colloidal surface. The kinetics of adsorption is in good accordance with the change in the flocculation rate.
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References
Bratby J (2006) Coagulation and flocculation in water and wastewater treatment, 2nd edn. IWA publishing Inc
Bolto B, Gregory J (2007) Organic polyelectrolytes in water treatment. Water Res 41:2301–2324
Swerin A, Ödberg L, Wågberg L (1996) An extended model for the estimation of flocculation efficiency factors in multicomponent flocculant systems. Colloids Surf A 113:25–38
Farrow JB, Swift JD (1996) A new procedure for assessing the performance of flocculants. Int J Miner Process 46:263–275
Petzold G, Schwarz S (2014) Polyelectrolyte complexes in flocculation applications. Adv Polym Sci 256:25–65
Gregory J (1973) Rates of flocculation of latex particles by cationic polymers. J Colloid Interface Sci 42:448–456
Ruehrwein RA, Ward DW (1952) Mechanism of clay aggregation by polyelectrolytes. Soil Sci 73:485–492
Fleer GJ, Cohen Stuart MA, Scheutjens JMHM, Cosgrove T, Vincent B (1993) Polymers at interfaces. Chapman & Hall
Netz RR, Andelman D (2003) Neutral and charged polymers at interfaces. Phys Rep 308:1–95
Gregory J (1988) Polymer adsorption and flocculation in sheared suspensions. Colloids Surfaces 31:231–253
Adachi Y (1995) Dynamic aspects of coagulation and flocculation. Adv Colloid Interface Sci 56:1–31
Adachi Y, Cohen Stuart MA, Fokkink R (1994) Kinetics of turbulent coagulation studied by means of end-over-end rotation. J Colloid Interface Sci 165:310–317
Adachi Y, Cohen Stuart MA, Fokkink R (1994) Dynamic aspects of bridging flocculation studied using standardized mixing. J Colloid Interface Sci 167:346–351
Adachi Y, Matsumoto T (1996) Dynamics of initial stage flocculation of polystyrene latex spheres with polyelectrolytes. Colloids Surf A 113:229–236
Besra L, Sengupta DK, Roy SK, Ay P (2004) Influence of polymer adsorption and conformation on flocculation and dewatering of kaolin suspension. Separation Purification Tech 37:231–246
Adachi Y, Xiao J (2013) Initial stage of bridging flocculation of PSL particles induced by an addition of polyelectrolyte under high ionic strength. Colloids Surf A 435:127–131
Aoki K, Adachi Y (2006) Kinetics of polyelectrolyte adsorption onto polystyrene latex particle studied using electrophoresis: effects of molecular weight and ionic strength. J Colloid Interface Sci 300:69–77
Somasundaran P, Yu X, Krishnakumar S (1998) Role of conformation and orientation of surfactants and polymers in controlling flocculation and dispersion of aqueous and non-aqueous suspensions. Colloids Surf A 133:125–133
Gregory J, Barany S (2011) Adsorption and flocculation by polymers and polymer mixtures. Adv Colloid Interface Sci 169:1–12
Feng L, Adachi Y, Kobayashi A (2014) Kinetics of Brownian flocculation of polystyrene latex by cationic polyelectrolyte as a function of ionic strength. Colloids Surf A 440:155–160
Popa I, Papastavrou G, Borkovec M (2010) Charge regulation effects on electrostatic patch-charge attraction induced by adsorbed dendrimers. Phys Chem Chem Phys 12:4863–4871
Szilagyi I, Trefait G, Tiraferri A, Maroni P, Borkovec M (2014) Polyelectrolyte adsorption, interparticle forces, and colloidal aggregation. Soft Matter 10:2479–2502
Borkovec M, Szilagyi I, Popa I, Finessi M, Sinha P, Manoni P, Papastavrou G (2012) Investigating forces between charged particles in the presence of oppositely charged polyelectrolytes with the multi-particle colloidal probe technique. Adv Colloid Interface Sci 179–182:85–97
Popa I, Gillies G, Papastavrou G, Borkovec M (2010) Attractive and repulsive electrostatic forces between positively charged latex particles in the presence of anionic linear polyelectrolytes. J Phys Chem B 114:3170–3177
Borkovec M, Papastavrou G (2008) Interactions between solid surfaces with adsorbed polyelectrolytes of opposite charge. Current Opinion Colloid Interface Sci 13:429–437
Lin W, Kobyashi M, Skarba M, Mu C, Galletto P, Borkovec M (2006) Heteroaggregation in binary mixtures of oppositely charged particles. Langmuir 22:1038–1047
Kobayashi M, Nanaumi H, Muto Y (2009) Initial deposition rate of latex particles in the packed bed of zirconia beads. Colloids Surf A 347:2–7
Adachi Y, Feng L, Kobayashi M (2015) Kinetics of flocculation of polystyrene latex particles in the mixing flow induced with high charge density polycation near the isoelectric point. Colloids Surf A 471:38–44
Takuya S, Yuji W, Kobayashi M (2015) Kinetics of turbulent hetero-coagulation of oppositely charged colloidal particles. Theoretical Applied Mechanics Japan 63:133–145
Zhou Y, Franks GV (2006) Flocculation mechanism induced by cationic polymers investigated by light scattering. Langmuir 22:6775–6786
Zhou Y, Jameson GJ, Franks GV (2008) Influence of polymer charge on the compressive yield stress of silica aggregated with adsorbed cationic polymers. Colloids Surf A 331:183–194
Bauer D, Buchhammer H, Fuchs A, Jaeger W, Killmann E, Lunkwitz K, Rehmet R, Schwarz S (1999) Stability of colloidal silica, sikron and polystyrene latex influenced by the adsorption of polycations of different charge density. Colloids Surfaces 156:291–305
Feng L, Adachi Y (2014) Brownian flocculation of negatively charged latex particles with low charge density polycation at various ionic strengths. Colloids Surf A 454:128–134
Elaissari A, Pefferkorn E (1991) Aggregation modes of colloids in the presence of block copolymer micelles. J Colloid Interface Sci 143:343–355
Ouali L, François J, Pefferkorn E (1999) Adsorption of telechelic poly(ethylene oxide) on colloids: influence on colloid stability. J Colloid Interface Sci 215:36–42
Saffman PG, Turner JS (1956) On the collision of drops in turbulent clouds. J Fluid Mech 1:16–30
Higashitani K, Yamauchi K, Matsuno Y, Hosokawa G (1983) Turbulent coagulation of particles dispersed in a viscous fluid. J Chem Eng Jpn 16:299
van de Ven TGM, Mason SG (1977) The microrheology of colloidal dispersions VII. Orthokinetic doublet formation of spheres. Colloid Polymer Sci 255:468–479
Goodwin JW, Hearn J, Ho CC, Ottewill RH (1974) Studies on the preparation and characterisation of monodisperse polystyrene laticee. Colloid Polymer Sci 252:464–471
Kobayashi M (2008) Electrophoretic mobility of latex spheres in the presence of divalent ions: experiments and modeling. Colloid Polymer Sci 286:935–940
Ohshima H (2012) Electrophoretic mobility of charged particles. In: Ohshima H (ed) Electrical phenomena at interfaces and biointerfaces: fundamentals and applications in nano-, bio-, and environmental sciences. John Wiley & Sons, Hoboken
Odijk T (1977) Polyelectrolytes near the rod limit. J Polymer Sci: Polymer Phy Ed 15:477–483
Becker AL, Henzler K, Welsch N, Ballauff M, Borisov O (2012) Proteins and polyelectrolytes: a charged relationship. Curr Opin Colloid Interface Sci 17:90–96
Bakeev KN, Izumrudov VA, Kuchanov SI, Zezin AB, Kabanov VA (1992) Kinetics and mechanism of interpolyelectrolyte exchange and addition reactions. Macromolecules 25:4249–4254
Barany S (2014) Polymer adsorption and electrokinetic potential of dispersed particles in weak and strong electric fields. Adv Colloid Interface Sci. doi:https://doi.org/10.1016/j.cis.2014.09.009
De Witt JA, van de Ven TGM (1992) Kinetics and reversibility of the adsorption of poly(vinyl alcohol) onto polystyrene latex particles. Langmuir 8:788–793
Santore M (2005) Dynamics in adsorbed homopolymer layers: understanding complexity from simple starting points. Current Opinion Colloid Int Sci 10:176–183
Pelssers EGM, Cohen Stuart MA, Fleer GJ (1990) Kinetics of bridging flocculation. Role of relaxations in the polymer layer. J Chem Soc Faraday Trans 86:1355–1361
Plunkett MA, Claesson PM, Ernstsson M, Rutland MW (2003) Comparison of the adsorption of different charge density polyelectrolytes: a quartz crystal microbalance and X-ray photoelectron spectroscopy study. Langmuir 19:4673–4681
Acknowledgments
This work is funded by a Grant-in-Aid for Scientific Research (A22248025 and 15H04563) from JSPS. We acknowledge Prof. M.A. Cohen Stuart for his helpful discussion on the electrophoresis data and Miss Y. Wu for her additional measurements of electrophoresis. L. F. expresses her thanks to the China Scholarship Council.
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Feng, L., Kobayashi, M. & Adachi, Y. Initial stage dynamics of bridging flocculation of polystyrene latex particles with low charge density polycation in a mixing flow near the isoelectric point. Colloid Polym Sci 293, 3585–3593 (2015). https://doi.org/10.1007/s00396-015-3729-y
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DOI: https://doi.org/10.1007/s00396-015-3729-y